Fe_(40)Co_(40)Zr_(10)B_9M_1(M=Cu,Ge,Ag)合金的热稳定性及微观结构研究

采用单辊快淬法制备Fe40Co40Zr10B9Cu1、Fe40Co40Zr10B9Ge1和Fe40Co40Zr10B9Ag1非晶合金薄带,并对3种合金在不同温度下进行热处理.利用差热分析仪(DTA)和X射线衍射仪(XRD)等测试手段对样品的热稳定性及微观结构进行研究.结果表明:Fe40Co40Zr10B9Cu1、Fe40Co40Zr10B9Ge1和Fe40Co40Zr10B9Ag13种合金的激活能分别为262.4、267.6和252.3 k J/mol,说明Cu元素、Ge元素和Ag元素的添加对合金的热稳定性影响不大,Ge元素的添加最有利于提高合金的热稳定性.3种合金的晶化过程相似:非晶→非晶+α-Fe(Co)→α-Fe(Co)+Zr Co3B2+Fe(Co)3Zr.     

Deformation transition of intact coal induced by gas injection

Gas migration in coal bed is a multiple-physical process, of which not only includes gas desorption/diffusion through coal matrix and gas Darcy flow through the cleat system, but also results in deform...     

Degradability and biocompatibility of bioglass/poly(amino acid) composites with different surface bioactivity as bone repair materials

Bioglass (BG) possesses excellent bioactivity and has been widely used in the manufacture of biomaterials. In this study, a composite with different surface bioactivity was fabricated via in situ melting polymerization by incorporating BG and poly(amino acid) (PAA) at a suitable ratio. The structure of the composite was characterized by Fourier transform infrared spectroscopy and XRD. The compressive strength of the BG/PAA composites was 139 MPa (BG:PAA = 30:70). The BG/PAA composites were degradable, and higher BG in composite showed higher weight loss after 4 weeks of incubation in simulated body fluid. In addition, the BG/PAA composite maintained adequate residual compressive strength during the degradation period. The SEM results showed the differences in surface bioactivities of the composites directly, and 30BG/PAA composite showed thicker apatite layer and higher Ca/p than 15BG/PAA. in vitro MG-63 cell culture experiments showed that the composite was noncytotoxic and thus allows cells to adhere, proliferate, and differentiate. This indicates that the composite has good biocompatibility. The implantations in the bone defects of rabbits for 4 and 12 weeks were studied. The composites had good biocompatibility and were capable of guiding new bone formation without causing any inflammation. The composite may be successfully used in the development of bone implants.     

Weathering modification of acrylic emulsion by introducing UV absorbing groups

A new kind of UV-absorbing silicon-fluorinated acrylic emulsion was prepared by emulsion polymerization with 4-allyloxy-2-hydroxybenzophenone, 3-methacryloxypropyltrimethoxysilane (MPS) and hexafluorobutyl methacrylate (HFMA) as functional monomers. The emulsion and its coating were characterized by transmission electron microscope, Fourier transform infrared spectrum (FTIR), X-ray photoelectron spectroscopy, ultraviolet absorption spectrum,thermo-gravimetric analysis, water contact angle (CA), and artificial accelerated aging test. The results indicated that the emulsion with core-shell structure was synthesized and showed prominent absorption peaks at 320 and 350 nm. The water CA of the coating was increased from 70.2° to 86.7° because of the incorporated HFMAs and MPSs. Both of the initial and final decomposition temperatures of the coating were increased by more than 20°C compared with those of the unmodified coating. After 10 days of accelerated aging, the color difference (ΔE) and rate of loss of gloss (ΔG) were only 2.78% and 5.22%, while those of the unmodified coating were as high as 22.94% and 78.57%, respectively. Because of the UV absorbers were incorporated by chemical reaction, the new coating had a more durable and effective anti-ultraviolet performance compared with the coatings the UV absorbers were introduced by physical blending.     

Oxidation Performance of Fe-Al/WC Composite Coatings Produced by High Velocity Arc Sprayed at 650 ℃

Fe-Al intermetallics with remarkable high-temperatureintensity and excellent erosion,high-temperatureoxidation and sulfuration resistance are potential lowcost high-temperature structural material.ProducingFe-Al/WC composite coating by high velocity arcspraying(HVAS)on structural materials would notonly obviate the problems faced in fabrication of thesealloys into useful shapes,but also allow the effectiveuse of their outstanding high-temperature performance,which might thus promisingly mak…     

用含Pb、As、Sn地方生铁砂型铸造生产D型石墨铸铁的研究

基于Ph、As、Sn等元素有增大铁液过冷倾向的作用，利用含Ph、As、Sn的地方生铁，采用合金化和砂型铸造可以获得D型石墨铸铁，对其工艺方案进行了研究。用正交试验法设计试验方案，得到最佳工艺方案为：在亚共晶成分（WB％：3．2C，2．1si）的铁液中加入适量的铝（0．6％）和钛（0．8％），可以得到含有100％D型石墨的铸铁，其抗拉强度最高可达276MPa。     

坯料外形对镁合金矩形盒拉深成形的影响

用商业有限元软件模拟了在同一套模具和成形条件下不同毛坯外形的镁合金矩形盒拉深成形过程．依据数值模拟结果，分析了不同坯料外形对镁合金矩形盒拉深成形的影响。结果表明：使用矩形圆角坯料比其他坯料的成形性能好。     

用双层辉光等离子法在钛表面制备的Ti-Pd合金层性能研究

采用双层辉光等离子冶金技术在纯钛表面制备了Ti—Pd合金层。其深度大约为90μm，Pd含量呈梯度变化，并出现了TiPd3，TiPd2，Ti2Pd3，Ti3Pd5，TiPd，Ti4Pd等6种化合物相和Pd相。合金层在100℃的NaCl饱和溶液＋HCl溶液以及40℃的8．6％H2SO4溶液中的耐缝隙腐蚀性能优于Ti0．2Pd合金；在室温80％H2SO4的溶液中，腐蚀速率仅为0．682mm／a，是Ti0．2Pd合金的18．2％：在室温30％HCl的溶液中，表面Ti—Pd的腐蚀速率仅为0．004mm／a，是Ti0．2Pd合金的12．5％。     

圆锯片的有限元模态分析

针对金属冷热锯机锯片在锯切轧件过程中出现的振动问题 ,利用 MSC/ NASTRAN有限元软件 ,计算分析了各种参数对锯片模态的影响。从而为锯片的设计及其制造工艺的确定提供了可靠的参考依据 ,为最终解决生产中的实际问题发挥了重要作用     

钨钴硬质合金电化学蚀刻加工研究

对YG6硬质合金电化学蚀刻工艺进行了研究,提出了采用光致抗蚀剂作保护膜,在生成一定钝化膜的情况下进行电化学蚀刻的方法.在一定的蚀刻深度范围内,该工艺的可控性好、腐蚀区表面质量较好.