Thermal and crystallization characteristics of poly(ethylene terephthalate) with poly(oxybenzoate‐p‐trimethylene terephthalate) copolymer

Poly(ethylene terephthalate) (PET) was blended with two different poly(oxybenzoate‐p‐trimethylene terephthalate) copolymers, designated T28 and T64, with the level of copolymer varying from 1 to 15 wt %. All samples were prepared by solution blending in a 60/40 (by weight) phenol/tetrachloroethane solvent at 50°C. The crystallization behavior of the samples was studied by DSC. The results indicate that both T28 and T64 accelerated the crystallization rate of PET in a manner similar to that of a nucleating agent. The acceleration of PET crystallization rate was most pronounced in the PET/T64 blends with a maximum level at 5 wt % of T64. The melting temperatures for the blends are comparable to that of pure PET. The observed changes in crystallization behavior are explained by the effect of the physical state of the copolyester during PET crystallization as well as the amount of copolymer in the blends. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1599–1606, 2002     

聚合转化率对硫调型氯丁胶结构与性能的影响

研究了硫调型氯丁橡胶乳液聚合中转化率对产晶结构与性能的影响.结果表明,随单体转化率的提高,聚合物的凝胶量及其交联密度增大,致使断链速度减慢,所得断链胶的门尼粘度上升,残存凝胶量增加,分子支化程度增大,分子量分布变宽,焦烧时间缩短。而相应硫化胶的拉伸强度、撕裂强度、冲击弹性和硬度等提高,扯断伸长率和永久变形下降。这些变化一般在转化率为80——85％时有明显转折.综合考虑产量与质量,聚合转化率控制在82±2％较为适宜。     

Fabrication and optical characterization of poly(2,5‐di‐n‐butoxyphenylene) nanofibril arrays

Anodic aluminum oxide (AAO) membrane can be used as template for the synthesized nanostructures. In this article, we have prepared the AAO membrane by using electrooxidation of aluminum substrate in phosphoric acid, and fabricated poly(2,5‐di‐n‐butoxyphenylene) (BuO–PPP) nanofibril arrays by oxidative coupling polymerization of 1,4‐di‐n‐butoxybenzene (DBB) within the pores of the AAO template membrane. The detailed molecular structure of the polymer nanofibrils was characterized by using infrared and ¹H nuclear magnetic resonance spectra, and estimated to consist of almost equal fractions of 1,4‐ and 1,3‐ linkages. We have used transmission electron microscopy, scanning electron microscopy, and atom force microscopy to confirm the morphologies and images of the AAO template membrane and the fabricated nanometer scale of BuO–PPP nanofibril arrays. The experimental results demonstrated that the pores of the AAO membrane were regular and uniform, and parallel each other, and the BuO–PPP chains in the narrowest template‐synthesized nanofibrils were oriented parallel to the porous axes of the AAO membrane and perpendicular to the surface of the aluminum substrate. The polymer chain orientation was partially responsible for the enhanced conductivity. The ultraviolet absorption spectrum of the BuO–PPP nanofibril arrays shown that the polymer contains a better extended π‐conjugation system along poly‐(p‐phenylene) backbone, which resulted in longer wavelength shift of the absorption band, the absorption maxima were located at 258 nm (E₁ absorption band) and 332 nm (E₂ absorption band), respectively. Photoluminescence spectrum of the BuO–PPP nanofibril arrays exhibited a blue emission. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 425–430, 2004     

Nanocrystalline CeO2 in SBA-15: Performance of Pt/CeO2/SBA-15 Catalyst for Water-gas-shift Reaction

CeO₂ particles confined within the pores of an SBA-15 mesoporous silica host were prepared by incipient wetness impregnation (IMP) and deposition precipitation (DP) methods. The materials were characterized by XRD, N₂-adsorption and temperature programmed reduction (TPR) to evaluate the structure, texture, and redox properties. The preparation procedure had significant impact on the assembling mode of CeO₂ inside the SBA-15 mesopores. A high dispersion of CeO₂ particles was achieved via DP, whereas the dispersion of CeO₂ prepared by IMP was found to be inhomogeneous and CeO₂ partially blocked the pores. The CO conversion in the water-gas-shift reaction was enhanced over 1 wt% Pt supported on CeO₂-modified SBA-15 obtained by DP.     

计算机远程控制的有关应用分析

通过远程控制软件介绍计算机远程控制的关键技术。在计算机普及速度加快的今天,计算机远程技术得到迅猛发展,研究计算机远程控制的应用,推动其推广和应用。本文论述计算机远程控制的应用,旨在为同行提供一些参考。     

一种基于ZigBee的分布式井盖监控系统

随着我国现代经济发展水平的不断提高,城市井盖数目逐渐增加。由于较多井盖被盗,致使路面形成陷阱,危害到过往车辆和行人安全。本文提出了一种基于ZigBee无线网络的智能安全监控系统,解决分布式布控困难、不能实时监控、成本较高的问题。融合GPRS网络,设计相应的嵌入式网关和Web服务器,实现了对缺失井盖的精确定位、自动报警功能。     

基于WiFi无线通信的温湿度检测节点设计

基于AM2303温湿度传感器、STC15F104W单片机和WiFi模块设计了一种无线温湿度检测节点。介绍了AM2303及其通信协议、WiFi模块及其组网特性等,并且给出了读取AM2303数据的软件流程。经测试,该节点通信距离远,组网灵活,可很好地应用于粮库粮情检测等实际工作环境。     

浅谈海南影视动画产业发展中的政府作为

影视动画产业是当今社会的朝阳产业,是传统经济发展和延伸的一种新方式,政府对影视动画产业十分重视.而影视文化产业具有浓厚文化色彩和广阔的自由发展空间,有利于影视动画的进一步发展与建设.影视动画产业发展对象可以是影视基地,也可以是影视剧本,产业发展对象丰富,所以此产业的发展前景非常明朗,并且还具有高度的研究价值.     

图像增强技术在安防监控系统中的应用

数字化的图像处理技术里面对于各个综合知识的跨度是相当大的,对于各个知识面的要求也是十分高的。那么图像处理技术在实际的生活应用中也是被广泛运用。随着科技时代的到来,人们对于图像的画质要求更高,所以对于图像处理技术的研发已经是整个行业必须解决的问题。那么在这样一个要求越来越高的情形下,在视频监控行业里面图像处理技术起到了那些作用？是怎么样去应用到安防监控行业里面的？本文针对这些问题作出了一些简单的讨论和研究。     

基于商业智能的小区日用水量预测模型研究

商业智能现在已广泛应用于各个领域,利用商业智能可以对趋势预测做出良好的支持,本文将其中一种常用商业智能的工具——数据仓库技术,应用于小区家庭的用水量预测研究。