Chemical structure of heavy oil from coal hydrogenation 1. Hydrogenation with zinc chloride catalyst

Oil product from the hydrogenolysis of a high-volatile bituminous coal was separated by solubility, fractionated by gel permeation chromotography and characterized by structural analysis. The average structural unit in the hexane-soluble, aromatic oil fraction consists of 1–3 aromatic rings with 0.3-0.5 of the ring carbons substituted by alkyl groups and oxygen containing groups. Molecular weights vary from 200 to 500. The larger molecular weight fractions have longer alkyl chains and lower carbon aromaticities. The molecules are mainly of single unit structures. The average structural units in asphaltene fractions contain from 2.5-4 aromatic rings, are of higher carbon aromaticities and contain shorter alkyl groups. The asphaltene molecules consist of two or more structural units, crosslinked together, and have molecular weights of 300–1400. The oxygen content of the fractions decreases with decreasing molecular weight. Increasing the amount of ZnCl₂ catalyst during hydrogenolysis resylts in an increased yield of lower-molecular-weight material, but no change in the structural properties of the product. This is interpreted to mean that ZnCl₂ is active in the scission of covalent bonds between structural units during liquefaction and that the hydrogenolysis reaction is mostly cleavage of crosslinks between structural units with minimal reaction of the units themselves.     

Crystal-structure-controlled tribological behavior ofcarbon-graphite seal materials in partial pressures of helium andhydrogen. I. Specimen characterization and fundamentalconsiderations

Tribology Letters - Three commercially available carbon-graphite cryogenic materials(EC-5, M234 and P5N) that are used as seals in rocket turbopumpassemblies have been characterized as part of a...     

Laparoscopic hernia repair in Leicester General Hospital: a prospective audit of 94 patients

Conventional hernia repair is effective in terms of cure but is associated with considerable postoperative pain and delay in return to normal activity. Laparoscopic repair has the potential to reduce pain and speed return to normal activity, but there have been few published reports of the outcome of this operation in the UK. We present a prospective audit of 94 patients who underwent laparoscopic repair. Of the 94 patients, 87 (92.6%) were male and 7 (7.4%) were female. Thirteen of the repairs were bilateral and 12 were recurrent. Two had to be converted to open repair. The mean operating time for unilateral repair was 56 min and for bilateral repair 98 min. Sixty-three patients (67%) were discharged within 24 h and 21 (22.4%) were discharged within 48 h. There were minor complications in 20 patients (21%), eight of whom (8.5%) developed a haematoma. The other minor complications included seromas (2), bruising at the site of the entry port (2), hyperaesthesia in the groin (2), port hernia (1), shoulder tip pain after surgery (3) and postoperative urinary retention (2). Nine (9.5%) patients claimed to have had no pain or discomfort at all; 35 (37.2%) were pain and discomfort free in 2 weeks. Thirty-two (34%) patients returned to normal activities in 2 weeks. With a median follow-up of 8 months 3 (3.2%) recurrences were noted. It is emphasised that this series represents a learning curve and that the operation is developmental. We are now restricting laparoscopic repair to recurrent and bilateral hernias where the technique offers particular advantages.     

Correlates of physical activity in a national sample of girls and boys in Grades 4 through 12.

Psychological, biological, social, and physical environmental variables were examined for their association with physical activity of young people. A national sample of 1,504 parents and children in Grades 4–12 were interviewed by telephone. Twenty-two potential determinants were assessed along with an 11-item child physical activity index (α?=?.76). Hierarchical multiple regressions were conducted separately for 6 age–sex subgroups. Percentage of variance explained ranged from 18% for boys in Grades 4–6 to 59% for girls in Grades 10–12. Three variables had strong and consistent associations with the child physical activity index that generalized across subgroups: use of afternoon time for sports and physical activity, enjoyment of physical education, and family support for physical activity. These 3 variables should be targeted for change to promote physical activity in all groups of young people. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Relative importance,specific investment and ownership in interorganizational systems

Implementation and maintenance of interorganizational systems (IOS) require investments by all the participating firms. Compared with intraorganizational systems, however, there are additional uncertainties and risks. This is because the benefits of IOS investment depend not only on a firm’s own decisions, but also on those of its business partners. Without appropriate levels of investment by all the firms participating in an IOS, they cannot reap the full benefits. Drawing upon the literature in institutional economics, we examine IOS ownership as a means to induce value-maximizing noncontractible investments. We model the impact of two factors derived from the theory of incomplete contracts and transaction cost economics: relative importance of investments and specificity of investments. We apply the model to a vendor-managed inventory system (VMI) in a supply chain setting. We show that when the specificity of investments is high, this is a more critical determinant of optimal ownership structure than the relative importance of investments. As technologies used in IOS become increasingly redeployable and reusable, and less specific, the relative importance of investments becomes a dominant factor. We also show that the bargaining mechanism—or the agreed upon approach to splitting the incremental payoffs—that is used affects the relationship between these factors in determining the optimal ownership structure of an IOS.

Anionic synthesis of poly(epichlorohydrin-g-styrene) and chemical modification of polyepichlorohydrin

Poly(epichlorohydrin-g-styrene) copolymers, P(ECH-g-S)s, have been prepared in solution by two different methods of coupling polyepichlorohydrin, PECH, with polystyrene, PS, containing a functional end group. In the first method, polystyryl carboxylic acid, PSCOOH, prepared from living polystyrene, was converted to the corresponding potassium salt which was coupled with PECH in dimethyl formamide solution usually at 60°C. In the second method, polystyryl potassium, PS^?K⁺, in tetrahydrofuran solution was end-capped with propylene sulphide to form PSCH₂CH(CH₃)S^?K⁺ which was coupled directly with PECH in tetrahydrofuran at 40°C. Grafting by the first reaction was relatively slow but occurred without significant adverse side reactions. The grafting by the second reaction was relatively fast, but side reactions occurred resulting in a cleavage of the graft copolymer. The graft copolymers were purified by fractional precipitation and extraction procedures and were characterized by infra-red and ultra-violet spectroscopy, microanalysis, gel permeation chromatography, differential scanning calorimetry, solution viscometry, dynamic mechanical testing, and electron microscopy. Solution properties of the graft copolymers in benzene-carbon tetrachloride and toluene-cyclohexane mixtures were studied. There was evidence of micelle formation in dilute solutions of the mixed solvents and microphase separation of components in the solid state. Nucleophilic substitution of chlorine atoms in PECH by phenyl acetate (C₆H₅ CH₂COO-) and thiophenoxide (C₆H₅S-) groups was performed.     

A comparison of screening methods for insect contamination in wheat

In collaboration with the United States Department of Agriculture and a number of major milling companies, the “Insect-Detect” immunoassay for analyzing insect contamination in grains has been compared with three more traditional methods, X-ray analysis, cracking and flotation, and the insect fragment test (IFT). Testing was carried out in blind fashion using clean wheat samples that were spiked with differing numbers of grain kernels infested with late instar larvae of the granary weevil (Sitophilus granarius (L.)). Three different laboratories analyzed the samples for each of the four methods. The collaborative trials showed that the insect immunoassay clearly provided the most accurate measurement of actual insect infestation, followed by X-ray analysis. While both cracking and flotation and IFT procedures provided a general measure of contamination, they showed much greater variability.     

Microstructure/Process Relations in Sol-Gel-Prepared KnbO3 Thin Films on (100) MgO

Epitaxial (110) orthorhombic KNbO₃ thin films were prepared using alkoxide solutions. Single-phase films were produced with stoichiometric sols while slight variations in stoichiometry (52/48 Nb/K or 48/52 Nb/K) created residual second phases. Nucleation and growth of KNbO₃, as a function of process conditions were monitored by observing the KNbO₃ rosettes produced from niobium-rich solutions. Methanolic solutions produced films with the highest rosette density and the highest amount of KNbO₃. Hydrolysis of the sol aided the crystallization of the KNbO₃ phase but also promoted the formation of second phases. Hydrolysis at 0°C reduced second-phase formation.     

Review Article

This paper addresses itself to a problem that faces all cities but which was — and was seen to be — an ever more grave one for the burgeoning cities of nineteenth century Europe: environmental pollution. This problem — and in particular sewage which is the focus of the article — has as yet been little studied by historians. The paper shows, first, that in Paris in the period 1750–1850 the city was confronted by rapidly increasing quantities of sewage and that for complex cultural, class and scientific reasons Parisian elites came to perceive sewage removal as a problem that required solution and to adopt a series of strategies to do so. It shows, secondly, that the city's administration brought about changes which were of greater import than those effected under Haussmann in the 1850s and 1860s. The limits to what it could do were imposed not by short‐sightedness or parsimony, but by long‐term structural constraints of different orders, attitudinal, technological, power relationships in the capitalist city.