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51.
Novel imide-aryl ether benzoxazole copolymers were prepared and their morphology and mechanical properties investigated. A key feature of these copolymers is the incorporation of a benzoxazole moiety by the use of 2,2′-bis[4-(3-aminophenoxy)phenyl]-6,6′-bibenzoxazole or 2,2′-bis[4-(4-aminophenoxy)-phenyl]-6,6′-bibenzoxazole as co-diamines in polyimide syntheses. The preparation of these diamines involved the nucleophilic aromatic substitution of 2,2′-bis(4-fluorophenyl)-6,6′-bibenzoxazole with either 3- or 4-aminophenol in the presence of K2CO3. The diamines were co-reacted with various compositions of pyromellitic dianhydride (PMDA) and 4,4′-oxydianiline (ODA) to synthesize the desired poly(amic acids). Films were cast and cured (350°C) to effect the imide formation, affording films with elongations between 40 and 110% and moduli in the 2000–2750 MPa range. The copolymers exhibited good dimensional (Tg in excess of 300°C) and thermal stability. Wide-angle X-ray diffraction measurements on the copolymers showed that the ordered morphology characteristic of PMDA/ODA polyimide was retained. Improvements in the auto-adhesion were observed, particularly in those copolymers which displayed a Tg. 相似文献
52.
Mesoporous molecular sieve MCM-41 with a Si/Al ratio of 35 was obtained by hydrothermal synthesis using a gel mixture with a molar composition of 6 SiO20.1 Al2O31 hexadecyltrimethylammonium chloride 0.25 dodecyltrimethylammonium bromide 0.25 tetrapropylammonium bromide0.15 (NH4)2O1.5 Na2O300 H2O. The MCM-41 sample was calcined in O2 flow at 813 K and subsequently ion exchanged with Ca2+. A small Pt cluster has been supported on the MCM-41 sample following a procedure using ion exchange of Pt(NH3)
4
2+
. The Pt(NH3)
4
2+
ion supported on MCM-41 has been activated in O2 flow at 593 K and subsequently reduced with Fh flow at 573 K, in the same way used for the preparation of a Pt cluster entrapped inside the supercage of zeolite NaY. The resulting Pt cluster supported on the MCM-41 shows hydrogen chemisorption oftotal two H atoms per Pt at 296 K (based on the total amount of Pt) and high catalytic activity for hydrogenolysis of ethane. The chemical shift in129Xe NMR spectroscopy of adsorbed xenon indicates that the Pt cluster is located inside the mesoporous molecular sieve. 相似文献
53.
Laura M. Russell Lloyd F. Johnson D. P. H. Hasselman Robert Ruh 《Journal of the American Ceramic Society》1987,70(10):226-C
The thermal conductivity and diffusivity of silicon carbide whisker reinforced mullite was shown to increase with whisker content. This effect was much greater for vapor-liquid-solid (VLS) whiskers than for rice-hull (RH) whiskers. This suggests that the thermal conductivity for the VLS whiskers was significantly higher than for the RH whiskers. Due to preferred orientation of the whiskers, thermal conductivity and diffusivity of the composite samples exhibited significant anisotropy. 相似文献
54.
In this article, the effect of fiber dimensional irregularities on the tensile behavior of fiber bundles is modeled with the finite element method. The fiber dimensional irregularities are simulated with sine waves of different magnitudes. The specific‐stress/strain curves of fiber bundles and their constituent single fibers are obtained and compared. The results indicate that fiber diameter irregularity along the fiber length has a significant effect on the tensile behavior of fiber bundles. For a bundle of uniform fibers of different diameters, all the constituent fibers will break simultaneously, regardless of the fiber diameter. Similarly, if fibers within a bundle have the same pattern and level of diameter irregularity along the fiber length, the fibers will break at the same time, also regardless of the difference in the average diameter of each fiber. In these cases, the specific‐stress/strain curve for the bundle overlaps with that of the constituent fibers. When a fiber bundle consists of single fibers with different levels of diameter irregularities, the specific‐stress/strain and load–elongation curves of the fiber bundle have a stepped or ladder shape. The fiber with the highest irregularity breaks first, even when the thinnest section of the fiber is still coarser than the diameter of a very thin but uniform fiber in the bundle. This study suggests that fiber diameter irregularity along the fiber length is a more important factor than the fiber diameter itself in determining the tensile behavior of a fiber bundle consisting of irregular fibers. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2664–2668, 2004 相似文献
55.
56.
G. Oladunni Taylor John J. Albers G. Russell Warnick Janet L. Adolphson H. McFariane D. R. Sullivan C. E. West V. Sri-Hari R. Edwards 《Lipids》1987,22(3):173-177
The high mortality rate from coronary heart disease (CHD) among Indians compared to Negroes in Trinidad led us to test plasma
lipid profiles to see whether dietary or genetic factors might be involved. There were no interracial differences in the composition
of plasma cholesterol ester fatty acids of the tested women and neonates. This finding suggests that dietary fat does not
account for the interracial difference in CHD, nor does the cause appear to be due to genetic differences in lipid profiles,
as there was no significant difference between values for plasma triglycerides, total cholesterol, high density lipoprotein
(HDL) cholesterol, apo-I, apo-II, apo B or cholesterol ester fatty acids in the cord blood of each racial group.
Blood samples were collected from 69 nonpregnant and 71 postpartum, fasted Negro and Indian women. Also taken were 71 umbilical
cord blood samples. The mean triglyceride level was significantly lower in the Negro nonpregnant and postpartum women than
in the Indians. HDL cholesterol and apo-I values were lower in the Indian women. There were no significant differences in
the total cholesterol and apo B measurements. The triglyceride values for postpartum women were higher than those of the nonpregnant
Negroes and Indians (75% and 47%, respectively), whereas the total cholesterol and HDL cholesterol, apo A-I and apo A-II ranged
from 9% to 29% higher in the postpartum women. Apo B was about 40% higher postpartum in both ethnic groups.
The high CHD rate of Indians in Trinidad cannot be explained by dietary factors, plasma total cholesterol or fatty acid composition.
However, the lower level of HDL cholesterol and plasma A-I could play a role in the higher CHD rate in Indians. 相似文献
57.
The photodegradation of polyesters prepared by the reaction of o-phthalic, adipic, and “dimer” acids with ethylene glycol has been studied. The polyesters softened at temperatures in the range of 25–50°C. Polymer films were irradiated in air by means of a medium pressure mercury lamp and the extent of formation of COOH groups determined by infrared spectroscopy. The films were also irradiated in vacuo and in air by means of a high-pressure mercury lamp, and the volatile products, consisting mainly of carbon monoxide and carbon dioxide, were determined by gas chromatography. The results are interpreted in terms of simultaneous Norrish type I and type II decompositions of the polyesters. The type I process accounts for the formation of carbon monoxide and carbon dioxide in the absence of air. The enhanced yield of carbon dioxide in irradiations performed in air is ascribed to the formation of hydroperoxide which undergoes further photolysis. The type II process accounts for the formation of COOH groups. The photodegradation of these glassy polyesters parallels that of crystalline poly(ethylene terephthalate) and is relatively unaffected by changes in composition of the aromatic polyester. 相似文献
58.
Penel Simon; Morrison R.Gwilym; Dobson Paul D.; Mortishire-Smith Russell J.; Doig Andrew J. 《Protein engineering, design & selection : PEDS》2003,16(12):957-961
We analysed the length distributions of different types of ß-strandin a high resolution, non-homologous set of 500 protein structures,finding differences in their mean lengths. Antiparallel edgestrands in strandturnstrand motifs show a preferencefor an even number of residues. This propensity is enhancedif the length is corrected for ß-bulges, which insertan extra residue into the strand. Residues in antiparallel edgeß-strands alternate between being in hydrogen bondedand non-hydrogen bonded rings. Antiparallel edges with an evennumber of residues are more likely to have their final ßresidue in a non-hydrogen bonded ring. This suggests that non-hydrogenbonded rings are intrinsically more stable than hydrogen bondedrings, perhaps because its side chain packing is closer. Therefore,we suggest that a simple way to increase ß-hairpinstability, or the stability of an antiparallel edge strand,is to have a non-hydrogen bonded ring at the end of the strand. Received June 19, 2003; revised October 25, 2003; accepted November 7, 2003 相似文献
59.
Wendy Loyens 《Polymer》2005,46(3):915-928
The present study focuses on the preparation of poly(ethylene oxide) (PEO) nanocomposites based on the synthetic Laponite clay. The clay was added both in its pure form as well as organically modified with low molar mass poly(ethylene glycol) (PEG) components in order to enhance the compatibility between Laponite and PEO. Several PEG's with different end groups were used. Almost all of them were found to intercalate in the clay intergallery spacing. An order of intercalation efficiency could be established. The modified clays displayed a good thermal stability at the nanocomposite processing temperature.The nanocomposites based on the pure Laponite clay as well as the modified clays display an intercalated structure with a modest intergallery spacing. The ion-dipole modification with the PEG's was ineffective in improving the compatibility between PEO and the Laponite silicate layers. Their respective mechanical properties were found to be increased a little, which can be attributed to the low effective aspect ratio of the silicate platelets present in the nanocomposites. This is caused by the low initial aspect ratio of Laponite (w/t=25) and the limited basal spacing increase. The addition of clay does not result in nucleation of the PEO crystallisation. In contrast, the crystallisation was inhibited, resulting in decreased heat of fusions, especially for the pure Laponite nanocomposites. The nanocomposites based on the modified Laponites display a good thermal stability. 相似文献
60.
A crosslink‐able elastomeric polyester urethane (PEU) was blended with a thermoplastic, polyacrylonitrile (PAN), and electrospun into nanofibers. The effects of the PEU/PAN ratio and the crosslinking reaction on the morphology and the tensile properties of the as‐spun fiber mats were investigated. With the same overall polymer concentration (9 wt %), the nanofiber containing higher composition of PEU shows a slight decrease in the average fiber diameter, but the tensile strength, the elongation at break and tensile modulus of the nanofiber mats are all improved. These tensile properties are further enhanced by slight crosslinking of the PEU component within the nanofibers. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献