氯化聚乙烯接枝氯乙烯聚合速率及传热

本文用气相色谱技术研究氯化聚乙烯(CPE)-接枝(g)-氯乙烯(VC)聚合动力学,对不同引发剂体系分析热负荷分布,并对7 m~3聚合釜传热面进行校核。     

Isotopic Oxygen Exchange and EPR Studies of Superoxide Species on the SrF2/La2O3 Catalyst

By using the in situ IR spectroscopy, the superoxide species (O₂⁻), characterized by the O–O stretching peak at 1130 cm⁻¹, was detected on the SrF₂/La₂O₃ catalyst at temperatures up to 973 K. The introduction of ¹⁸O₂ isotope caused the 1130 cm⁻¹ peak to shift to lower wavenumbers (1095 and 1064 cm⁻¹), consistent with the assignment of the spectra to the superoxide species. A good correlation between the rate of the disappearance of the O₂⁻ species and that of the formation of C₂H₄ was observed, suggesting that O₂⁻ was the active oxygen species responsible for the oxidative coupling of methane (OCM) on the SrF₂/La₂O₃ catalyst. This conclusion was reinforced by the EPR experiments (g_xx = 2.0001, g_yy = 2.0045, g_zz = 2.0685), showing that O₂⁻ was the only paramagnetic oxygen species detectable on the O₂-preadsorbed SrF₂/La₂O₃ catalyst. These results suggest that superoxide O₂⁻ can be a stable active oxygen species, whose role in the OCM reaction cannot be overlooked.     

Synthesis and characterization of poly(butyl acrylate)/silica and poly(butyl acrylate)/silica/poly(methyl methacrylate) composite particles

Poly(butyl acrylate)/poly(methyl methacrylate) (PBA/PMMA) core–shell particles embedded with nanometer‐sized silica particles were prepared by emulsion polymerization of butyl acrylate (BA) in the presence of silica particles preabsorbed with 2,2′‐azobis(2‐amidinopropane)dihydrochloride (AIBA) initiator and subsequent MMA emulsion polymerization in the presence of PBA/silica composite particles. The morphologies of the resulting PBA/silica and PBA/silica/PMMA composite particles were characterized, which showed that AIBA could be absorbed effectively onto silica particles when the pH of the dispersion medium was greater than the isoelectric potential point of silica. The critical amount of AIBA added to have stable dispersion of silica particles increased as the pH of the dispersion medium increased. PBA/silica composite particles prepared by in situ emulsion polymerization using silica preabsorbed with AIBA showed higher silica absorption efficiency than did the PBA/silica composite particles prepared by direct mixing of PBA latex and silica dispersion or by emulsion polymerization in which AIBA was added after the mixing of BA and silica. The PBA/silica composite particles exhibited a raspberrylike morphology, with silica particles “adhered” to the surfaces of the PBA particles, whereas the PBA/silica/PMMA composite latex particles exhibited a sandwich morphology, with silica particles mainly at the interface between the PBA core and the PMMA shell. Subsequently, the PBA/silica/PMMA composite latex obtained had a narrow particle size distribution and good dispersion stability. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3425–3432, 2006     

A social recommendation method based on opinion leaders

With the rapid development of information technology, social media has been widely used, and Internet information has been exploded, and consumers may experience information overload. Recommender systems using the social recommendation method that integrates social relationship information can provide users with target information that meets their needs. However, most of the existing methods only rely on the user’s ordinary friends to make recommendations, neglecting another influential group, the opinion leaders. In this study, we propose a new social recommendation method based on opinion leaders. The proposed method assumes that the influence of the opinion leader on the user is much greater than that of the user’s ordinary friends. The experimental results on two real datasets show that the proposed method not only has a better recommendation effect than the state-of-the-art recommendation algorithms, but also has a good performance in the cases of cold-start users.

     

Effect of special structure of clam shell powder on structure and properties of castor oil-based composites

Castor oil (CO) is an environmentally friendly renewable green resource and ideal alternative to petroleum resources. The preparation of high strength and high toughness castor oil-based polyurethane prepolymer (COPU) composites has significant applications such as supporting material and engineering plastic sheet. In this study, unmodified clam shell powder (CSP) with a unique CaCO₃-proteoglycan structure was used as a filler to prepare compatible reinforced COPU composite materials. Investigation of the mechanical properties revealed that the elastic modulus of the composite COPU reinforced with 50 wt% of CSP had increased to 5859.0 ± 8.4 MPa representing 187.77% to obtain stiffer and stronger material over pure COPU (2036.6 ± 196.9 MPa). Moreover, the scanning electron microscopy, thermogravimetric analysis and contact angle results demonstrated that the reinforced COPU composites have better compatibility, thermal stability, and water resistance than pure COPU. This work will promote the application prospects of CO-based polyurethane.     

压力加工机械载荷与轴温的监测

分析了压力加工载荷和轴温监测的基本要求，介绍了载荷和轴温测量的原理与技术，说明了监测方案的设计及实施方法。     

金属蜂窝负载Pd催化甲烷部分氧化制合成气

采用浸渍法制备负载金属Pd(其中金属Pd含量0.6g/L)活性组分的金属蜂窝载体催化剂,应用于甲烷部分氧化制合成气。实验表明,焙烧温度为950℃的催化剂较600℃的催化剂甲烷转化率、CO和H2的选择性更高,焙烧温度为950℃的催化剂在反应温度800℃,GHSV=1×105ml/g·h条件下,甲烷转化率为91%,CO和H2的选择性分别达到90%和89%。用SEM与XPS对催化剂进行表征,结果表明,950℃焙烧催化剂并没有出现明显的烧结现象,且可能由于更多零价Pd的出现,使得该催化剂的性能更好。由于金属蜂窝载体优良的导热性,对950℃焙烧温度制备的金属蜂窝催化剂,催化剂床层的飞温点温度小于880℃,可以解决其它类型催化剂在甲烷部分氧化反应中出现的飞温问题,具有一定的工业化意义。     

Hydraulic erosion of concrete by a submerged jet

The hydraulic erosion of concrete is often found in civil and marine engineering construction. The present study explores the effects of several erosion parameters on the material loss of a concrete specimen subject to the hydraulic flow produced by a submerged jet. Such an investigation has rarely been reported in the literature. The concrete specimen has a typical compressive strength of 35 MPa, and the experimental parameters include the exposure time, incidence angle, standoff distance, and the hydraulic jet pressure. The impinging velocity is estimated based on the distance considered in the round jet model. The regression analysis shows the relationship between each parameter and the material loss. One finds that the material loss is proportional to the exposure time and the hydraulic pressure. The maximum erosion lies at an incidence angle of around 30° to 45° and is affected by the fourth-order polynomial of impinging velocity. The result of the present study provides a reference to engineering practice where concrete erosion is a concern.     

盖下坝水电站坝址区岩溶发育情况初步分析

盖下坝水电站工程为高山峡谷型电站,坝址区及附近岩石为碳酸盐岩,属中等坚硬易溶岩.岩溶发育是影响本工程库水外渗的重大工程地质问题之一.从施工开挖揭示的各种溶蚀现象中分析岩溶发育特征及其规律,为防渗设计提供依据.     

一种面向中小企业PDM系统的设计与实现

根据中小企业在信息化建设中对于产品数据管理的实际需求,针对某一具体行业设计了一个适合中小企业的产品数据管理系统。分析系统的开发平台和采用基于．Net框架下采用B／S模式的系统结构,阐述系统具有的图档管理、产品结构和配置管理、项目管理和安全管理等主要功能。应用结果表明,该系统能有效地提高企业对产品数据管理的效率。