固载杂多酸催化剂气相催化合成乙酸丁酯的研究

在气固相反应体系中研究了酸处理膨润士固载的具有 Keggin结构的四种杂多酸在乙酸丁酯合成中的催化性能。实验结果表明 :同一载体负载不同杂多酸催化活性相似 ;不同载体负载的同一种杂多酸的催化活性与催化剂的表面酸性呈顺变关系。同时考察了反应温度 ,空速 ,酸 /醇比对催化活性的影响。在酸 /醇比为 1 ,温度为 1 2 0℃ ,空速为 3～ 5h- 1时 ,正丁醇和乙酸有较高的转化率 ,选择性接近 1 0 0 %。     

残余应力对55SiMnVB弹簧钢疲劳性能的影响

研究了５５ＳｉＭｎＶＢ弹簧钢板疲劳断口特征及裂扩展过程。结果表明，喷丸强化在表层产生的残余压应力可明显提高疲劳抗力，增强裂纹闭合效应，降低裂纹扩展速度。     

智能测温仪表的研究与实现

文章介绍了一种以8098单片机为核心、以铂铑一铂为测温元件研制的智能化测温仪表，它与传统的接触式温度传感器相比具有价格低、性能高、应用范围广、人机界面好等特点。     

Using a Three-Phase Deterministic Model for the Columnar-to-Equiaxed Transition

In order to overcome the limitations of previous columnar-to-equiaxed (CET) models, which neglect melt convection and the movement of free equiaxed grains, this article presents a three-phase deterministic CET model. With appropriated multiphase volume-averaging approaches, it is possible to account for nucleation and growth of equiaxed grains ahead of a growing columnar front, the influence of melt convection, and grain sedimentation, and the occurrence of a CET in a casting of engineering scale. Special modeling assumptions ensure that both CET mechanisms, namely, “hard” and “soft” blocking, are tackled. It is highly recommended that both mechanisms should be considered, especially in the situation where grain sedimentation and melt convection are present. Although the current model incorporates almost all the physical variables relevant to a CET event, under special condition of a one-dimensional case, the model still reproduces the results of Hunt’s classical CET approach. This article is based on a presentation made in the symposium entitled “Solidification Modeling and Microstructure Formation: In Honor of Prof. John Hunt,” which occurred March 13–15, 2006, during the TMS Spring Meeting in San Antonio, Texas, under the auspices of the TMS Materials Processing and Manufacturing Division, Solidification Committee.     

房地产开发企业会计核算问题探讨

本文就房地产开发企业会计核算的现状及特点进行了分析,并提出了完善房地产开发企业会计核算规范的对策。     

Analysis of dinosaur samples by nuclear microscopy

Several dinosaur bone and eggshell fossil samples unearthed at different sites in China were analyzed by means of nuclear microscopy. Concentrations and distributions of elements such as Na, Mg, Al, P, S, Ca, Cr, Mn, Fe, Cu, Zn, As, Br, Sr, Y, Ce, Pb and U, etc. were obtained for each sample. The results of quantitative PIXE and RBS analyses show unusually high concentrations of U and Ce in several samples obtained from a period near the K-T boundary (between Cretaceous and Tertiary periods, 65 million years ago), suggesting that some form of environmental pollution could be the cause of dinosaur extinction.     

透水性沥青面层材料设计新法及应用

本文提出了一种根据主骨料空隙率设计透水性面层沥青混合料级配的新方法，根据这一方法设计的透水性沥青面层具有良好的路面使用功能，应用前景广阔。     

The relations of impregnated cathode properties to the tungsten matrix structure

Some data of emission and evaporation properties related to tungsten matrix structures of the impregnated cathodes are analyzed. The results indicate that the particle size of tungsten powder and the pore size in the porous matrix determine the total inside surface area of all pores, the diffusion length of barium atoms over tungsten grain surfaces, and the diameter and length of the path through which barium atoms are transported. These factors all relate to the properties and operation mechanism of an impregnated cathode; therefore, it would not be strictly correct to use only the matrix porosity for characterizing the cathode properties. Finally, the preferred structures of porous tungsten matrix depending on different applications of impregnated, cathodes are proposed.