Ring‐opening polymerization of D,L‐lactide by rare earth 2,6‐dimethylaryloxide

Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)₃) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)₃ exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 10⁴ g mol^?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)₃ has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)₃ is 69.6 kJ mol^?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry     

Face recognition using elastic local reconstruction based on a single face image

In this paper, we propose a new face recognition algorithm based on a single frontal-view image for each face subject, which considers the effect of the face manifold structure. To compare two near-frontal face images, each face is considered a combination of a sequence of local image blocks. Each of the image blocks of one image can be reconstructed according to the corresponding local image block of the other face image. Then an elastic local reconstruction (ELR) method is proposed to measure the similarities between the image block pairs in order to measure the difference between the two face images. Our algorithm not only benefits from the face manifold structure, in terms of being robust to various image variations, but also is computationally simple because there is no need to build the face manifold. We evaluate the performance of our proposed face recognition algorithm with the use of different databases, which are produced under various conditions, e.g. lightings, expressions, perspectives, with/without glasses and occlusions. Consistent and promising experimental results were obtained, which show that our algorithm can greatly improve the recognition rates under all the different conditions.     

Average consensus in networks of dynamic agents with switching topologies and multiple time-varying delays

In this paper, we discuss average consensus problem in undirected networks of dynamic agents with fixed and switching topologies as well as multiple time-varying communication delays. By employing a linear matrix inequality method, we prove that all the nodes in the network achieve average consensus asymptotically for appropriate communication delays if the network topology is connected. Particularly, several feasible linear matrix inequalities are established to determine the maximal allowable upper bound of time-varying communication delays. Numerical examples are given to demonstrate the effectiveness and the sharpness of the theoretical results.     

Investigation of Mechanical and Electrical Characteristics for Cracked Conductive Particle in Anisotropic Conductive Adhesive (ACA) Assembly

In an anisotropic conductive adhesive (ACA) assembly, the electrical conduction is usually achieved with the conductive particles between the bumps of integrated circuit (IC) and corresponding conductive tracks on the glass substrate. Fully understanding of the mechanical and electrical characteristics of ACA particles can help to optimize the assembly process and improve the reliability of ACA interconnection. Most conductive particles used in the ACA assembly are with cracks in the metal coating of the particles after the ACA bonding. This paper introduced the fracture analysis by applying the cohesive elements in the numerical model of the nickel-coated polymer particle and further simulating the cracks initiation and propagation in the nickel coating during the ACA bonding. The simulation results showed that the stress distribution on the nickel-coated particle with cracks was significantly different from that on the nickel-coated particle without crack, indicating that the stress analysis by taking the crack into consideration is very important for the reliability assessment of the ACA interconnection. The stress analysis of cohesive elements indicated that the cracks initiated at the central area of the nickel coating and propagated to the polar area. Furthermore, by the introduction of a new parameter of the virtual resistance, a mathematical model was established to describe the electrical characteristics of the nickel-coated particle with cracks. The particle resistance of the nickel-coated particle with cracks was found to be much higher than that of the particle without crack in the optimized bonding pressure range, indicating that it is necessary to take the crack into consideration for the particle conduction analysis as well. Therefore, the fracture analysis on the conductive particle by taking the crack into consideration could accurately evaluate the reliability of ACA interconnection and avoid serious reliability issues.     

镁钴铝类水滑石催化合成安息香甲醚

采用共沉淀法制备了镁钴铝类水滑石化合物(MgCoAl-HTLcs),并用 X 射线衍射、扫描电子显微镜、NH_3程序升温脱附等方法对 MgCoAl-HTLcs 进行了表征,并以 MgCoAl-HTLcs 为催化剂催化苯甲醛与甲醇反应合成安息香甲醚,研究了n(Mg):n(Co):n(Al)、催化剂用量、原料配比、反应温度、反应时间对合成反应的影响。表征结果显示,MgCoAl-HTLcs 的晶相完整,表面主要为弱酸、弱碱性。催化合成安息香甲醚的适宜条件为:MgCoAl-HTLcs 催化剂用量0.10 g(约为原料总质量的0.23%),n(Mg):n(Co):n(Al)=0.4:1.6:1.0,V(苯甲醛):V(甲醇)=3:50,反应温度50℃,反应时间150 min。在此条件下,苯甲醛的平衡转化率达77.49%,安息香甲醚选择性接近100%。为洁净合成安息香甲醚开辟了一条新的途径。     

炼铁生产环境负荷分析和预测研究

利用寿命周期评价的思想，计算了炼铁生产过程中的环境负荷，并分析了各因素对环境负荷的影响，运用神经网络对炼铁生产过程环境负荷进行了预测。     

日本落叶松及其在造纸领域中的应用

日本落叶松是适合在北半球广泛种植的早期速生树种 ,在我国的生长适应范围比较广 ,如今在我国华北、西北、西南和华中亚热带山区的部分地区已有种植。它在造纸领域中的应用研究已经开始 ,而且已经证实是一种很有潜力的造纸木材     

负温度系数传感器特性检测系统设计

负温度系数(NTC)传感器是一种阻值随温度升高而降低的热敏电阻,广泛应用于家用电器的测控系统中.鉴于不同NTC元件的温度-电阻特性一致性较差,给批量家用电器产品的调试带来不便.因此,NTC特性的自动测量和筛选是十分重要的.文中介绍了一种新型的NTC热敏电阻特性检测系统,阐述了该系统的检测原理和硬件组成,给出了系统的硬件框图和软件流程.该系统实现了NTC传感器温度特性的自动测量和筛选,方便了整机装配前对使用的NTC传感器温度特性的检测,降低了后道工序的调整难度,节省了工时.     

GPRS业务模型和无线网络的研究

根据GPRS业务及业务发展情况，对GPRS业务模型进行深入研究，并对GPRS无线网络进行了更深入的探讨。