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901.
Peng Jiang Liuyu Yang Yongle Sun Dingjun Li Tiejun Wang 《Journal of the American Ceramic Society》2021,104(3):1455-1464
Premature spallation of thermal barrier coatings (TBCs) is a critical issue during the service of gas turbines, and nondestructive evaluation is crucial to address this problem. Herein, a novel approach that indicates delamination by measuring the residual stress evolution of thermally grown oxide (TGO) for air plasma spraying (APS) TBCs is proposed and verified via the combination of photoluminescence piezo-spectroscopy (PLPS) and X-ray computed tomography. A mineral-oil-impregnating approach and a cold-mount low-shrinkage epoxy-mounting approach are used to alleviate the signal attenuation by pores and microcracks in APS TBCs, improving the detectable PLPS signal and X-ray transmission for stress measurement and delamination characterization, respectively. We have nondestructively measured the TGO residual stress mapping in APS TBCs and its evolution with oxidation. Furthermore, the evolution of TGO morphology and critical microcracks are obtained by X-ray computed tomography. The synchronous evolution of TGO residual stress, TGO thickness, and critical microcracks as a function of oxidation time is obtained and correlated. The transition point, as experimentally identified, at which the TGO stress starts to drop, agrees well with the critical moment of microcrack coalescence. This directly verifies that the TBC delamination can be effectively indicated by residual stress evolution of TGO in APS TBCs. 相似文献
902.
Xiaoying Li Qiang Liu Xin Liu Danyang Zhu Dianjun Hu Feng Tian Lexiang Wu Zhaoxiang Yang Tengfei Xie Haohong Chen Jiang Li 《Journal of the American Ceramic Society》2021,104(5):2116-2124
Transparent terbium aluminum garnet (TAG) ceramics were achieved by the vacuum sintering plus HIP post-treating from the coprecipitated TAG nanoparticles. The influences of vacuum sintering temperature and sintering aid TEOS on the optical quality of the TAG ceramics were studied. The results show that with the increase of sintering temperature, the optical quality of TAG ceramics is improved gradually, and the in-line transmittance of the TAG ceramics treated at 1720°C for 20 hours under vacuum and then HIP post-treated at 1700°C for 3 hours under 200 MPa argon gas is 81.6% at 1064 nm. The sintering additive TEOS can improve the optical quality of TAG ceramics and inhibit the valence state change of Tb3+ ions to Tb4+ during the annealing process. The Verdet constant of the TAG ceramics at 632.8 nm is about −178 rad·T−1·m−1 at room temperature, which is 1.3 times that of the commercial TGG crystals (−134 rad·T−1·m−1). 相似文献
903.
Junhang Tian Weidong Zhuang Ronghui Liu Yuanhong Liu Guantong Chen Siwei Chen Ze Jiang 《Journal of the American Ceramic Society》2021,104(8):4014-4023
The Eu2+-activated nitride phosphors have been widely used in solid-state lighting, but the applications in high-power white-light-emitting diodes (wLEDs) field require higher thermal stability of luminescent materials. The oxidation of Eu2+ and the damage of nitride host in the Eu2+-activated nitride phosphors are the two crucial reasons for the luminescence loss while operating. A superficial organic carbon modification is performed on the red-emitting (Sr,Ca)AlSiN3:Eu2+ phosphor via the incorporation of organic carbon by solution mixing and thermal post-treatment under the N2-H2 atmosphere. After the superficial organic carbon modification, the oxidation of Eu2+ and the formation of impurity phases on the phosphor surface are effectively reduced. When the superficial organic carbon modified sample was treated in the 2 wt.% sucrose solutions, the relative brightness is strengthened by 2.15%, the thermal quenching characteristic is improved by 8.9% at 300℃, and the aging test results show an excellent thermal stability. All above indicate that the superficial organic carbon modification is a promising technique to enhance the thermal stability of analogous Eu2+-activated nirtide phosphors. 相似文献
904.
Cheng Jiaqi Gong Junyi Yue Shuai Jiang Yao Hou Xiangjun Ma Jianjun Yao Yali Jiang Cairong 《Journal of Applied Electrochemistry》2021,51(8):1175-1188
Journal of Applied Electrochemistry - La-doped titanate materials have been widely investigated as alternative Ni-free anodes for solid oxide fuel cells (SOFCs). In this study, La0.4Sr0.6TiO3 (LST)... 相似文献
905.
Wenyan Jiang Yihao Xing Linye Zhang Xiaoming Guo Yiwen Lu Mei Yang Jing Wang Guangtao Wei 《应用聚合物科学杂志》2021,138(7):49830
Polyethylenimine-modified sugarcane bagasse cellulose (SBCMP), as a new adsorbent, was synthesized by the reaction of polyethylenimine (PEI) with sugarcane bagasse cellulose and glutaraldehyde. The adsorption of Cu(II) by SBCMP was pH-dependent, and the higher removal efficiency of Cu(II) appeared in the range of pH 3.0–6.0. The adsorption isothermal data fitted well with the Langmuir model, and the maximum adsorption capacity of SBCMP was up to 107.5 mg/g. The adsorption kinetics was best described by the pseudo-second-order kinetic. The adsorption of Cu(II) by SBCMP was unfavorable at high temperatures, and thermodynamic analyses implied that the adsorption of Cu(II) by SBCMP was an exothermic reaction. Fourier transform infrared spectroscopy (FT-IR) combined with X-ray photoelectron spectroscopy (XPS) revealed that Cu(II) adsorption on SBCMP mainly controlled by the nitrogen atoms of NH group in PEI. The results of regeneration cycles showed that SBCMP was suitable for reuse in the adsorption of Cu(II) from aqueous solution. These experimental results suggested that SBCMP is expected to be a new biomass adsorbent with high efficiency in removing Cu(II) from wastewater. 相似文献
906.
Boqiong Xue Yuchun Li Jia Guo Jun Sun Xiaodong Liu Hongfei Li Xiaoyu Gu Sheng Zhang Shengling Jiang Zhiyuan Zhang 《应用聚合物科学杂志》2021,138(11):50015
In order to improve the flame retardancy and antistatic properties of polyamide 6 (PA6) at as low amount of additives as possible, an integrated-functional additive was synthesized by 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and multiwalled carbon nanotubes (MWCNTs). The results showed 2 wt% of DOPO-MWCNTs distributed in PA6 formed an electric network and decreased volume resistivity sharply to 3.1 × 108 Ω cm. In other words, it helped PA6 to get to the percolation threshold of semiconductor. By using of 3 wt% DOPO-MWCNTs, the severe dripping in burning of PA6 was almost controlled. The possible reason was also ascribed to the network formed by evenly dispersed DOPO-MWCNTs, which strengthened the char structure and held severe dripping of PA6. As a result, the heat and smoke release were also suppressed obviously. The most important is that CO release was about half cut in CONE test. 相似文献
907.
A core-shell modifier with the cross-linked acrylate and silicone copolymer as the core and polymethyl methacrylate (PMMA) as the shell (PASi-g-PMMA) was used to toughen the brittle polylactide (PLA). In addition, the copolymer of methyl methacrylate (MMA) and glycidyl methacrylate (GMA) (MG) was utilized to further enhance the modification efficiency of the PASi-g-PMMA. The MG copolymer played the double roles of compatibilizer and chain extender, which not only improved the interfacial adhesion between the PLA and PASi-g-PMMA particles, but also increased the molecular weight and chain entanglement of the PLA. Compared with the PASi-g-PMMA toughened PLA blend, the PLA/PASi-g-PMMA/MG blends showed much higher heat-resistance, melt strength, transparency, toughness and stiffness balance. When the PASi-g-PMMA content was 20 wt%, 20 wt% MG increased the glass transition temperature (Tg), complex viscosity (η*), transparency, impact and tensile strength of PLA/PASi-g-PMMA blend from 60.1°C, 1.9 × 103 Pa·s, 76.1%, 748 J/m and 37 MPa to 71.5°C, 0.5 × 104 Pa·s, 78.4%, 860 J/m and 45 MPa for the PLA/PASi-g-PMMA/MG blend. This research provided a facile and practical method to overcome the shortcomings of the PLA and promoted its application in broader fields. 相似文献
908.
The flame retardant polypropylene containing the micro-envelope core-shell structure flame retardant, which encapsulated ammonium polyphosphate into melamine-formaldehyde resin and sodium silicate through in situ polymerization was prepared with polyamide 6, added as a carbon-forming agent. The composition of ammonium polyphosphate, encapsulated ammonium polyphosphate with melamine-formaldehyde resin and the micro-envelope core-shell structure flame retardant were characterized. The fire safety and thermal stability were investigated and showed an improvement including limiting oxygen index, thermogravimetric analysis, vertical burning tests, and microscale combustion calorimeter. The burned compounds were also studied to confirm the burning mechanism. The results showed the flame retardant performance had been greatly improved, while polyamide 6 had better char-forming effect. Besides, the water solubility of flame retardants and their influence on the mechanical properties of polypropylene were also investigated. The results on the effects of additives demonstrated a high efficiency flame retardant to polypropylene. A core-shell flame retardant that sodium silicate and melamine-formaldehyde resin-coated ammonium polyphosphate had been constructed. The effect of the built flame retardant system on the combustion performance of polypropylene was studied from the mechanism and performance. The LOI of the most flame retardant polypropylene reached 28.6%, and UL-94 reached the V-0 level. 相似文献
909.
A semi-interpenetrating polymer network superabsorbent polymer based on sodium lignosulfonate-graft-poly(acrylic acid-acrylamide)/potassium dihydrogen phosphate and polyvinyl alcohol (PVA/SL-g-P[AA-AM]/KDP) was synthesized by using solution polymerization. The PVA/SL-g-P(AA-AM)/KDP was further hydrolyzed in NaOH solution. The structure, thermal stability, and morphologies of samples were examined by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The results of FTIR, TGA, and DSC showed that PVA interpenetration through SL-g-P(AA-AM)/KDP network has occurred, and PVA/SL-g-P(AA-AM)/KDP was successfully alkaline hydrolyzed. From the SEM images, the high porous and loose surface structure of polymers was formed after hydrolysis, which greatly increased the specific surface area. Samples after hydrolysis exhibited higher equilibrium swelling capacity (1963 g/g) compared to the nonhydrolyzed samples (866 g/g). The swelling kinetics of all samples well complied with the pseudo-second order swelling kinetics model. Simple hydrolysis treatment not only improved the swelling capacity of PVA/SL-g-P(AA-AM)/KDP but also induced an enhancement on its water retention performance, which made it potentially useful as a water retention agent in the revegetation of abandoned mines or slope wasteland. 相似文献
910.
该文研究了中频400~800Hz条件下纵磁真空灭弧室内的磁场特性,利用Ansys Maxwell求解了三维瞬态纵向磁场分布.由计算结果可知:在电流变化的过程中,中心区域纵向磁场的变化明显滞后于其他区域.电流峰值时在触头片开槽交错放置的位置有磁场峰值区域,电流过零时中心区域有明显剩磁.当频率增加时,涡流效应更明显,使纵向磁场的磁感应强度值减弱.对中心点,频率提高导致过零时剩磁增加,磁场滞后相位更明显,影响电弧扩散.增加触头片开槽数可以减弱涡流效应,而增加触头杯座槽旋转角,触头中间平面磁感应强度的最大值近似线性增加.文中通过分析电弧形态和电压等实验结果验证了磁场滞后对真空灭弧室的开断能力的影响. 相似文献