金属/聚合物复合材料对中能电子的屏蔽作用研究

运用MULASSIS计算程序模拟计算了不同组成的屏蔽材料对空间辐射环境的屏蔽效果,在此基础上进行屏蔽材料的初步设计,并制备了一系列不同组成的金属/聚合物复合材料,结合中能电子照射的实验结果,讨论了组成对金属/聚合物复合材料的屏蔽效果的影响.研究发现,高原子序数和低原子序数金属混合添加的复合物样品具有较好的屏蔽效果.     

酚醛树脂在油田化学领域的应用

对酚醛树脂及其改性产品在油田化学领域的应用动态作了初步探讨,分别介绍了磺化酚醛树脂及其改性产品在钻井液中的应用情况,以及酚醛树脂及其改性产品在采油、修井、堵漏、破乳、固井、压裂液和防腐等作业中的应用情况.探讨了SMP的作用机理.     

（1S，2S，5R）-薄荷基取代烯烃的合成

以(L)-薄荷基氯为原料,通过薄荷基氯化镁分别与烯丙基溴、2-甲基-3-氯丙烯、1-溴-3-甲基-2-丁烯在Cul催化下发生偶联反应,首次合成了3-(1S,2S,5R)-薄荷基-1-丙烯,2-甲基-3-(1S,2S,5R)-薄荷基-1-丙烯和2-甲基-4-(1S,2S,5R)-薄荷基-2-丁烯,总收率分别为80.5%、83.1%和79.6%.探讨了影响反应的多种因素,找到了较好的合成条件,并用IR、 1HNMR和元素分析对产物进行了表征.     

La doping effects on intergrowth Bi2WO6–Bi3TiNbO9 ferroelectrics

La doping effects on intergrowth Bi₂WO₆–Bi₃TiNbO₉ ferroelectric ceramics were studied by X-ray diffraction, electron probe microanalysis and dielectric spectroscopy. It was found that the La³⁺ distribution, ferroelectric phase transition and dielectric relaxation behavior are apparently affected by La doping. With increasing La³⁺ content, the site of dopant ion varies, the grain growth of Bi₅TiNbWO₁₅ is restrained, the Curie temperature is reduced and broadened. Furthermore, two dielectric relaxation loss peaks were observed both in temperature and frequency spectra. The calculated relaxation parameters revealed the oxygen vacancy related to the relaxation process.     

氧化铝厂渣浆泵机械密封的失效形式及改进措施

本文介绍了渣浆泵机械密封的失效形式,并根据长期现场工作经验,分析了机械密封泄漏的主要原因,据此提出了改进措施,通过对动静环密封面倒角,改变密封面尺寸及载荷系数后有效地解决了由于径向跳动过大而引起的密封面刮碰擦裂的失效问题。     

炼钢厂脱硫倾翻车液压系统的改造

脱硫倾翻车是炼钢厂80T炉区脱硫站的重要设备,通过它的倾翻,扒渣机的扒渣等工艺降低了钢中的含硫量,提高了钢的品质,为宣钢的品种钢开发打下坚实的基础.     

高炉冷却壁失效原因研究

本文针对安钢高炉冷却壁破损的形式、原因进行研究分析,探讨了冷却壁的结构、材质、加工与安装工艺对其寿命的影响。介绍了安钢高炉炉役后期冷却壁的维护生产实践。     

The thermal behavior of mechanically activated galena by thermogravimetry analysis

The thermal decompositions of mechanically activated and nonactivated galenas were studied by thermogravimetry analysis (TGA) at the heating rate of 10 K min⁻¹ in argon. Results indicate that the initial temperature of thermal decomposition (abbreviated as T _di) in the TGA curves for different galenas decreases gradually with increased grinding time. The specific granulometric surface area (S _G), the structural disorder, and the content of elemental sulfur of mechanically activated galenas were analyzed by an X-ray diffraction (XRD) laser particle-size analyzer, XRD analysis, and the gravimetric method, respectively, which shows that the specific granulometric surface area of mechanically activated galenas remains almost constant after a certain grinding time, but the lattice distortions (ε) rise, the crystallite sizes (D) decrease, and the elemental sulfur contents of mechanically activated galenas increase with increased grinding time. The results imply that the decrease of the initial temperature of thermal decomposition in the TGA curves for mechanically activated galenas is mainly caused by the increase of lattice distortions, and the formation of new dangling bonds resulted from the production of elemental sulfur of mechanically activated galenas with increased grinding time. Finally, the differences in the thermal-decomposition reactivity between nonactivated and mechanically activated galenas were also discussed.     

M8011H16铝合金防盗盖板生产工艺研究

研究了元素含量变化对8011铝合金防盗盖板综合性能的影响，在8011合金中改变Cu、Mn元素含量后可提高防盗盖板的强度，同时研究了烘烤处理后的强度变化问题。本文研究出了8011铝合金防盗盖板新的生产工艺制度。     

利用大港羊三木低硫环烷基原油生产45#变压器油

1　前言变压器油作为影响变压器输电性能好坏的重要因素,它质量性能的好坏,直接决定着电力工业能否顺利运行及运行效率的高低。因此,生产高性能的变压器油,满足电力行业的需要,也是炼油企业的重要任务。中国石油大港石化分公司(以下简称大港石化)利用羊三木低硫环烷基原油生产的45#变压器油具有良好化学稳定性和抗氧化安定性性能,且不易裂化,不产生积炭,具有良好的电性能和导热性以及与其它绝缘材料的适应性。2　45#变压器油的生产45#变压器油的工序生产流程为:常压蒸馏→加氢精制→糠醛精制→白土精制→加剂调合→产品。2.1　常压蒸馏装置…