Oxidation behavior and mechanism of aluminum oxynitride (AlON) at elevated temperatures

The oxidation behavior and mechanism of aluminum oxynitride (AlON) powder exposed to air at elevated temperatures between 800°C and 1300°C was investigated by X-ray diffractometry (XRD), scanning electron microscope (SEM), electron spin resonance (ESR), nuclear magnetic resonance (NMR), and simultaneous thermogravimetry, differential thermal analysis, and mass spectrometry techniques (TG-DTA-MS). The weight of AlON gradually increases to a maximum value at 1150°C and then decreases with further heating. Meanwhile, AlON powder undergoes chemical changes, as evidenced by lattice expansion, and turns eventually into alumina. ESR spectra reveal the occurrence of lone pair electrons in the oxidized products and the intensity of corresponding resonance signal increases before disappearing with the increase in temperature. Combined with the results of NMR and TG-DTA-MS, the measured data suggest that Al-N in [AlO₃N] tetrahedron and [AlO₅N] octahedron are gradually oxidized into Al-O-N group with lone pair electrons, which causes continuous weight gain and lattice expansion. Further oxidation at higher temperatures results in alumina and N₂.     

AN APPROACH TO THE ACTIVATION PROCESS OF LaNi_5

本文研究了LaNi_5在不同温度和压力下的活化过程。结果表明,LaNi_5的活化可分为三个阶段,即孕育期;吸氢速度随时间增加而增加的第一阶段和吸氢速度随时间增加而减少的第二阶段。讨论了每一阶段的特征,并给出了吸氢速度的近似表达式。     

中厚板轧机工作辊失效分析及对策

介绍了济钢中厚板厂使用国外高镍铬和高铬工作辊的主要失效形式 ,并对该工作辊的断裂和裂纹产生原因进行了分析 ,同时针对所存在的问题提出了对策和具体改进措施。     

铜金粉的颜色及其影响因素

利用分光光度计对国内外铜金粉的颜色进行了测试，研究了铜金粉的成分、微观状态对颜色的影响。结果表明：铜金粉颜色可以用色彩三要素进行描述，其中铜金粉的色相只与合金成分有关，而与铜金粉片的大小、形状及粒度分布无关；明度和纯度与铜金粉片在油墨层中定向排列状态、片的大小、形状及粒度分布有关，而与成分无关；合金成分的微小波动不会引起铜金粉色相的明显改变。     

基于Excel VBA的职称评审专家抽取系统的设计与实现

通过对职称评定过程中专家抽取流程和原则的分析,针对人工抽取的弊端,使用Excel及VBA设计实现了一个操作简单、维护方便的专家抽取系统。实践证明该系统运行可靠性强,有效提高了工作效率,真正实现了专家抽取的公开、公正和公平性。     

基于CCD技术的外观纸病检测系统

设计了CCD在线外观纸病检测系统,介绍了该系统的硬件组成情况和系统的工作原理、技术指标和软件设计,重点阐述了外观纸病检测系统中CCD技术的优势。     

技工院校“一体化技能双证书”课程模式研究探索

阐述"一体化技能双证书"课程模式对技工院校计算机网络专业教学改革的重要意义,分析当前计算机网络相关职业资格证书存在的问题,把知名行业企业认证培训融合进计算机网络专业一体化教学改革中。