Preparation,characterization, and adsorption properties for metal ions of a novel chelating resin containing sulfoxide and diethylene glycol

A novel chelating resin containing sulfoxide and diethylene glycol, poly{4‐vinylbenzyl‐[2‐2‐(hydroxyethyl)ethoxyl]sulfoxide} (PVESO) was synthesized using chloromethylated polystyrene (PS‐Cl) as material. Its structure was characterized by elemental analysis, infrared spectra, and scanning electron microscopy (SEM). The adsorption capacities of the resin for Hg²⁺, Ag⁺, Cu²⁺, Zn²⁺, and Pb²⁺ at various pH values were determined. The maximum adsorption capacities for Hg²⁺ and Ag⁺ were 1.56 and 0.75 mmol g^?1 respectively. The resin had high selectivity for Hg²⁺ and Ag⁺ over the pH range 1.0–7.0. The adsorption capacities for Hg²⁺ and Ag⁺ under competitive condition were also determined by batch experiment method. In addition, the adsorption kinetics of the resin towards Hg²⁺ at different temperatures was also investigated. The results showed that the adsorption rate was governed by film diffusion at 20°C and 25°C, by particle diffusion at 30°C and 35°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6054–6059, 2006     

不同形貌ZnO气敏材料的制备及影响气敏性因素分析

以锌盐和碱为原料,采用水热和溶剂热法合成了三种形貌的氧化锌粉体,利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)和X射线光电子能谱仪(XPS)对产物的结构和形貌及表面化学状态进行了表征,并将粉体制备成厚膜型气敏元件,测试了其对几种还原性气体的气敏性能,结果表明:在工作温度为395℃时,三种形貌氧化锌对相同浓度的同种测试气体的灵敏度大小顺序为:菜花状氧化锌﹥棒状氧化锌﹥六棱柱状氧化锌。并对影响氧化锌材料气敏性的各种因素进行了分析。     

Sliding mode control design via piecewise smooth Lipschitz surfaces based on contingent cone criteria

In order to improve flexibility of sliding mode control (SMC) for a class of nonlinear systems, a new control design method is proposed in this paper. The sliding surface is extended to be a generic Lipschitz continuous surface instead of a smooth one, with which different characteristics of sliding motion may be realized. Due to the nonsmoothness of the sliding surface, the control design problem is discussed in the framework of Filippov’s differential inclusion, by analyzing the geometric properties of the nonsmooth surface. Discontinuous control laws are presented based on new contingent cone criteria, which steer all of the trajectories of the closed-loop system to reach the piecewise smooth sliding surface in finite time.     

合成香料的绿色技术研究进展简述

采用绿色技术是制备合成香料的发展趋势.本文介绍了微波技术、有机电合成、分子氧氧化、催化加氢、新型催化剂和不对称催化等绿色技术在香料合成过程中的应用研究进展.     

基于集成压控振荡器的调频电路仿真分析

LM566是一种积分-施密特触发电路型的单片集成 VCO 芯片,在调频电路的教学中作为调制器和解调器,通过对其芯片的仿真,可以在软件平台形象的展示其工作特点,便于定量分析。由于Multisim元件库里没有LM566所需模型,为实现LM566在Multisim12仿真环境中的建模,首先,运用Multisim元件库中现有的基本元件模型,构建LM566芯片内部结构;然后,对外围调频电路的静态工作方式和动态工作方式的分析;最后,实验结果表明,给出的芯片模型能够客观的描述LM566的基本特性,为运用该芯片完成包括调频电路在内的各种功能电路的仿真分析奠定了基础,有效扩展了Multisim仿真软件的使用范围,具有一定的借鉴意义。     

Relationship of structure to properties of surfactants. 16. Linear decyldiphenylether sulfonates

The properties of some well-characterized sodium linear decyldiphenylether (C₁₀DPE)sulfonates have been studied. Among the properties investigated are dynamic and equilibrium surface tension, critical micelle concentration (CMC), area per molecule at the aqueous solution/air interface, wetting time by the Draves technique, foaming by the Ross-Miles method, solubilization, and hydrotropy. The decyldiphenylether moiety appears to be equivalent to a terminally substituted straight alkyl chain of 16 carbon atoms. The trialkyl- and dialkyl-mono-sulfonates have solubilities of < 0.01 g/dm³ in water, but are readily soluble in hexane. The didecyldiphenyl ether disulfonate (DADS) has a very low CMC value (1.0 × 10⁻⁵ mol dm⁻³) in aqueous 0.1 N Na⁺ solution (NaCl), characteristic of surfactants with two hydrophilic and two hydrophobic groups. It also has a much larger area per molecule at the aqueous solution/air interface than the monodecyldiphenyl-ether monosulfonate (MAMS) and a much higher surface tension at the CMC. MAMS has a much lower surface tension at a surface age of 1 second (γ_1s) than either DADS or the monodecyldiphenylether disulfonate (MADS). In agreement with γ_1s and γ_eq values, wetting times increase in the order: MAMS < DADS < MADS and initial foam heights decrease in the order: MAMS > DADS > MADS. Solubilization for three water-insoluble surfactants decreases in the order: DADS > MAMS > MADS, while hydrotropy is most pronounced with the disulfonates.     

基于表面反应和扩散迁移控制的灰岩单裂隙渗流—溶解模型及其数值模拟

针对碳酸盐类可溶岩地区水电站坝址流场、化学场以及固相介质属性等随时间发生改变,从而对工程安全运行造成不利影响等问题,研究了灰岩地区地下水运移过程中各物理场间的相互作用,分析了影响灰岩溶解速率的两个因素,即表面反应控制和扩散迁移控制。在此基础上,建立了单裂隙中的渗流—溶解耦合模型,并进行数值求解。模拟结果表明,在垂直裂隙延伸方向,其溶蚀锋面为非齐整平面,而是呈似“虫洞”状非均一变化,而沿裂隙延伸方向即自上游侧向下游方向溶蚀程度逐渐减轻;而通过裂隙的流量呈现随时间逐渐增大的趋势,但变幅不大;根据流量求得的等效水力隙宽,其增幅和增长速率均小于实际平均隙宽;同时,化学场中Ca2+浓度的分布与裂隙开度变化具有相似性,不同时刻下上游侧反应速率R均大于下游侧。就反应机制而言,在初期均受表面反应控制,而随反应进行,位于上游补给区部位转为受扩散迁移控制,但在下游位置仍受表面反应控制。     

板坯连铸结晶器Co基合金涂层抗冷热疲劳性能研究

采用HVOF对板坯连铸结晶器窄边CrZrCu板喷涂C0基合金涂层，与电镀Co—Ni镀层进行对比分析。结果表明：450℃下进行冷热疲劳试验，Co基合金涂层经过113次后，涂层还保持完好无损，未出现任何缺陷，而电镀镀层只能承受37．8次；800℃时，Co基合金涂层经过29．4次冷热疲劳后，有3l％的涂层剥落，而电镀层只能承受21．4次。这说明HVOF涂层具有非常高的抗冷热疲劳性能。     

High Temperature Creep Deformation Mechanisms of a Hot Corrosion-Resistant Nickel-based Superalloy

Creep properties of the experimental superalloy were investigated in the temperature range 1073–1223 K and stress range 110–550 MPa. The observations of dislocation structures during different creep conditions reveal that in the high stress region, particle-shearing mechanisms including stacking fault formation and antiphase boundary creation are operative and in the low stress region, the dislocation climb mechanism is dominant. From the plot of minimum creep rate versus applied stress, a very low stress region with exponent n < 2, which is related to diffusional creep, is found. Based on the experimental results, a stress–temperature creep deformation mechanism map for the alloy is constructed. On the basis of particle hardening theories and various dislocation-creep theories, the dislocation-creep transitions in terms of internal stress are discussed and calculated threshold stresses of various creep deformation mechanisms indicates that the particle shearing is easier to operate than Orowan looping at high stresses, and general climb is easy to happen at low stresses.