This study reports the effect of Lu addition on the microstructural and superconducting properties of YBa2LuxCu3O7?δ (Y123) superconducting samples with x = 0, 0.1, 0.3, 0.5 and 0.7 by means of X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), electron dispersive X-ray (EDX), electrical resistivity and transport critical current density (Jc) measurements. The samples prepared by the liquid ammonium nitrate and derivatives are exposed to various annealing time (20, 40 and 60 h) and temperature (950, 960 and 970 °C), and the best ambient for the sample fabrication is determined to be 970 °C for 20 h. Zero resistivity transition temperatures (Tc), critical current densities (Jc), variation of transition temperatures, hole-carrier concentration, grain size, lattice parameter, surface morphology, element distribution, crystallinity and resistivity (at room temperature) values of the bulk superconducting samples prepared at 970 °C for 20 h are compared with each other. Tc and Jc values of the samples are inferred from the dc resistivity and the critical current measurements, respectively. The results show that the Tc value of the pure sample is about 90.6 K while the sample doped with 0.1 wt% Lu has the maximum Tc value (92.5 K). However, beyond x = 0.1, the Tc value is observed to decrease toward to 83.5 K with increment in the Lu addition. Similarly, the Jc values measured are found to reduce from 142 to 76 A/cm2 with the addition. Moreover, XRD measurements show that both pure and Lu-doped samples exhibit the polycrystalline superconducting phase with the changing intensity of diffraction lines and contain Y123 and Y211 phase, confirming the incorporation of Lu atoms into the crystalline structure of the samples studied. At the same time, comparing of the XRD patterns of samples, the intensity ratio of the characteristic (110) and (013) peaks on the sample doped with 0.1 wt% Lu is more than that on the other samples prepared. Additionally, SEM images display that the sample doped with 0.1 wt% Lu obtains the best crystallinity, grain connectivity and largest grain size whereas the worst surface morphology is observed for the maximum doped sample (x = 0.7). Further, EDX results demonstrate that the Lu atoms doped are successfully introduced into the microstructure of the Y123 samples studied and the maximum Cu element level is observed for the sample doped with 0.1 wt%, explaining that why this sample obtains the best superconducting properties compared to others. According to all the results obtained, it is concluded that the 0.1 wt% Lu addition into the Y123 system improves the microstructural and superconducting properties of the samples studied. 相似文献
ABSTRACTThe present study aimed to evaluate the antimicrobial effect of gaseous ozone against specific oral pathogens on denture base resins. 1080 round samples were prepared (10mm-diameter, 2mm-thickness). Candida albicans, Streptococcus mutans, Streptococcus gordonii, and Aggregatibacter actinomycetemcomitans, polyamide-Deflex, heat-cured polymethyl-methacrylate (PMMA)-QC-20, and cold-cured-PMMA-Meliodent. The doses and durations: 25, 50 and 100µg/ml, 5, 10, 20, 30 minutes. For Cell viability (CV) MTT was used. 100µg/ml was most effective dose for C. albicans, S .gordonii, and A. actinomycetemcomitans were in heat-cured-PMMA and polyamide for S.mutans. For polyamide, lowest CV was 43% in S.mutans and A.actinomycetemcomitans. CV of heat-cure and cold-cure PMMA were 31% and 32% in S.gordonii, respectively. CV was similar for all resins and durations in S.mutans and A.actinomycetemcomitans and for polyamide for C.albicans and for heat-cure PMMA for S.gordonii. 30-min ozone application killed 80% of all microorganisms in all resins except for C.albicans in polyamide (65% cell death) and cold-cure PMMA (57% cell death). Optimal dose/duration combination was 100 µg/ml-10 min. Gaseous ozone can be considered as an effective cleansing agent for denture base resins. 相似文献
In this paper, the need for knowledge-based simulation technique in shop floor scheduling are addressed. A prototype integrated system in Feed Mill manufacturing utilizing an integrated approach of Artificial Intelligence (AI) and simulation is discussed. The system is designed to support the production planner in scheduling and controlling the shop floor on real-time and on-line basis. System overview with the emphasis on knowledge-based simulation module is described. 相似文献
Interface crack problems in graded orthotropic media are considered using analytical and computational techniques. In the analytical formulation an interface crack between a graded orthotropic coating and a homogeneous orthotropic substrate is considered. The principal axes of orthotropy are assumed to be parallel and perpendicular to the crack plane. Mechanical properties of the medium are assumed to be continuous with discontinuous derivatives at the interface. The problem is formulated in terms of the averaged constants of plane orthotropic elasticity and reduced to a pair of singular integral equations which are solved numerically to compute the mixed mode stress intensity factors and the energy release rate. In the second part of the study, enriched finite elements are formulated and implemented for graded orthotropic materials. Comparisons of the finite element and analytical results show that enriched finite element technique is capable of producing highly accurate results for crack problems in graded orthotropic media. Finally, periodic interface cracking and the four point bending test for graded orthotropic solids are modeled using enriched finite elements and the results are briefly discussed. 相似文献
Aerodynamic shape optimization based on computational fluid dynamics (CFD) requires three steps: updating the geometry based on the design variables, updating the CFD surface mesh for the new geometry, and updating the CFD volume mesh based on the new surface mesh. While there are many tools available for the first and third steps, the methods available for the second step are insufficient for geometries that have intersecting components. For these geometries, the CFD surface mesh needs to be updated near component intersections to conform to the component geometries and the updated intersection curves. To address this need, we introduce a method that can deform the CFD surface mesh nodes near component intersections. The method can handle arbitrary design changes for each intersecting component as long as the geometric topology is unchanged. Furthermore, the method is suitable for gradient-based optimization because it smoothly deforms every CFD surface node without introducing topological changes in the CFD surface mesh. In this paper, we detail each step of the proposed method and visualize the range of design changes that can be achieved with this approach. Finally, we use the proposed method in an aerodynamic shape optimization problem to optimize the wing-body intersection of the DLR-F6 configuration. These results demonstrate the effectiveness of the proposed method in a high-fidelity design optimization framework. The method applies to both structured and unstructured CFD meshes and makes it possible to use computer-aided design and conceptual design geometry tools within high-fidelity design optimization.
Ethylene-vinyl acetate (E-VA) copolymers containing 12, 28, and 40 wt% of vinyl acetate, ethylene-vinyl acetate-vinyl alcohol terpolymers obtained by partial hydrolysis of (E-VA) copolymers and ethylene-vinyl alcohol (E-VOH) copolymers obtained by complete hydrolysis of (E-VA) copolymers were investigated by one-liquid contact-angle method. The polar force component of surface-free energy (γ) of copolymers drastically increased by the substitution of the acetate groups with hydroxyl groups. The dispersion force component (γ) of copolymers increased only slightly with the hydrolysis degree and deviated largely from the additivity law in regards of the surface area functions. The surface-free energy analysis of the cross-linked ethylene-vinyl alcohol and surface-hydrolyzed ethylene-vinyl acetate copolymers was also carried out. 相似文献
Nowadays, gas welding applications on vehicle’s parts with robot manipulators have increased in automobile industry. Therefore, the speed of end-effectors of robot manipulator is affected on each joint during the welding process with complex trajectory. For that reason, it is necessary to analyze the noise and vibration of robot’s joints for predicting faults. This paper presents an experimental investigation on a robot manipulator, using neural network for analyzing the vibration condition on joints. Firstly, robot manipulator’s joints are tested with prescribed of trajectory end-effectors for the different joints speeds. Furthermore, noise and vibration of each joint are measured. And then, the related parameters are tested with neural network predictor to predict servicing period. In order to find robust and adaptive neural network structure, two types of neural predictors are employed in this investigation. The results of two approaches improved that an RBNN type can be employed to predict the vibrations on industrial robots. 相似文献
The automatic recognition of user’s communicative style within a spoken dialog system framework, including the affective aspects, has received increased attention in the past few years. For dialog systems, it is important to know not only what was said but also how something was communicated, so that the system can engage the user in a richer and more natural interaction. This paper addresses the problem of automatically detecting “frustration”, “politeness”, and “neutral” attitudes from a child’s speech communication cues, elicited in spontaneous dialog interactions with computer characters. Several information sources such as acoustic, lexical, and contextual features, as well as, their combinations are used for this purpose. The study is based on a Wizard-of-Oz dialog corpus of 103 children, 7–14 years of age, playing a voice activated computer game. Three-way classification experiments, as well as, pairwise classification between polite vs. others and frustrated vs. others were performed. Experimental results show that lexical information has more discriminative power than acoustic and contextual cues for detection of politeness, whereas context and acoustic features perform best for frustration detection. Furthermore, the fusion of acoustic, lexical and contextual information provided significantly better classification results. Results also showed that classification performance varies with age and gender. Specifically, for the “politeness” detection task, higher classification accuracy was achieved for females and 10–11 years-olds, compared to males and other age groups, respectively. 相似文献