MEMS圆片级封装用Cu-Sn低温键合机理与工艺研究

研究了利用低温等温凝固技术实现Cu-Sn键合在MEMS圆片级封装中的应用.基于Cu-Sn二元平衡相图,对键合层结构进行了设计,同时设计了用于测试的键合图形,并对设计的键合结构进行了流片实验.通过对圆片制作及键合等工艺的一系列优化,在250℃的低温条件下生成了熔点为415℃的金属间化合物,获得了良好的键合层.得到的键合样品剪切力强度值达到了GJB548B-2005标准的要求.研究表明,Cu-Sn等温凝固键合技术具有实际应用的潜力.     

A unified model in the pulsed laser ablation process

In this unified model, we introduce the electron-phonon coupling time （tie） and laser pulse width （tp）. For long pulses, it can substitute for the traditional thermal conduction model; while for ultrashort pulses, it can substitute for the standard two- temperature model. As an example of the gold target, we get the dependence of the electron and ion temperature evolvement on the time and position by solving the thermal conduction equation using the finite-difference time-domain （FDTD） method. It is in good agreement with experimental data. We obtain the critical temperature of the onset of ablation using the Saha equation and then obtain the theoretical value of the laser ablation threshold when the laser pulse width ranges from nanosecond to femtosecond timescale, which consists well with the experimental data.     

基于EVD分解的OFDM系统时变信道估计

OFDM系统中,需要获得信道状态信息实现相干解调。信道的时变性会带来子载波间干扰(ICI),降低信道估计算法的精度。针对信道的快时变性,提出一种基于特征值分解的时变信道估计方法,同时设计一种新的导频结构。该方法利用信道矩阵时域及频域相关性,将信道频域矩阵表示为其特征向量的线性加权,并用贝叶斯模型估计加权系数。仿真结果表明,所提方法能有效降低ICI对系统性能的影响,可较好地满足快时变信道环境的要求。     

Perovskite Single Crystals: Synthesis,Optoelectronic Properties,and Application

Recently, lead halide perovskite (PVSK) polycrystalline films have drawn much attention as photoactive material and scored tremendous achievements in solar cells, photodetectors, light-emitting diodes, and lasers owing to their engrossing optoelectronic properties and facile solution-processed fabrication. However, large amounts of grain boundaries unfavorably induce ion migration, surface defect, and poor stability, impeding PVSK polycrystalline film-based optoelectronic devices from practical application. In comparison with the polycrystalline counterparts, PVSK single crystals (SCs) with lower trap density serve as a better platform for not only fundamental research but also device applications. In light of this, the idea of using PVSK single crystals (SCs) to construct the optoelectronic devices is then proposed. Since then, a series of synthesis methods of PVSK SCs have emerged. In this review, recent progress of synthesis method of PVSK SCs is tried to be summarized and their advantages and limitations are analyzed. And then, the optoelectronic properties including carrier dynamic, defects, ion migration, and instability issues in these 3D and 2D PVSK SCs are overviewed and accordingly the proper device configurations of corresponding solar cells, photodetectors, X-ray, γ-ray detectors, etc., are proposed. It is believed that this review can provide the guidance for the further development of PVSK SCs and their applications.     

热丝法氢处理多晶硅锗薄膜

优化了热丝法氢处理多晶硅锗薄膜工艺条件.通过测试材料暗电导的温度特性得出多晶硅锗材料的电导激活能,从而考察氢处理效果.结果表明,采用此技术可有效减少多晶硅锗薄膜中的缺陷态.在优化氢处理时衬底和热丝的温度后,可以把处理时间缩短致30min之内,明显短于其他氢处理技术.     

Ultra-Damping Composites Enhanced by Yolk–Shell Piezoelectric Damping Mechanism

High-performance damping materials are significant toward reducing vibration and maintaining stability for industrial applications. Herein, a yolk–shell piezoelectric damping mechanism is reported, which can enhance mechanical energy dissipation and improve damping capability. With the addition of yolk–shell particles and carbon nanotube (CNT) conductive network, damping properties of various resin matrices are enhanced with the energy dissipation path of mechanical to electrical to heat energy. Particularly, the peak loss factor of epoxy composites reaches 1.91 and tan δ area increases by 25.72% at 20 °C. The results prove the general applicability of yolk–shell piezoelectric damping mechanism. Besides, the novel damping materials also exhibit excellent flexibility, stretchability, and resilience, offering a promising application toward damping coating, indicating broad scope of application in transportation and sophisticated electronics, etc.     

A Polymer Defect Passivator for Efficient Hole-Conductor-Free Printable Mesoscopic Perovskite Solar Cells

Due to the low cost and excellent potential for mass production, printable mesoscopic perovskite solar cells (p-MPSCs) have drawn a lot of attention among other device structures. However, the low open-circuit voltage (V_OC) of such devices restricts their power conversion efficiency (PCE). This limitation is brought by the high defect density at perovskite grain boundaries in the mesoporous scaffold, which results in severe nonradiative recombination and is detrimental to the V_OC. To improve the perovskite crystallization process, passivate the perovskite defects, and enhance the PCE, additive engineering is an effective way. Herein, a polymeric Lewis base polysuccinimide (PSI) is added to the perovskite precursor solution as an additive. It improves the perovskite crystallinity and its carbonyl groups strongly coordinate with Pb²⁺, which can effectively passivate defects. Additionally, compared with its monomer, succinimide (SI), PSI serves as a better defect passivator because the long-chained macromolecule can be firmly anchored on those defect sites and form a stronger interaction with perovskite grains. As a result, the champion device has a PCE of 18.84%, and the V_OC rises from 973 to 1030 mV. This study offers a new strategy for fabricating efficient p-MPSCs.     

The Influences of DMF Content in Composite Polymer Electrolytes on Li+-Conductivity and Interfacial Stability with Li-Metal

Trace N, N-dimethylformamide(DMF) containing composite polymer electrolytes (CPEs) has attracted much attention owing to the dramatically increased Li⁺-conductivity. But the amount of DMF is critical and needs to be clarified for the interfacial stability, since DMF is easily reduced by Li-metal. Herein, the influences of DMF in poly(ethylene oxide) (PEO) and poly(vinylidene fluoride) (PVDF) based CPEs are studied on the Li⁺-conductivity and interfacial stability. In PEO-based CPEs, owing to a stronger interaction of lithium bis(trifluoromethanesulfon)imide (LiTFSI) with PEO than DMF, DMF can not be confined and be easily evaporated off. Only ≈0.25wt.% DMF is absorbed on ceramic electrolyte fillers, giving two times increased Li⁺-conductivity compared with the DMF-free counterparts and generating stable interface with Li-metal; but over much DMF (≥2.2 wt.%) leads to serious interfacial reactions with Li-metal. While in PVDF-based CPEs, ≈8wt.% DMF is confined by LiTFSI owing to a stronger interaction of LiTFSI with DMF than with PVDF. Short-term stable interface with Li-metal can be obtained, but longer-term cycling or higher current density leads to the gradually aggravated reactions with Li-metal. Thanks to the high-voltage stability of PVDF based CPEs, better cycling performance is obtained when they are used as catholytes to match high-voltage cathodes.     

Functional 2D Phases in Mixed Dimensional Perovskite Photovoltaics

Organic-inorganic hybrid perovskite solar cells (PSCs) with unique properties exhibit their powerful competitiveness in the photovoltaic field over the past few years. However, the challenges of stability for perovskite devices limit the commercialization and further development. The 2D/3D hybrid structures combine the superior efficiency of bulk perovskites and the superior stability of layered perovskites and gradually get hotspots of the photovoltaic field. In addition, there remains a lack of comprehensive understanding and systematic summary of the function of 2D perovskite attributed to the complex nature of 2D/3D structures. Here, the latest progress of 2D/3D hybrid structures and focus on the functionality of 2D phases in mixed structures and the underlying mechanism from the perspective of their different distributions in the perovskite layer is summarized. Then, the insight and vital factors for overall improvements in the stability of 2D/3D structures are thoroughly discussed. Finally, it is expected that this review will contribute to the present challenges and future research prospects in the photovoltaic industry.     

Numerical analysis of concentration quenching model of Er/sup 3+/-doped phosphate fiber amplifier

Based on the homogenous model and inhomogeneous model of concentration quenching of erbium-doped fiber amplifier with high doping concentration, the rate equation and power evolution equation of erbium-doped phosphate fiber are solved numerically and analyzed. The dependence of the calculated gain and noise figure on pump power is compared with experimental data, and the results indicate that the combined model of the two models is in good agreement with experimental data. The relative number of clusters in erbium-doped phosphate fibers is estimated from the numerical analysis, and the optimal doping concentration and length of erbium-doped phosphate fibers are proposed in this paper. By numerical analysis, the results show that with 200-mW/980-nm pump power, an erbium-doped phosphate fiber amplifier with a doping concentration of 4.0/spl times/10/sup 26/ ion/m/sup 3/ and length of 10 cm may reach 27.0-dB gain.