Corrosion resistance of ceramics SiC and Si3N4 in flowing lead-bismuth eutectic

A corrosion test was conducted to investigate the corrosion characteristics of SiC and Si₃N₄ in a flowing lead-bismuth eutectic (Pb-Bi) with a fluid temperature of 550 °C, a velocity of 1 m/s, and an oxygen concentration of 1 × 10⁻⁶ wt% for an exposure time of 2000 h. The weight losses of the SiC and Si₃N₄ specimens were lower than those of corrosion-resistant steels tested under the same condition. The specimens showed excellent resistance against an element dissolution and an oxidation in the Pb-Bi flow. The surface was slightly damaged due to some stresses of the Pb-Bi flow and/or those generated by adhered Pb-Bi in the test procedure.     

Fracture strength distribution of porous ceramics under quasi-static load

The purpose of this paper is to estimate the fracture strength distribution of porous ceramics under quasi-static load. Four-point bending test was performed for SiC-porous ceramics at room temperature under quasi-static load. Fracture strength distributions obtained in the above test were estimated with the aid of a conventional probabilistic time-dependent fracture model on the basis of the slow crack growth concept in conjunction with two-parameter Weibull distribution. The results showed that the estimated fracture strength distribution curves were not in good agreement with the experimental data at stress rates. Porous ceramics have damage-tolerable property due to failure of a lot of grain boundaries. Therefore, this is because the dispersion of applied stress was not considered in the conventional model. A new probabilistic time-dependent fracture model considered the dispersion of applied stress was proposed based on Markov process in conjunction with local load sharing rule. The fracture strength distribution curves estimated the aid of the new model were in reasonably good agreement.     

Development of simplified evaluation method for creep-fatigue crack propagation

In the design assessment of fast reactor plant components, prevention of crack initiation from defect-free structures is a main concern. However, existence of initial defects such as weld defects cannot be entirely excluded and this potential cracks are to be evaluated to determine if initiated cracks do not lead to component failure instantly. Therefore, evaluation of structural integrity in the presence of crack-like defects is also important to complement the formal design assessment. The authors have been developing a guideline for assessing long-term structural integrity of fast reactor components using detailed inelastic analysis and nonlinear fracture mechanics. This guideline consists of two parts, evaluation of defect-free structures and flaw evaluation. In the latter, creep-fatigue is considered to be one of the most essential driving force for crack propagation at high operating temperature exceeding 500 °C. The uses of J-integral-type parameters (fatigue J-integral range and creep J-integral) are recommended to describe creep-fatigue crack propagation behavior in the guideline. This paper gives an outline of the simplified evaluation method for creep-fatigue crack propagation.     

Compatibility of surface-coated steels, refractory metals and ceramics to high temperature lead–bismuth eutectic

Compatibility of cladding material with lead–bismuth eutectic at temperature higher than 650 °C is one of the most crucial issues for feasibility of lead–bismuth-cooled fast reactors with cycle efficiency as high as 40%. In order to search for corrosion-resistant materials with lead–bismuth eutectic at temperature higher than 650 °C, surface-coated steels, some refractory metals and various ceramics were tested by means of stirred-type corrosion test. Lead–bismuth was heated up to 700 °C electrically in an alumina crucible, and oxygen concentration in the lead–bismuth was adequately controlled by injection of argon, steam and hydrogen gas mixture into the lead–bismuth. Specimens of aluminum–iron-alloy-surface-coated steels, refractory metals and ceramics including SiC/SiC composites were immersed in the stirred lead–bismuth for 1000 h. It was found that the surface-coated steels showed good compatibility with the lead–bismuth due to formation of a thin and stable protection layer on the surfaces. Tungsten and molybdenum exhibited high corrosion resistance. On the other hand, niobium is not a reliable material for the high temperature LBE. SiC and Ti₃SiC₂ also exhibited high corrosion resistance. On the other hand, the physical performance of the SiC/SiC composite must be improved especially by minimizing the porosity.     

Dependence of PXR beam performance on the operation of the pulsed electron linac

Advanced applications of parametric X-ray radiation (PXR) such as energy-dispersive X-ray absorption fine structure (DXAFS) analysis and phase-contrast imaging have been developed at the Laboratory for Electron Beam Research and Application (LEBRA) of Nihon University. To improve the electron beam quality and geometrical stability of the target crystal, the cooling-water system for the linac and the PXR target was replaced with a new one capable of more precise control. As a result, the reliability of the experimental data in PXR applications, especially in X-ray imaging, has improved. The effect of the electron beam focusing on the target crystal was also investigated. The results of X-ray imaging with a long propagation distance and measurement of the time-structure of the PXR intensity suggest that the correlation between the electron beam profile and the X-ray coherence is rather complicated. It is possible that incident electrons cause some deformation of the target crystal, becoming the dominant factor restricting the quality of intense PXR.     

河道疏浚淤泥固化处理设备、流程及应用

河道疏浚中产生的淤泥如采取抛弃处理会造成资源浪费。介绍一种淤泥固化系统,可对城市污泥、淤泥、隧洞和建筑工程等产生的污泥在工地现场进行瞬间造粒后固化。以图示方式简单描述了淤泥投入、固化出料及养护的处理流程。根据强度试验结果,经系统固化后改良土的强度达到第3类工程用土。总结了淤泥固化系统具有体积小、高机动性、无副产物和处理数据自动记录等特点。介绍了该系统在日本应用的工程实例。最后指出,污泥固化处理成本取决于污泥特性、产物用途及环境指标等因素。     

Successive changes in community structure of an ethylbenzene-degrading sulfate-reducing consortium

The microbial community structure and successive changes in a mesophilic ethylbenzene-degrading sulfate-reducing consortium were for the first time clarified by the denaturing gradient gel electrophoresis (DGGE) analysis of the PCR amplified 16S rRNA gene fragments. At least ten bands on the DGGE gel were detected in the stationary phase. Phylogenetic analysis of the DGGE bands revealed that the consortium consisted of different eubacterial phyla including the delta subgroup of Proteobacteria, the order Sphingobacteriales, the order Spirochaetales, and the unknown bacterium. The most abundant band C was closely related to strain mXyS1, an m-xylene-degrading sulfate-reducing bacterium (SRB), and occurred as a sole band on DGGE gels in the logarithmic growth phase that 40% ethylbenzene was consumed accompanied by sulfide production. During further prolonged incubation, the dominancy of band C did not change. These results suggest that SRB corresponds to the most abundant band C and contributes mainly to the degradation of ethylbenzene coupled with sulfate reduction.     

Predicted and observed initial short circuit current for lead-acid batteries

Initial short circuit currents have been observed using our electronic short circuit switch and also predicted from terminal voltage and ohmic resistance according to Ohm's law for several kinds of lead-acid batteries in various states-of-charge. Ohmic resistance was measured by the d.c. step and the a.c. impedance methods. The predicted and the observed values have been compared in order to establish a prediction method for initial short circuit current. A good agreement was obtained, the root mean square percentage deviation of the predicted value from that observed being only 219%, which confirms the validity of the prediction method for the initial short circuit current.     

Genotoxic effect of Physalis angulata L. (Solanaceae) extract on human lymphocytes treated in vitro

Physalis angulata L (Solanaceae) is a medicinal plant from North of Brazil, whose different extracts and infusions are commonly used in the popular medicine for the treatment of malaria, asthma, hepatitis, dermatitis and rheumatism. However, the genotoxic effects of P. angulata on human cells is not well known. The main purpose of the present study was to evaluate the in vitro genotoxic effects of aqueous extract of P. angulata using the comet assay and the micronucleus assay in human lymphocytes provided from 6 healthy donors. Treatments with P. angulata extracts were performed in vitro in order to access the extent of DNA damage. The comet assay has shown that treatments with P. angulata at 0.5, 1.0, 2.0, 3.0 and 6.0 microg/mL in culture medium were genotoxic. Lymphocytes treated with P. angulata at the concentrations of 3.0 and 6.0 microg/mL in culture medium showed a statistically significant increase in the frequency of micronucleus (p<0.05), however, the cytokinesis blocked proliferation index (CBPI) was not decreased after P. angulata treatment. In conclusion, the present work demonstrated the genotoxic effects of P. angulata extract on human lymphocytes in vitro.