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51.
The effects of gallia additions on the sintering behavior of gadolinia-doped ceria were systematically investigated from the following aspects: the variation in sintered density, the variation in grain size, and the existing forms of Ga2O3 in CeO2.Sintered density increased with increasing Ga2O3 content up to 5 mol.% and then it decreased with further addition of Ga2O3. Grain size also increased with increasing Ga2O3 content up to 5 mol.% and then decreased with further addition of Ga2O3. Decrease in grain size was caused by a pinning effect of Ga2O3 precipitation at grain boundaries. Lattice constant decreased with increasing Ga2O3 content up to 5 mol.%. This decrease will be due to the substitution of smaller Ga3+ ions for Ce4+ ions in the CeO2 structure. According to the results obtained from scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses, the solubility limit of Ga2O3 in Ce0.8Gd0.2O1.9 ceramics can be estimated to be nearly 5 mol.%. The addition of Ga2O3 up to the solubility limit was found to promote the sintering properties of Gd2O3-doped CeO2. 相似文献
52.
Jeongsoo Choi 《Polymer》2005,46(23):9725-9735
A series of star-branched poly(ε-caprolactone)s (SPCLs) was synthesized with structural variation of the arm numbers and lengths through ring-opening polymerization under bulk condition. Arm numbers were varied to be 3, 4, and 6 by using multifunctional initiating cores such as trimethylol propane, pentaerythritol, and dipentaerythritol, respectively. The lengths of the poly(ε-caprolactone) arms were varied by controlling the molar ratio of monomer-to-initiating hydroxyl group molar ratio ([CL]0/[-OH]0=5, 10, 15). Molecular weights were determined by both 1H NMR end-group analysis and MALDI-TOF mass spectrometry, which gave reasonably consistent values. On the contrary, the GPC method failed to give accurate values of molecular weight of SPCLs due to the discrepancy with the linear standard. The branching architecture of SPCLs was evaluated by the branching ratio, g, which is the ratio of the mean-square radius of SPCL to that of liner counterpart, linear poly(ε-caprolactone) (LPCL), which is of the same chemistry and having the same molecular weight. The radii of gyration of SPCLs and LPCLs were determined using small-angle X-ray scattering (SAXS) from the initial slopes of Zimm plots, represented as 1/I(q) vs q2 with I(q) and q being the scattered intensity and scattering vector, respectively. The g values were observed to decrease with increasing arm numbers, indicating more compact molecular structure for SPCLs with higher arm numbers, while no such effect was observed for arm length variation. Thermal properties as well as the degree of crystallinity of SPCLs were found to be also dependent on structural variations. The melting points and the degradation temperatures were observed to increase with increasing arm lengths but with constant arm number. On the other hand, arm number variation with constant arm length gave no such changes to the thermal transitions of SPCLs. However, for the SPCLs with equivalent molecular weights, the degree of crystallinity was found to decrease with increasing arm numbers. 相似文献
53.
Du Young Choi Long Mei Jin Dexian Wang Kyung Ho Row 《Korean Journal of Chemical Engineering》2005,22(3):465-469
High-performance frontal analysis (HPFA) was used for a protein binding study of isoflavones (daidzein, genistin, and genistein),
enantiomers of perillyl alcohol and S-ibuprofen to human serum albumin (HSA). The analyses were performed on a Develosil and
Inertsil 100-Diol-5 column (10 cm×4.6mm). Sodium phosphate solution (pH 7.4, ionic strength 0.17) was used as the mobile phase
at a flow rate of 1 ml/min. To ensure the drug to be eluted as a trapezoidal peak with a plateau, injection volumes were each
fixed up the zonal profile with an evident plateau appears. The unbound drug concentration was determined from a plateau height
of the plateau region after that experimental data were fitted by Scatchard equation. The binding constants (K) and total
binding affinities (nK) of drugs to HSA were calculated, respectively. 相似文献
54.
A W-band divide-by-3 frequency divider with wide bandwidth and low power dissipation is presented using harmonic injection-locking technique. A cascode FET is employed for a self-oscillating second-harmonic mixer which is injection-locked by third-harmonic input to obtain the division order of three. The fabricated frequency divider using 0.1 /spl mu/m GaAs metamorphic HEMT technology shows superior performance such as large bandwidth of 6.1 GHz around 83.1 GHz (7.3%) under small DC power consumption of 12 mW. 相似文献
55.
M. K. Bakhadyrkhanov O. É. Sattarov Kh. M. Iliev K. S. Ayupov Tuérdi Umaier 《Semiconductors》2005,39(7):789-791
It is experimentally ascertained that light stimulates the negative magnetoresistance observed in a high electric field in silicon doped with boron and manganese. The optimum conditions (the electric field, temperature, illumination, and resistivity of the material) for observation of the largest magnitude of negative magnetoresistance in (Si:B):Mn are determined. The dependence of the negative magnetoresistance on the concentration of compensating impurity is established. 相似文献
56.
Nguyen An Tien I. Ya. Mittova O. V. Almjasheva S. A. Kirillova V. V. Gusarov 《Glass Physics and Chemistry》2008,34(6):756-761
Nanocrystalline LaFeO3 is prepared by the dehydration of coprecipitated lanthanum and iron(III) hydroxides. It is shown that the behavior of the samples during heating and the size distribution of LaFeO3 nanocrystals can be considerably different depending on the scheme used for coprecipitation of lanthanum and iron hydroxides; independently of the method employed for coprecipitation of the initial compounds, sintering of the samples at 950°C leads to the formation of lanthanum orthoferrite crystals up to 100 nm in size. 相似文献
57.
Vjacheslav V. Zuev 《Journal of Polymer Research》2008,15(5):351-356
Functionalized polyanilines containing biphenyl, terphenyl, carbazole, anthracene, and 4-n-hexylphenyl moieties were synthesized though the reaction of polyaniline in emeraldine base form with sodium salt of corresponding
vinylketoaromatics with quantitative yields. Polymers were characterized with Fourier transform infrared spectroscopy, proton
nuclear magnetic resonance spectroscopy, and thermogravimetry. The emission characteristics of these polymers in N-methyl-2-pyrrolidone solution were examined. The functionalized polyanilines exhibited an intense green emission. 相似文献
58.
The effects of key parameters on the preparation and regeneration of protoplast from the β-carotene-producing fungus Blakeslea trispora were discussed in this paper, including the combination of various enzymes, mycelial age, digesting time and temperature,
pH value, osmotic stabilizers, pretreatment, culture medium and culture method. Under the condition of mixed enzymes in osmotic
stabilizer (0.6 M NaCl) combined with 2% lysozyme, 3% cellulase and 3% snailase, the highest protoplast yield, as high as
7.48×106 protoplasts/mL, was obtained when mycelial age was 60 h at pH 5.0–6.0 with digesting for 14–16 h at 28 °C. After
purification of the obtained protoplasts, they were regenerated in PDA regenerative medium using bilayer plate culture method.
To validate the usability of the protoplasts, a novel plasmid with green fluorescent protein (GFP) was used in transformation
for easy visual observation. The results showed that the protoplasts prepared by the optimized method were active and applicable
in further gene manipulation experiments.
This work was presented at 13
th
YABEC symposium held at Seoul, Korea, October 20–22, 2007. 相似文献
59.
Min Chan Kim Dong Won Lee Chang Kyun Choi 《Korean Journal of Chemical Engineering》2008,25(6):1239-1244
When a horizontal homogeneous solid is melted from below, convection can be induced in a thermally unstable melt layer. In
this study the onset of buoyancy-driven convection during time-dependent melting is investigated by using similarly transformed
disturbance equations. The critical Rayleigh numbers based on the melt-layer thickness are found numerically for various conditions.
For small superheats, the present predictions approach the well known results of classical Rayleigh-Bénard problems, that
is, critical Rayleigh numbers are located between 1,296 and 1,708, regardless of the Prandtl number. However, for high superheats
the critical Rayleigh number increases with an increase in phase change rate but with decrease in Prandtl number. 相似文献
60.
Ottavia Colombo Simona Villani Giovanna Pinelli Claudia Trentani Maurizia Baldi Orazio Tomarchio Anna Tagliabue 《Nutrition journal》2008,7(1):5