Mediated electrochemical reduction of dibromonorcarane in an emulsified system using Cr(II)

High material yields were obtained in the indirect electrochemical reduction of 7,7-dibromobicyclo-[4-1-0]heptane (dibromonorcarane) to give the corresponding monobromo derivative in an ethylene chloride/water emulsion. The reducing agent was Cr(II) generated by current controlled electrolysis of aqueous chromic chloride at a silver cathode. The effect of the concentration of Cr(II) and the temperature was studied. At 0.1 M Cr(II) and at 40° C the best results were obtained (90% yield).     

Study on poly(vinyl chloride) paste blending resins

Polyvinyl chloride paste blending resins were prepared by a suspension polymerization process, and the optimum ingredients and technological conditions were studied experimentally. The effect of dispersant, surfactant, and agitator design on the particle morphology was discussed. In order to improve the thermal stability of the blending resin, stabilizer was added to the polymerization system, and a special after-treatment was adopted. The effect of blending resins on the rheological and gelation characteristics of the plastisols formed and on mechanical properties, thermal stability, and foamability of the finished articles is demonstrated.     

新型微球调驱剂与L区块的适应性研究

为探究纳微米微球调驱剂与葡北油田L区块的适应性,在纳微米微球深部调驱机理的基础上,开展了纳微米微球室内性能评价实验。结果表明,纳微米微球在油田回注污水中具有较好的分散性,其水化膨胀后的粒径中值满足对L区块地层的封堵要求。当纳微米微球质量浓度为2000mg/L时,水化膨胀效果最好,其水化膨胀30d后的膨胀倍率达到5.7。纳微米微球调驱实验使最终采收率提高了10%,说明纳微米微球可以对非均质地层中的高渗层进行封堵。     

TiC陶瓷先驱体制备和裂解研究

以钛酸四丁酯和二乙烯基苯(DVB)为原料,制备了TiC先驱体,并采用红外(IR)、热重-差热(TGA-DSC)、X射线衍射(XRD)等方法对先驱体和裂解产物进行了表征.结果表明:在283～296℃温度段,由于有机物分解出小分子导致TGA-DSC曲线上大的失重;在445～461 ℃之间,先驱体分解生成TiO_2.更高温度下,TiO_2与DVB裂解生成的碳发生碳热还原反应,生成TiC,且随着裂解温度的提高,TiC的结晶度也随之提高.XRD分析表明随着DVB用量的增加,同一温度下制备的产物结晶度提高.1200 ℃裂解的陶瓷产率均在30%左右.     

基于CFD技术优化50 L发酵罐内气体分布器

通过CFD模拟技术对50L通气搅拌发酵罐内不同气体分布器的传质混合效果进行气液双相流模拟。首先对发酵罐自带气体分布器进行流场模拟,针对模拟结果提出两种改进气体分布器。结果表明:双层环形气体分布器表现出一种较理想的混合传质效果,为此类发酵罐的优化和放大提供一种有效的技术手段。     

基于Hilbert解调技术的齿轮箱故障诊断

从理论上分析了根据Hilbert解调原理进行齿轮诊断的可行性 ,并利用齿轮箱诊断实例证明了理论分析的结果。在论文结尾 ,指出了齿轮箱诊断所应注意的两个基本问题。     

Electrochemical behaviour of cationic polyelectrolytes at a polarized liquid/liquid interface

The behaviours of several cationic polyelectrolytes (chitosan; polyquaternium-4; diethylaminoethyl dextran; polyquaternium-10, and aminoacrylmethacrylate copolymer, Eudragit^® E100) at a polarised liquid/liquid interface are analysed and compared in the present paper. Based on the analysis of the voltammetric results, it was possible to determine some of the relationships between polymer structure and the tendency to adsorb at the interface. It was also possible to determine the substitution degree of a polymer comprising a chitosan main chain modified with glycidyltrimethylammonium chloride, and the values obtained are in agreement with those calculated using other methodologies. Finally, we report a comparative study concerning the effect of cationic (chitosan) and anionic (dextran sulphate) polyelectrolytes on the compactness of a phospholipid film.     

4600串联式原子化器原子吸收分光光度计能量提高的探讨

为了解决串联式原子化器原子吸收分光光度计因光路延长带来的紫外区能量降低问题,重点探讨了对4600串联式原子吸收分光光度计的光路和电路进行优化设计使紫外区能量得到提高的方法.通过对砷元素(As193.7nm)边缘能量进行重点测试,结果证明:线性、特征量、精密度等指标符合国家标准.     

Comparison of phase noise simulation techniques on a BJT LC oscillator

The phase noise resulting from white and flicker noise in a bipolar junction transistor (BJT) LC oscillator is investigated. Large signal transient time domain SPICE simulations of phase noise resulting from the random-phase flicker and white noise in a 2 GHz BJT LC oscillator have been performed and demonstrated. The simulation results of this new technique are compared with Eldo RF and Spectre RF based on linear circuit concepts and experimental result reported in the literature.     

增塑挤压法制备不锈钢多孔过滤管

采用316L不锈钢粉末与增塑剂的混合物,用增塑挤压烧结法制备了不锈钢过滤管,研究了烧结温度和时间对挤压管组织结构和性能的影响.结果表明:合适的挤压料配比为8%～14%,挤压力为30～50kN;随烧结温度、时间的提高,挤压管的烧结收缩率和抗拉强度都提高;最大孔径和相对透气系数呈现先增大后降低的趋势;温度的影响大于时间的影响.最佳烧结参数为1100℃及2h,此时多孔体的最大孔径为5.8μm、相对透气系数为30.5 m3/(h·kPa·m2).孔隙度与抗拉强度有密切关系,当孔隙度为32%时,抗拉强度达到136MPa.