无规共聚聚丙烯的结构与性能研究

通过核磁共振(13CNMR),红外光谱(IR)和差示扫描量热法(DSC)等表征分析手段对无规共聚聚丙烯(PPR)的物理结构与机械性能进行研究。结果表明:PPR具有典型的无规共聚物的结构,乙烯基团较均匀的无规分散于丙烯分子长链中;在分子序列结构中,EE和EEE联排的结构并不多;乙烯含量低的EP接点的含量偏低,相应的抗冲击强度偏低,乙烯含量高的EP接点的含量偏高,相应的抗冲击强度较高。乙烯在丙烯分子长链中的无规插入也适当的降低了共聚物的熔点。     

城市公园视听感知品质评价研究——以成都环城生态区为例

随着城市进入高质量发展阶段,人们愈发重视景观所能带来的丰富感官体验,以往视觉环境特征主导的城市公园营造方法难以满足人们的更高需求。视觉和听觉作为人们最主要的环境信息感知途径,探索二者与景观体验之间的关系可为优化城市公园视听感知品质提供新的视角。研究选取了视景感知、声景感知、声源感知和公园功能特征4个维度共计13项指标,对公园城市建设试点城市—成都环城生态区内3类具有不同主导功能的公园视听感知品质进行评价,探索各维度之间的相互作用及其对总体感知评价的影响。结果发现当公园主导功能特征与其视景、声景协调时,呈现的总体评价结果相对较好,且不同功能城市公园视听感知品质的影响因素、影响方式均不相同。研究在揭示案例公园视听感知品质问题的基础上,提出利用视听交互影响间接提升公园景观体验的思路,为优化不同功能城市公园视听感知品质提供科学依据和灵活策略。     

Route planning for irregular measuring area based on polygon approximation

Route planning plays a key role in reverse engineering. Currently, a rectangle is usually taken as the approximation of an irregular measuring area. This would lead to a low efficiency in measuring because unnecessary region is included and blank routes are generated. In this paper, a polygon-based method is presented to more accurately approximate irregular area. An irregular area is decomposed into a set of sub-polygons. Within each sub-polygon, there is no blank route. Unnecessary region is thus much more reduced. Experiment shows that measuring efficiency is improved a great deal by adopting the polygon-based method, compared with the rectangle approximation method.     

基于FFT方法对微小信号3D分析研究

为了全面准确地分析微小信号,引入基于FFT技术的三维方法,利用LabVIEW2011高级开发者工具包编程设计,实现将微小信号从一维显示转换成三维能量谱的形式。使用所设计的程序成功实现对微小信号的准确分析。采用该方法可以实现对于微小信号的全面研究。     

橄榄苦苷改善db/db小鼠糖尿病的肝脏转录组学及生物信息学分析

通过转录组学及其生物信息学分析,研究了橄榄苦苷缓解db/db小鼠糖尿病的肝脏差异表达基因及相关信号通路。结果发现与db/db对照组相比,橄榄苦苷处理组的539个基因发生显著变化,其中450个基因显著上调,89个基因显著下调。将上调和下调的差异表达基因在基因本体论数据库中注释,这些差异表达基因主要在细胞过程、细胞部分和结合中分布。京都基因与基因组百科全书通路富集分析结果显示上调的差异表达基因主要富集在磷酸肌醇3-激酶-蛋白激酶B信号通路途径,该通路共涉及27个差异表达基因;下调的差异表达基因主要富集在花生四烯酸代谢和真核生物中核糖体的生物发生信号通路途径,分别涉及4个差异表达基因。本研究为进一步阐明橄榄苦苷缓解2型糖尿病的分子机制奠定了基础。     

超声波辅助煤泥脱水的研究

为了探索添加助滤剂以及超声波辅助处理后煤泥脱水效果的变化,以微细粒煤泥为研究对象,对煤泥性质进行了分析,综合考察了助滤剂用量、超声波频率、超声作用时间等因素对脱水效果的影响.试验结果表明:采用禾草沟选煤厂煤泥样品,在超声波与助滤剂共同作用下,当氯化钙用量为1 600 g/t,聚合氯化铝用量为1 000 g/t,聚丙烯酰...     

Preparation and properties of fluorinated silicon two‐component polyurethane hydrophobic coatings

A polyurethane (PU) hydrophobic coating was prepared by the two‐component method, polycarbonate diol and isophorone diisocyanate becoming a two‐phase composition. The PU films with hydrophobic surface were prepared by establishing a rough structure on the surface of silica (SiO₂) modified with silane coupling agents (γ‐(2,3‐epoxypropoxy)propytrimethoxysilane (KH560) and (heptadecafluoro‐1,1,2,2‐tetradecyl)trimethoxysilane (FAS)). First, the surface of SiO₂ was covered by a layer of hydrophobic methyl and fluorocarbon (C–F) groups. Then, the SiO₂ and modified SiO₂ were obtained by the introduction of KH560 and FAS with the silanol reaction by ultrasonic stirring. The effect of SiO₂ and modified SiO₂ on the structure and hydrophobic properties of PU was investigated by a series of test instruments. The results showed that the introduction of SiO₂ and modified SiO₂ was beneficial for increasing the roughness of the PU coating surface; the roughness of FAS/SiO₂‐PU could reach up to 14.790 nm, four times better than pure PU. A hydrophobic modified PU coating with water contact angle 123° was fabricated by using the hydrophobic C–F group FAS as a low surface energy material and establishing a micro rough structure on the surface of PU. Moreover, PU modified with KH560 and FAS can reduce the glass transition temperature (T_g) of soft segments, resulting in improvement of micro‐phase separation. © 2020 Society of Chemical Industry     

干燥方法对超微枣粉品质的影响

本文研究了变温压差膨化干燥、中短波红外干燥、热风干燥和真空冷冻干燥4种干燥方式对超微枣粉品质的影响。结果发现:在物理特性方面,变温压差膨化干燥超微枣粉的色泽最好,中短波红外干燥和变温压差膨化干燥超微枣粉的粒径小,变温压差膨化干燥超微枣粉具有较好的溶解性,真空冷冻干燥法超微枣粉的堆积密度最大。在营养成分方面:4种干燥方法制备的超微枣粉的营养成分较鲜样均有不同程度的下降,变温压差膨化干燥、中短波红外干燥和热风干燥超微枣粉的总糖含量较高,总酸含量无显著差异;真空冷冻干燥超微枣粉的维生素C和黄酮含量显著高于其他干燥方法;真空冷冻干燥和变温压差膨化干燥有利于超微枣粉中环磷酸腺苷的保存。结论:变温压差膨化干燥超微枣粉的综合品质优于其他3种枣粉,该工艺生产效率高、成本低,是超微枣粉生产中较适宜的干燥工艺。     

米糠肽抗氧化活性的研究

通过测定米糠肽的还原力、抗卵黄脂蛋白的脂质过氧化能力、抗油脂过氧化能力以及H2O2诱导的红细胞氧化溶血试验和大鼠肝匀浆脂质过氧化试验研究了米糠肽的抗氧化作用.结果表明:米糠肽具有较强的还原力,对脂质过氧化和油脂过氧化均具有良好的抑制作用,并能抑制H2O2诱导的红细胞氧化溶血反应和肝组织匀浆脂质过氧化反应的发生,有望作为天然抗氧化剂及功能性食品得到开发应用.