醇溶性疏水交联型丙烯酸酯环保胶黏剂的制备与表征

以乙醇为溶剂,N,N'-亚甲基双丙烯酰胺为交联单体,丙烯酸十八酯为长链疏水单体,通过溶液聚合制备了一种丙烯酸酯环保胶黏剂.通过1HNMR,FTIR,GPC,SEM,TGA等对聚合物的结构和性能进行表征与测试.研究了反应时间、反应温度、交联单体和疏水单体的用量以及硬软单体物质的量比对聚合物和膜性能的影响.结果表明,当反应时间为4 h,反应温度为80℃,交联单体含量为1％(占单体总质量,下同),硬软单体物质的量比为2:1时,聚合物重均相对分子质量为1.286×105,热分解温度为309.3℃,玻璃化转变温度为85.2℃,胶膜硬度达到4H.疏水单体的加入提高了聚合物膜的拉伸强度和疏水性能,与没加疏水单体相比,加入3％疏水单体后,胶膜的拉伸强度提高了184.2％,达到0.79 MPa;水接触角提高219.5％,达到78.6°.制备的环保型胶黏剂可用于含沙土壤的固化以及沙画、沙瓶画和浮雕画的固定等.     

严重事故工况下 M31核电机组应急补水设施可用性研究

国内核电厂吸取福岛事故的经验教训,增加了严重事故后应急补水设施,完善了应急补水的相关功能,进一步提高了核电厂的安全水平.对M 310核电机组严重事故状态下的应急补水设施进行技术分析,分析计算结果表明,应急水源到应急补水泵接入点距离过长,水损过大,实际补水压力及流量无法满足设计要求.针对该问题提出一系列设计改进措施,优化改进后的应急补水设施可保证严重事故工况下M 310核电机组应急补水设施的可用性,从而进一步提高核电机组的安全性.     

基于长短期记忆网络的电网故障区域定位与故障传播路径推理

为了在发生故障后维持电力系统的安全稳定,有必要实现对故障区域的快速定位并确定故障冲击的传播路径,提出基于长短期记忆网络(LSTM)的故障区域定位和故障传播路径推理方法.首先,利用LSTM建立2个故障诊断模型分别实现在线检测故障时刻和确定故障区域;然后,通过计算故障点附近线路的端口供给能量确定故障冲击的传播路径;最后,以8机36节点电网为例进行算例验证,结果表明所提模型可在发生故障后短时间内检测到故障,给出故障区域和故障冲击传播的路径,且对噪声有较强的鲁棒性.     

Johnson-Cook dynamic constitutive relationship for TC 16 titanium alloy

The true stress--strain curves of TC16 alloy with a wide range of strain rates were investigated under uniaxial quasi-static tension and uniaxial dynamic compression with the lnstron 8032 test machine and the split Hopkinson bar respectively. The results indicate that the true stress increases with increasing strain rate, while decreases with increasing temperature. Under the 105 s^-1 high strain rate and temperature higher than 673 K, the true stress would even be less than that under quasi-static condition. A new method incorporating TCl6＇s stress strain curve developing item was proposed to determine the coefficients in J-C model easily and to avoid the estimation of the adiabatic temperature rising. The Johnson-Cook dynamic constitutive relationship for TC16 was obtained for the first time. Good agreement was obtained between the model prediction and the experimental stress--strain curves for TC16 under both quasi-static and dynamic loadings.     

Crack initiation and propagation induced by inclusions in a nickel-base P/M superalloy under fatigue load

1 IntroductionRecently the key components in advanced aircraftengines are widely made of nickel-base P/M super-alloy. However, non-metallic inclusions are intro-duced into this material during powder metallurgyprocessing. In industry, although many method…     

ECAP制备的亚微米7050铝合金的力学性能和微观结构

采用等通道角挤压法 (ECAP法 )制备亚微米 70 5 0铝合金。为了提高合金的力学性能 ,在挤压过程中增加了固溶时效处理工艺 ,并对 70 5 0铝合金在不同处理工艺条件下的显微组织和力学性能的变化进行了研究。结果表明 :ECAP挤压后进行固溶和时效处理能明显提高合金的力学性能。退火态合金经过ECAP后 ,晶粒尺寸明显细化到亚微米级。将挤压一次的试样进行固溶处理和时效处理 ,合金的强度在 5 75MPa左右 ,而延伸率能达到2 5 .5 %左右 ;若经等通道角挤压过的试样在固溶处理后立即进行再次挤压 ,并配合时效处理 ,合金强度能迅速达到 6 16MPa ,延伸率为 16 .9%。     

Preparation and electrochemical performance of nanosized Co3O4 via hydrothermal method

The hydrotalcite-type cobalt compounds were prepared through oxidation of Co（OH）2 gel using NH4OH as precipitating agent and H2O2 as oxidant. These hydrotalcite-type cobalt compounds were transformed into Co3O4 through hydrothermal decomposition with nanostructural deformation. The precursor and product were characterized by Fourier-transform infrared（FT-IR） spectrum, X-ray diffractometry（XRD） and transmission electron microscopy（TEM）. The electrochemical performances of as-prepared nanosized Co3O4 as anode materials in lithium-ion batteries were tested by charge-discharge test in the voltage range of 0-3.0 V. The influence of morphology of Co3O4 particle on the capacity and cycling performance was studied. The results show that the shape and size of the final product can be controlled by altering cobalt sources. The irregular cubic Co3O4 with the average particle size of about 10 nm shows the best electrochemical performance. After 10 charge-discharge cycles, the specific charge capacity retains 555 mA.h/g.     

过氧化氢分光光度法测定湿法提钒工艺中钒

为了提高湿法提钒工艺过程控制效率,采用以过氧钒离子(VO(O₂)⁺)显色特性为基础的过氧化氢分光光度法测定钒含量,实现了样品中钒含量的现场快速测定。首先通过在试样溶液中加入适量氢氧化钠溶液,调整溶液pH值至9～10,然后加入过氧化氢将低价态钒全部氧化至钒(V),再加入硫酸调整溶液至酸性,钒(V)与过氧化氢在室温下形成稳定的红棕色过氧钒离子(VO(O₂)⁺),于450 nm处测定吸光度。钒质量浓度在2.0~400 mg/L内与吸光度值符合比尔定律。采用实验方法测定3种湿法冶金提钒液体试样(包括钒浸取溶液、钒盐沉淀后溶液以及废水等)中钒,结果的相对标准偏差(RSD,n=10)分别为0.38%、3.5%和7.6%;与高锰酸钾氧化-硫酸亚铁铵滴定法结果相一致。     

激光合金化熔池成分均匀性与形状系数的关系SCIEI

本文研究了激光工艺参数对镀Cr中碳低合金钢激光合金化熔池形状系数及成分均匀性的影响。实验结果表明,熔池成分均匀性取决于其截面形状系数,后者是光束功率密度和交互作用时间的函数。在功率密度一定时,形状系数与交互作用时间成线性关系。当形状系数为1.6—3.0时,可以获得成分均匀的熔池。