Single-ion-conducting nanocomposite polymer electrolytes based on PEG400 and anionic nanoparticles: Part 2. Electrical characterization

Molecular relaxation and polarization phenomena of twelve single-ion-conducting nanocomposite polymer electrolytes (nCPEs) are studied using Broadband Electrical Spectroscopy (BES). The electrolytes are obtained by combining PEG400 oligomers with increasing amounts of anionic nanofiller comprised of fluorinated-TiO₂ associated with Li⁺ cations (LiFT^®), resulting in [PEG400/(LiFT)_y] systems with 0 ≤ y ≤ 26.4. This new class of [PEG400/(LiFT)_y] electrolytes allows us to achieve a significant single-ion conductivity (1.1·10⁻⁵ S cm⁻¹ at 30 °C for n_Li/n_O = 0.113) without the addition of lithium salts. To the best of our knowledge, this is the highest conductivity value reported for this class of electrolytes. This study, in conjunction with the results reported in Part 1, leads us to hypothesize a conduction mechanism in terms of two types of long-range charge-transfer processes. The first charge-transfer occurs at the interface between the filler nanoparticles and filler-PEG domains, while the second occurs through the PEG400 matrix with the assistance of polymer segmental motion. The measured Li⁺ transference numbers confirm that the studied materials are single-ion conductors.     

Producing mind

Those who support a computationalist view of the mind tend to hold that it must apply to all aspects of mentality. This view is called computational universalism. An apparently opposed perception-phenomenal universalism-is that consciousness is at the root of all mental processes. Computationalists tend to cognitivize, or otherwise play down, phenomenal consciousness. The recent book by David Chalmers proposes one way to take both computation and phenomenal consciousness seriously. A different way is explored here, which avoids the commitment to a non-materialist ontology of consciousness in Chalmers' position. This alternative approach rejects universalism of both the computational and the phenomenal kinds. Instead a pluralistic view of mind is proposed. Cognitive and phenomenal aspects of mind are to be taken as equally fundamental and as complementary. Cognitive or productive aspects of mind have their own kind of reality which is independent of consciousness. Semantic content may well result from the combination of cognitive productivity and consciousness. The view proposed offers solutions to old problems affecting computational accounts.     

Aesthetic 3D model evolution

A new research frontier for evolutionary 2D image generation is the use of mathematical models of aesthetics, with the goal of automatically evolving aesthetically pleasing images. This paper investigates the application of similar models of aesthetics towards the evolution of 3-dimensional structures. We extend existing models of aesthetics used for image evaluation to the 3D realm, by considering quantifiable properties of surface geometry. Analyses used include entropy, complexity, deviation from normality, 1/f noise, and symmetry. A new 3D L-system implementation promotes accurate analyses of surface features, as well as productive rule sets when used with genetic programming. Multi-objective evaluation reconciles multiple aesthetic criteria. Experiments resulted in the generation of many models that satisfied multiple criteria. A human survey was conducted, and survey takers showed a statistically significant preference for high-fitness highly-evolved models over low-fitness unevolved ones. This research shows that aesthetic evolution of 3D structures is a promising new research area for evolutionary design.