Studies on high density polyethylene (HDPE) functionalized by ultraviolet irradiation and its application

The structure and properties of high density polyethylene (HDPE) functionalized by ultraviolet irradiation at different light intensities in air were studied by electron analysis, FTIR spectroscopy, contact angle with water, differential scanning calorimetry and mechanical properties measurement. The results show that oxygen‐containing groups such as C?O, C—O and C(?O)O were introduced onto the molecular chain of HDPE following irradiation, and the rate and efficiency of HDPE functionalization increased with enhancement of irradiation intensity. After irradiation, the melting temperature, contact angle with water and notched impact strength of HDPE decreased, the degree of crystallinity increased, and their variation amplitude increased with irradiation intensity. Compared with HDPE, the yield strength of HDPE irradiated at lower light intensity (32 W m^?2 and 45 W m^?2) increases monotonically with irradiation time, and the yield strength of HDPE irradiated at higher light intensity (78 W m^?2) increases up to 48 h and then decreased with further increase in irradiation time. The irradiated HDPE behaved as a compatibilizer in HDPE/polycarbonate (PC) blends, and the interface bonding between HDPE and PC was ameliorated. After adding 20 wt% HDPE irradiated at 78 W m^?2 irradiation intensity for 24 h to HDPE/PC blends, the tensile yield strength and notched Izod impact strength of the blend were increased from 26.3 MPa and 51 J m^?1 to 30.2 MPa and 158 J m^?1, respectively. Copyright © 2003 Society of Chemical Industry     

Monte Carlo simulation of gas phase polymerization of 1,3‐butadiene. Part II: Kinetics optimization and confirmation

Studies on the deactivations and initiations of gas phase polymerizations of 1,3‐butadiene have been achieved by Monte Carlo simulation. Initiation and deactivation control the reaction before and after the peak of the polymerization rate, respectively. The influence of polymerization temperature has been studied. Monte Carlo modeling of polymerization kinetics and mechanism was confirmed by the agreement of experimental data and simulation results of polymerizations run with a temporary evacuation of monomer. The balance of catalysts and active chains is established by both initiation and chain transfer reactions with cocatalyst, which causes a ‘pseudo‐stability’ stage. © 2003 Society of Chemical Industry     

应用时频分析方法辨识时变系统的模态参数

应用Gabor展开及Hilbert变换进行时变线性系统模态参数的辨识。利用非平稳信号的Gabor变换将结构响应信号表示在时频面上，并通过Gabor展开重构分离模态分量，建立每一阶模态的时变线性模型。对单模态时变线性模型应用Hilbert变换来辨识随时间变化的模态频率和阻尼。通过对刚度和阻尼慢变的两自由度系统模态参数的仿真辨识验证辨识方法的有效性。仿真结果表明：本文方法为时变线性系统的模态参数辨识提供了一条新的途径。     

欧盟电信管制的新规则及其管制趋势

1987年前，除个别成员国在推动电信改革外。欧盟没有共同的电信政策，更没有形成统一的电信市场。欧盟的电信改革始于1987年。先后经历了三个阶段，第一阶段：公布《开发电信服务和设备的共同市场》绿皮书，开放终端设备和增值服务市场。实行电信业的管理与经营分离。保留对语音电话服务     

通用串行总线(USB)接口芯片USBN9602的应用

简要介绍了通用串行总线USB的特点,对USB接口芯片USBN9602的内部结构、引脚、寄存器组作了详细的论述,并介绍了其应用。     

中原油田岩石可钻性与声波时差关系研究

选取中原油田的大量岩心，采用常规岩石力学测试方法测定了岩石的可钻性、声波测试方法测定了岩石和岩屑声波时差，通过对测得的岩石可钻性级值和声波时差进行回归拟合，得出了中原油田岩石可钻性与声波时差的关系式。现场应用表明，该关系式较好地反映了中原油田地层岩石可钻性与声波时差的关系，可以在优选钻头时作为参考或直接应用。     

热管传热性能对小型热管换热器散热效能影响

在零重力辅助下,小热管热阻是小型热管换热器散热效能的重要影响因素之一。基于集总参数法对于换热器系统数值计算的高效性思想,建立了热管、热管换热器的集总参数模型。对同一热管换热器选用不同传热性能的热管,在不同传热温差和流体质量流速下,就其散热效能进行了数值计算。计算结果表明,在零重力辅助下,热管换热器管内热阻存在一临界值Rcri。当热阻RHP≤Rcri时,管外热阻起主导作用,热管换热器的散热效能εh几乎不随热管管内热阻的值而变化。