全文获取类型
收费全文 | 353253篇 |
免费 | 28374篇 |
国内免费 | 15533篇 |
专业分类
电工技术 | 20767篇 |
技术理论 | 45篇 |
综合类 | 25375篇 |
化学工业 | 58941篇 |
金属工艺 | 20737篇 |
机械仪表 | 22469篇 |
建筑科学 | 27343篇 |
矿业工程 | 11528篇 |
能源动力 | 9688篇 |
轻工业 | 23652篇 |
水利工程 | 6709篇 |
石油天然气 | 23148篇 |
武器工业 | 2804篇 |
无线电 | 38454篇 |
一般工业技术 | 39004篇 |
冶金工业 | 18007篇 |
原子能技术 | 3619篇 |
自动化技术 | 44870篇 |
出版年
2024年 | 1124篇 |
2023年 | 5222篇 |
2022年 | 8976篇 |
2021年 | 13511篇 |
2020年 | 10169篇 |
2019年 | 8309篇 |
2018年 | 9670篇 |
2017年 | 10806篇 |
2016年 | 9893篇 |
2015年 | 13699篇 |
2014年 | 17325篇 |
2013年 | 20794篇 |
2012年 | 22700篇 |
2011年 | 25165篇 |
2010年 | 22242篇 |
2009年 | 21064篇 |
2008年 | 20650篇 |
2007年 | 19710篇 |
2006年 | 20072篇 |
2005年 | 17688篇 |
2004年 | 11973篇 |
2003年 | 10702篇 |
2002年 | 9900篇 |
2001年 | 8821篇 |
2000年 | 8782篇 |
1999年 | 9372篇 |
1998年 | 7160篇 |
1997年 | 6106篇 |
1996年 | 5795篇 |
1995年 | 4762篇 |
1994年 | 3852篇 |
1993年 | 2605篇 |
1992年 | 2058篇 |
1991年 | 1557篇 |
1990年 | 1223篇 |
1989年 | 983篇 |
1988年 | 807篇 |
1987年 | 486篇 |
1986年 | 388篇 |
1985年 | 237篇 |
1984年 | 186篇 |
1983年 | 139篇 |
1982年 | 124篇 |
1981年 | 72篇 |
1980年 | 94篇 |
1979年 | 43篇 |
1978年 | 17篇 |
1977年 | 23篇 |
1976年 | 28篇 |
1973年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
181.
Wei Lai Lihong Ge Huaming Li Yilin Deng Bin Xu Bo Ouyang Erjun Kan 《International Journal of Hydrogen Energy》2021,46(53):26861-26872
The electrochemical water splitting to produce H2 in high efficiency with earth-abundant-metal catalysts remains a challenge. Here, we describe a simple “cyclic voltammetry + ageing” protocol at room temperature to activate Ni electrode (AC-Ni/NF) for hydrogen evolution reaction (HER), by which Ni/Ni(OH)2 heterostructure is formed at the surface. In situ Raman spectroscopy reveals the gradual growth of Ni/Ni(OH)2 heterostructure during the first 30 min of the aging treatment and combined with polarization measurements, it suggests a positive relation between the Ni/Ni(OH)2 amount and HER performance of the electrode. The obtained AC-Ni/NF catalyst, with plentiful Ni–Ni(OH)2 interfaces, exhibits remarkable performance towards HER, with the low overpotential of only 30 mV at a H2-evolving current density of 10 mA/cm2 and 153 mV at 100 mA/cm2, as well as a small Tafel slope of 46.8 mV/dec in 1 M KOH electrolyte at ambient temperature. The excellent HER performance of the AC-Ni/NF could be maintained for at least 24 h without obvious decay. Ex situ experiments and in situ electrochemical-Raman spectroscopy along with density functional theory (DFT) calculations reveal that Ni/Ni(OH)2 heterostructure, although partially reduced, can still persist during HER catalysis and it is the Ni–Ni(OH)2 interface reducing the energy barrier of H1 adsorption thus promoting the HER performance. 相似文献
182.
针对选煤机排料系统的刮板易出现磨损、弯曲等问题,通过对刮板结构、受力情况进行详细分析,并提出了相应的优化设计方案.仿真结果表明,该设计方案可满足煤矿安全高效的生产需求,对实际生产中的刮板结构设计有一定应用价值. 相似文献
183.
Jiajia Ye Xuting Li Guang Xia Guanghao Gong Zhiqiang Zheng Chuanzhong Chen Cheng Hu 《材料科学技术学报》2021,77(18):100-107
We report for the first time a Na-ion battery anode material composed of P-doped CoSe2 nanoparticles(P-CoSe2)with the size of 5-20 nm that are uniformly embed in a 3D porous honeycomb-like carbon network.High rate capability and cycling stability are achieved simultaneously.The honeycomb-like carbon network is rationally designed to support high electrical conductivity,rapid Na-ion diffusion as well as the accommodation of the volume expansion from the active P-CoSe2 nanoparticles.In particular,heteroatom P-doping within CoSe2 introduces stronger P-Co bonds and additional P-Se bonds that signif-icantly improve the structure stability of P-CoSe2 for highly stable sodiation/desodiation over long-term cycling.P-doping also improves the electrical conductivity of the CoSe2 nanoparticles,leading to highly elevated electrochemical kinetics to deliver high specific capacities at high current densities.Benefiting from the unique nanostructure and atomic-level P-doping,the P-CoSe2(2∶1)/C anode delivers an excel-lent cycle stability with a specific capacity of 206.9 mA h g-1 achieved at 2000 mA g-1 after 1000 cycles.In addition,this material can be synthesized using a facile pyrolysis and selenization/phosphorization approach.This study provides new opportunities of heteroatom doping as an effective method to improve the cycling stability of Na-ion anode materials. 相似文献
184.
Junyu Chen Yuze Li Yuming Jiang Liucheng Mao Mi Lai Lixia Jiang Huihui Liu Zongxiu Nie 《Advanced functional materials》2021,31(52):2106743
Cancer remains an intractable medical problem. Rapid diagnosis and identification of cancer are critical to differentiate it from nonmalignant diseases. High-throughput biofluid metabolic analysis has potential for cancer diagnosis. Nevertheless, the present metabolite analysis method does not meet the demand for high-throughput screening of diseases. Herein, a high-throughput, cost-effective, and noninvasive urine metabolic profiling method based on TiO2/MXene-assisted laser desorption/ionization mass spectrometry (LDI-MS) is presented for the efficient screening of bladder cancer (BC) and nonmalignant urinary disease. Combined with machine learning, TiO2/MXene-assisted LDI-MS enables high diagnostic accuracy (96.8%) for the classification of patient groups (including 47 BC and 46 ureteral calculus (UC) patients) from healthy controls (113 cases). In addition, BC patients can also be identified from noncancerous UC individuals with an accuracy of 88.3% in the independent test cohort. Furthermore, metabolite variations between BC and UC individuals are investigated based on relative quantification, and related pathways are also discussed. These results suggest that this method, based on urine metabolic patterns, provides a potential tool for rapidly distinguishing urinary diseases and it may pave the way for precision medicine. 相似文献
185.
Among various carbon materials, diamond stands out due to excellent physical and chemical properties. In this work, we designed Dia@SiO2@Ag composites combining diamond micropowder and Ag nanoparticles by a simple chemical method and obtained stable substrate for surface enhanced Raman scattering (SERS) owing to its high surface-to-volume ratio, low density, as well as close bond between diamond and Ag. As-prepared Dia@SiO2@Ag presented high activity to detect crystal violet and rhodamine 6G molecules, which was demonstrated by significantly enhanced SERS spectra and high enhancement factor values (108-109). Moreover, Dia@SiO2@Ag also showed desired sensitivity, which was investigated by detection limit. Therefore, our study provided more theoretical support and broadened the functional applications of diamond, particularly in Raman detection. 相似文献
186.
Qiang Liu Xinyu Mao Xiaoying Li Penghui Chen Xin Liu Ziyu Liu Danyang Zhu Haohong Chen Tengfei Xie Jiang Li 《Journal of the American Ceramic Society》2021,104(10):4927-4931
0.5 at.% Cr:ZnGa2O4 precursor was synthesized by the co-precipitation method with nitrates as raw materials, using ammonium carbonate as the precipitant. Low-agglomerated Cr:ZnGa2O4 powders with an average particle size of 43 nm were obtained by calcining the precursor at 900℃ for 4 h. Using the powders as starting materials, 0.5 at.% Cr:ZnGa2O4 ceramics with an average grain size of about 515 nm were prepared by presintering at 1150℃ for 5 h in air and HIP post-treatment at 1100℃ for 3 h under 200 MPa Ar. The in-line transmittance of 0.5 at.% Cr:ZnGa2O4 ceramics with a thickness of 1.3 mm reaches 59.5% at the wavelength of 700 nm. The Cr:ZnGa2O4 ceramics can be effectively excited by visible light and produce persistent luminescence at 700 nm. For Cr:ZnGa2O4 transparent ceramics, the brightness of afterglow was larger than 0.32 mcd/m2 after 30 min, which is far superior to that of Cr:ZnGa2O4 persistent luminescence powders. 相似文献
187.
从老旧建筑结构现状展开论述,详细阐述了砌体墙加固设计、构造柱与圈梁加固设计、基础结构加固设计这几种老旧建筑结构改造加固设计,实现了对建筑结构改造工程施工技术的深入分析,希望能够为城乡建设事业的发展提供助力。 相似文献
188.
189.
Neural Computing and Applications - Traffic identification is currently an important challenge for network management and security. In this paper, we propose a novel application identification... 相似文献
190.
Oxygen reduction reaction(ORR) plays a critical role in many energy conversion and storage processes.Therein, a comparative study of the electrocatalytic activity for ORR in 0.1 mol/L KOH solution was conducted using layered perovskite-like LaSr_3 Fe_3 O_(10) and LaSr3 Fe_3 O_(10)-graphene oxide(GO) composite as electrodes. Linear sweep voltammetry(LSV) results show that the LaSr3 Fe_3 O_(10)-GO hybrid exhibits higher current density, a more positive onset potential(-0.15 V vs. Hg/HgO) in comparison with LaSr_3 Fe_3 O_(10).The value of the overall transferred electrons for both catalysts implies a dominant two electron process for ORR. Both catalysts under alkalic conditions exhibit a two-step Tafel slope, suggesting a change in the reaction mechanism for ORR. The composite electrode exhibits a higher ORR current density, but inferior durability performances in relative to the LaSr_3 Fe_3 O_(10) electrode. 相似文献