Hydrogen embrittlement of super duplex stainless steel – Towards understanding the effects of microstructure and strain

The effects of austenite spacing, hydrogen charging, and applied tensile strain on the local Volta potential evolution and micro-deformation behaviour of grade 2507 (UNS S32750) super duplex stainless steel were studied. A novel in-situ methodological approach using Digital Image Correlation (DIC) and Scanning Kelvin Probe Force Microscopy (SKPFM) was employed. The microstructure with small austenite spacing showed load partitioning of tensile micro-strains to the austenite during elastic loading, with the ferrite then taking up most tensile strain at large plastic deformation. The opposite trend was seen when the microstructure was pre-charged with hydrogen, with more intense strain localisation formed due to local hydrogen hardening. The hydrogen-charged microstructure with large austenite spacing showed a contrasting micro-mechanical response, resulting in heterogeneous strain localisation with high strain intensities in both phases in the elastic regime. The austenite was hydrogen-hardened, whereas the ferrite became more strain-hardened. SKPFM measured Volta potentials revealed the development of local cathodic sites in the ferrite associated with hydrogen damage (blister), with anodic sites related to trapped hydrogen and/or micro voids in the microstructure with small austenite spacing. Discrete cathodic sites with large Volta potential variations across the ferrite were seen in the coarse-grained microstructure, indicating enhanced susceptibility to micro-galvanic activity. Microstructures with large austenite spacing were more susceptible to hydrogen embrittlement, related to the development of tensile strains in the ferrite.     

Histogram-based automatic segmentation of images

Neural Computing and Applications - The segmentation process is defined by separating the objects as clustering in the images. The most used method in the segmentation is k-means clustering...     

Changes in motor performance in persons with Parkinson''s disease after exercise in a mountain area

OBJECTIVE: Hyperandrogenic anovulation is the principal risk factor for non-insulin-dependent diabetes mellitus (NIDDM) in young women. Since many of these women undergo depilatory therapy, the purpose of this study was to estimate the probability of undiagnosed glucose intolerance associated with hyperandrogenic anovulation among premenopausal women requesting electrolysis. DESIGN: Case-series study. INTERVENTIONS: Women (N = 791) attending one of 27 electrology clinics in the United States, Canada and Germany received questionnaires requesting anthropometric data; personal information regarding age, surgery and medication use, and family histories of excess hair growth in female relatives and diabetes in parents or siblings. RESULTS: Of 652 respondents less than age 50 years, 643 (98.6%) women had hirsutism, of whom 465 had regular menstrual cycles. One hundred seventy-eight (27.3%) women less than 50 years of age had hirsutism with irregular menses, and one-half of these women also were obese. Regardless of adiposity, one-third of hirsute women with menstrual irregularity knew the cause of their androgen excess, while the remaining two-thirds were unaware of the reason for their excess hair growth. CONCLUSIONS: Assuming a 20% risk of glucose intolerance in obese hyperandrogenic anovulatory women by the fourth decade of life, the estimated prevalence of undiagnosed glucose intolerance from hyperandrogenic anovulation is 1.7% among women requesting electrolysis before age 50 years.     

Assessment of duration and frequency of work tasks by telephone interview: reproducibility and validity

Quantitative estimation of physical work load requires breakdown of jobs into smaller entities. The objective was to study the inter-rater reproducibility of the contents, frequency and duration of work tasks assessed by telephone interview. Two researchers interviewed 18 industrial workers with an interval of from 2 to 3 weeks in a balanced and blinded design. Altogether 114 tasks were identified, 68 of which were recorded by both interviewers. The tasks were classified into regularly occurring (n = 34) and occasional (n = 80). The outcome was the total duration of the tasks per day computed from the data on frequency and duration. Validity of the interview was studied against prestructured diaries filled in by nine workers. The interviewers' assessments of the overall contents of the tasks were rated as 'similar' or 'very similar' for 17 of the 18 workers. Both interviewers detected all 34 regularly occurring tasks. The intraclass correlation coefficient (ICC) of the total duration between the interviewers was 0.81 for regularly occurring tasks. ICCs of the total duration between the diary and the two interviewers were 0.90 and 0.91. However, in many cases the workers could not give a numerical value for duration or frequency. A telephone interview can be used as a first step in exposure assessment in epidemiological studies on risk factors of musculoskeletal disorders. These results show that a single telephone interview can give reproducible and valid information of the frequency and duration of tasks occurring daily. For occasional tasks interview methods should be developed further.     

Laser-induced plasma spectroscopy to as low as 130 nm when a gas-purged spectrograph and ICCD detection are used

An experimental setup is described for measuring laser-induced plasma emission spectra in the near vacuum UV with a Czerny-Turner spectrograph and intensified charge-coupled device under atmospheric pressure. With a simple gas-purge technique, emission lines down to 130 nm could be recorded. The strongest emission lines of bromine, chlorine, and iodine in the near vacuum UV are easily detected.     

Astigmatic bessel laser beams

Abstract

The oblique incidence of a He-Ne laser beam onto a phase-only diffractive optical element (DOE) that simultaneously produces several unimode different-order Bessel beams propagating at various angles with respect to the optical axis is studied theoretically and experimentally. It is shown that, under obliquely incident illumination of a DOE that forms Bessel beams, the resulting astigmatic diffraction pattern can be used to unambiguously identify the direction of the Bessel beam's phase rotation and the order of the Bessel mode.     

Psychoendocrine concomitants in patients following a new design of a geriatric day-care unit

To identify common animal species by analysis of the cytochrome b gene a method has been developed to obtain PCR products of a large domain of the cytochrome b gene (981 bp out of 1140 bp) in humans, selected mammals and birds using the same specifically designed primers. Species-specific RFLP patterns are generated by co-restriction with the restriction endonucleases ALU I and NCO I. The RFLP patterns obtained are conclusive even in mixtures of two or more species. The results were confirmed by sequence analysis which in addition explained intraspecies variations in the RFLP patterns. The method has been applied to forensic casework studies where the origin of roasted meat, stomach contents and a bone sample has been successfully identified.     

Multi-angular reflectance properties of a hemiboreal forest: An analysis using CHRIS PROBA data

Forest types differ in their hyperspectral anisotropy patterns mainly due to species-specific geometrical structure, spatial arrangement of canopies and subsequent shadow patterns. This paper examines the multi-angular, hyperspectral reflectance properties of typical hemiboreal forests during summer time using three simultaneous CHRIS PROBA (mode 3) scenes and stand inventory data from the Järvselja Training and Experimental Forestry District in southeastern Estonia. We investigated the magnitude and reasons for the differences in the anisotropy patterns of deciduous and coniferous stands at three backward viewing angles. A forest reflectance model (FRT) was used as a tool to provide a theoretical basis to the discussion, and to estimate the directional contribution of scattering from crowns and ground to total stand reflectance for the two forest types. The FRT model simulated successfully the HDRF (hemispherical–directional reflectance factor) curves of the study stands to match those obtained from the CHRIS image, yet it produced a smaller and less wavelength-dependent angular reflectance effect than was observed in the satellite image. The main results of this study provide new information for separating the spectral contribution of the forest floor (or understory layer) from the tree canopy layer: (1) the red edge domain was identified to have the largest contribution from forest understory, and (2) the more oblique the viewing angle, the smaller the contribution from the understory. In addition, coniferous stands were observed to have a specific angular effect at the red and red edge domain, possibly as a result of the hierarchical structure and arrangement of coniferous canopies.     

Scanning Kelvin probe force microscopy study of chromium nitrides in 2507 super duplex stainless steel—Implications and limitations

The effect of chromium nitrides on localized corrosion resistance of 2507 super duplex stainless steel was investigated in this study. The Volta potential difference measured with scanning Kelvin probe force microscopy (SKPFM) indicates that chromium nitrides with the size range of 80–230 nm precipitated isothermally at the ferrite/austenite phase boundaries may detrimentally affect the corrosion resistance due to the observed local Volta potential drop at the phase boundaries. Small quenched-in nitrides with the size range of 50–100 nm formed in the centre of the ferrite phase, on the other hand, may have small or no adverse effect on the corrosion resistance since they showed no difference in Volta potential relative to the matrix.