Synthesis and Characterization of Segmented Block Copolymers Based on Hydroxyl‐Terminated Liquid Natural Rubber and α,ω‐Diisocyanato Telechelics

Summary: Segmented block copolymers, consisting of non‐polar soft segments from hydroxyl‐terminated liquid natural rubber (HTNR) and polar hard segments from α,ω‐diisocyanato telechelics obtained by “criss‐cross”‐cycloaddition, have been synthesized. The block copolymer formation took place under relatively mild reaction conditions at 80 °C in dichloroethane in the presence of dibutyltin dilaurate as a catalyst. The resulting block copolymers were characterized by spectroscopic techniques (¹H NMR, FTIR, UV‐vis spectroscopy) as well as GPC for molar mass determination. The block copolymers were compression molded in a hot stage press, and the resulting samples were characterized by DSC and stress‐strain measurement. The solubility and phase morphology of the materials have also been studied.

Segmented block copolymer from HTNR and α,ω‐diisocyanato telechelics     

Diastereoselective Heterogeneous Catalytic Hydrogenation of Aromatic or Heteraromatic Compounds

The diastereoselective hydrogenation catalyzed by heterogeneous metallic catalysts uses a covalently bound chiral auxiliary to induce the chirality. It remains an active synthetic methodology in the asymmetric synthesis of chiral products and may proceed with high diastereoselectivity. This review describes recent examples using this method, such as hydrogenation of C=C, C=O, and C=N bonds. The use of a chiral auxiliary group has also been successfully applied to the hydrogenation of aromatic and heteroaromatic rings. The choice of the chiral auxiliary was found to play a key role in the asymmetric hydrogenation. The results could be explained in terms of steric effect, with a preferred conformation of the adduct substrate and the addition occurring from the less bulky side. The catalytic metal, the support and the presence of additives were also found to have a significant influence.     

一种基于Fuzzy ART的层次化彩色图像分割算法

针对传统彩色图像分割中出现的单纯利用颜色空间,只考虑图像的全局分布,或是只考虑图像的局部区域和边缘信息等问题,提出了一种基于Fuzzy-ART模型的层次化彩色图像分割算法。该算法有效地利用图像的亮度空间分布、细节信息以及颜色空间信息,对图像进行分级特征提取,利用Fuzzy-ART模型基于人类视觉特性的稳定、快速的在线学习和记忆能力,对图像进行层次化的区域划分,形成对图像的分层表达方式,从而达到良好的分割效果;将其与FFCM算法进行比较,取得了较好的结果。     

ASSIMILATION AND ATTACHMENT IN THE CONTEXT OF INTERNATIONAL MIGRATION: THE CASE OF GUESTWORKERS IN GERMANY

"Immigrants' attachments to home and their assimilation into the host society have been identified as major factors influencing international return migration. This paper provides an empirical analysis of the determinants of attachment and assimilation, with a special focus on the impact of duration of stay. Using survey data on guestworkers in West Germany in 1984 and 1989, the study finds that assimilation increases at a decreasing rate as the duration of stay is extended. The relationship between attachment and length of stay is less strong, but shows a general trend of decreasing attachment levels as guestworkers prolong their stay in Germany. The resulting trends for return migration are characterized by an overall decline in the propensity to return as the duration of stay is extended. However, the rate of decline varies by gender, marital status, and nationality. Overall, the results allude to the importance of distinguishing between short term and long term immigrants."     

Fiber-optic array algebraic processing architectures

A high-accuracy fiber-optic array processor (FOAP) based on the algorithm of digital multiplication by analog convolution is proposed. The FOAP architecture is a local regularly interconnected processor that utilizes an array of identical all-optical elemental-processing lattice units, namely, an optical splitter, an optical combiner, and a binary programmable fiber-optic transversal filter. Various FOAP matrix multipliers are proposed for nonnegative and twos-complement binary arithmetic matrix-vector, matrix-matrix, triple-matrix, and high-order matrix operations. The overall performances of the FOAP matrix multipliers are compared with the time-integrating and space-integrating architectures and with the digital multipliers. Extension of the digital-multiplication-by-analog-convolution algorithm is also considered.     

Ecological assessment of Phragmites australis wetlands using multi-season SPOT-5 scenes

Ecologists and conservationists need accurate and replicable tools for monitoring wetland conditions in order to develop and implement adaptive management strategies efficiently. The Rhone Delta (Camargue) in southern France encloses 9200 ha of fragmented reed marshes actively managed for reed harvesting, waterfowl hunting or cattle grazing, and holding significant numbers of vulnerable European birds. We used multi-season SPOT-5 data in conjunction with ground survey to assess the predictive power of satellite imagery in modelling indicators of reed structure (height, diameter, density and cover of green/dry stems) relevant to ecosystem management and bird ecology. All indicators could be predicted accurately with a combination of bands (SWIR, NIR) and indices (SAVI, OSAVI, NDWI, DVI, DVW, MSI) issued from scenes of March, June, July, September or December and subtraction between these. All models were robust when validated with an independent set of satellite and field data. The high spatial resolution of SPOT-5 scenes (pixel of 10 × 10 m) permits the monitoring of detailed attributes characterizing the reed ecosystem across a large spatial extent, providing a scientifically-based, replicable tool for managers, stakeholders and decision-makers to follow wetland conditions in the short and long-term. Combined with models on the ecological requirements of vulnerable bird species, these tools can provide maps of potential species ranges at spatial extents that are relevant to ecosystem functioning and bird populations.