Solution intercalation of polystyrene and the comparison with poly(ethyl methacrylate)

Polystyrene nanocomposites have been prepared via solution intercalation method. Combination of wide-angle X-ray diffraction and thermogravimetric analysis is used to study the effect of solvents on the morphology of the nanocomposites as a function of the amount of residual solvent. d-Spacing of the polystyrene nanocomposites has a minimum value when the residual solvent concentration is between 2 and 4 wt%. Different interaction level between the solvent molecules and polymer chains is considered to be the reason for this special d-spacing change behavior. By comparing the solution intercalation of polystyrene and poly(ethyl methacrylate) from different solvents, it is concluded that the interactions between polymer-surfactant, solvent-surfactant, and polymer-solvent play important role for the solution intercalation of polymers.     

标准椅全身计数器对不同年龄组均匀体模源全能峰效率的刻度

本文介绍了用标准液体源均匀充入聚氯乙烯制的体模,刻度标准椅全身计数器〔φ8″×4″(NaI)〕的方法和结果。分别就代表6个年龄组的体模,测定了标准椅全身计数器对5种能量(364,637,898,1460和1836keV)γ射线的全能峰效率;给出了全能峰效率与γ射线能量和被测对象体重的关系曲线。     

铜锌铝合金表面非线性振荡花样的研究

在Ｃｕ－Ｚｎ－Ａｌ形状记忆合金表面观察到尚未被人们认识的非线性振荡花样。这些花样经计算机图像处理得知，在空间和时间上明显呈现分形特征。这种振荡花样的产生可能与未知相变的预转变过程有关。     

面向Web服务的制造企业业务流程管理集成应用研究

本文在探讨现代制造企业对信息资源与技术的实际需求基础上，针对企业在信息系统架构方面形成的一个个“信息孤岛”，采用企业应用集成(EAI)方法和技术，提出面向分布式网络环境下基于Web服务的企业业务流程管理集成应用解决方案与实现途径，有力地促进了企业实现各种遗产系统与新的企业应用系统的集成，更进一步促进制造企业加速实现信息化工程。     

数控车床镗孔刀座的车削试验与结构改进设计

文章结合笔者的实际工作,具体介绍了当前数控车床镗孔刀座的车削试验,分析了镗孔刀座未改之前与改进之后对镗孔震动的作用和影响,为如何有效地解决镗孔震动的问题进行了研究和总结.     

工程图学课中的能力培养与实体建模技术

论述了工程图学引入"融入式"教学的必要性,提出在工程图学课程体系中融入实体建模技术的基本思路.     

Minimizing Energy Barrier in Intermediate Connection Layer for Monolithic Tandem WPeLEDs with Wide Color Gamut

Perovskite light-emitting diodes (PeLEDs) show promising prospects in the wide color gamut display owing to their ultra-narrow full width at half maximum (FWHM). However, up to now, all perovskite white LEDs integrated by standard red, green, and blue perovskite emitters, namely, monolithic white PeLEDs (WPeLEDs), have been rarely reported, owing to facing some issues, e.g., solvent incompatibility in solution technique, ion exchange, and energy transfer between different emission centers. Herein, centered on these issues, an optimal intermediate connection layer (ICL) of Po-T2T/LiF/Ag/HAT-CN/MoO₃ is adopted to successfully develop monolithic tandem multicolor PeLEDs and WPeLEDs for the first time. The multicolor PeLEDs can achieve the best external quantum efficiency of 1.8% and the highest luminance of 4844 cd m⁻². Besides, the red/green/blue (R/G/B) monolithic tandem WPeLED shows a standard white International Commission on Illumination coordinate of (0.33, 0.33) and achieves an extremely wide color gamut reaching  National Television Standards Committee of 130%. This study is the first to realize the standard R/G/B co-electroluminescence in a monolithic perovskite device and offers a feasible strategy for developing wide-color gamut perovskite displays.     

In Situ Topochemical Transformation of ZnIn2S4 for Efficient Photocatalytic Oxidation of 5-Hydroxymethylfurfural to 2,5-Diformylfuran

Photocatalytic selective oxidation of 5-hydroxymethylfurfural (HMF) coupled H₂ production offers a promising approach to producing valuable chemicals. Herein, an efficient in situ topological transformation tactic is developed for producing porous O-doped ZnIn₂S₄ nanosheets for HMF oxidation cooperative with H₂ evolution. Aberration-corrected high-angle annular dark-field scanning TEM images show that the hierarchical porous O-ZIS-120 possesses abundant atomic scale edge steps and lattice defects, which is beneficial for electron accumulation and molecule adsorption. The optimal catalyst (O-ZIS-120) exhibits remarkable performance with 2,5-diformylfuran (DFF) yields of 1624 µmol h⁻¹ g⁻¹ and the selectivity of >97%, simultaneously with the H₂ evolution rate of 1522 µmol h⁻¹ g⁻¹. Mechanistic investigations through theoretical calculations show that O in the O-ZIS-120 lattice can reduce the oxidation energy barrier of hydroxyl groups of HMF. In situ attenuated total reflection surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS) results reveal that DFF^* (C₄H₂(CHO)₂O^*) intermediate has a weak interaction with O-ZIS-120 and desorb as the final product. This study elucidates the topotactic structural transitions of 2D materials simultaneously with electronic structure modulation for efficient photocatalytic DFF production.     

Sandwiched Thin‐Film Anode of Chemically Bonded Black Phosphorus/Graphene Hybrid for Lithium‐Ion Battery

A facile vacuum filtration method is applied for the first time to construct sandwich‐structure anode. Two layers of graphene stacks sandwich a composite of black phosphorus (BP), which not only protect BP from quickly degenerating but also serve as current collector instead of copper foil. The BP composite, reduced graphene oxide coated on BP via chemical bonding, is simply synthesized by solvothermal reaction at 140 °C. The sandwiched film anode used for lithium‐ion battery exhibits reversible capacities of 1401 mAh g^?1 during the 200th cycle at current density of 100 mA g^?1 indicating superior cycle performance. Besides, this facile vacuum filtration method may also be available for other anode material with well dispersion in N‐methyl pyrrolidone (NMP).     

循环经济视角下高校快递包装物回收模式优化研究

为了优化现有回收模式,提出高校后勤部门与校园快递代理点协同回收快递包装物模式,运用Stackelberg博弈构建模型求出最优快递包装物价格和回收率的关系式,并分析两者的主要影响因素。高校可以通过改变奖惩力度,来控制快递代理点及后勤部门对快递包装物的回收率;采用教育和奖惩相结合的方式提高学生回收意识,充分调动学生的积极性,以保障高校环境清洁,促进资源循环利用。