Preparation and characterization of PEGDE crosslinked silk fibroin film

To obtain water-insoluble silk fibroin(SF) materials, polyethylene glycol diglycidyl ether(PEG-DE) was selected as a crosslinking agent to prepare SF films(blends). The reaction conditions were optimized for the crosslinking of the SF molecules. The hot water stability of the blends was measured using BCA protein assay and gravimetric analysis. The molecular conformation and crystalline structure of the blends were analyzed by FTIR and XRD, respectively. When the mass ratio of SF:PEG-DE was 1.0:0.8, the hot water loss rate of the SF blends was minimized. PEG-DE could induce SF molecules to form β-sheets during the gel reaction process, resulting in improved crystallinity and hot water dissolved resistance of the blend films. In order to demonstrate the cytotoxicity of the chemical reagents used to crosslink SF, L929 cells were seeded on the blend film(SF:PEG-DE = 1:1) and cultured for 3 days. Cells of L929 readily adhered and spread in the fusiform on the blend film resulting in high cell viability. The extracted liquid from the SF porous film did not inhibit cell proliferation, as estimated by the MTT assay.     

江垭水电站碾压混凝土重力坝的温度应力分析

为研究温度荷载对江垭水电站碾压混凝土重力坝的影响,以其非溢流坝段为研究对象,建立有限元模型,根据江垭水电站的水温、气温、坝体温度、地基温度等监测资料,计算分析了大坝运行期的温度场,研究了大坝在温度场影响下的应力变化规律.研究结果表明:温度荷载对大坝运行有较大影响,但是大坝仍满足规范设计要求;夏季持续高温时,应避免大坝在高水位下运行;冬季持续低温时,应避免大坝在低水位下运行.     

大型预应力梁式渡槽动力特性分析

渡槽结构的动力特性分析是渡槽结构地震响应分析及抗震设计的基础.采用有限元分析软件ANSYS对滏阳河渡槽进行动力特性分析,水体和槽壁之间的相互作用采用附加质量法来处理,计算分析矩形渡槽在不同水深时的自振频率和主振型.计算结果表明:水体对渡槽结构主振型的影响可以忽略不计,但是对渡槽结构自振频率的影响很大;渡槽的频率随水深的加深而减小.研究结果可以为滏阳河渡槽的抗震设计及其防护提供依据.     

镀锡K板板面烧蚀缺陷形成机理研究

宝钢在生产K板过程中,在高锡层面易产生针尖状烧蚀缺陷．本文通过扫描电镜和光学轮廓仪观察了其微观形貌,应用能谱仪分析了烧蚀内部成分,并分析了缺陷的产生原因．结果表明,烧蚀呈火山口形貌,大小为0．2～0．6mm．其产生是由于带钢与软熔接地辊辊面接触不良引发局部大电流电弧放电,导致带钢局部温度急剧升高,引起板面锡层熔化而形成的．提出了预防该缺陷的措施：保持软熔接地辊辊面及淬水槽溶液清洁,并在软熔接地辊前增加热风喷吹装置．将上述措施应用于实际生产中,避免了镀锡K板板面烧蚀缺陷的产生．     

Effective model based fault detection scheme for rudder servo system

The inherent nonlinearities of the rudder servo system（RSS） and the unknown external disturbances bring great challenges to the practical application of fault detection technology. Modeling of whole rudder system is a challenging and difficult task. Quite often, models are too inaccurate, especially in transient stages. In model based fault detection, these inaccuracies might cause wrong actions. An effective approach, which combines nonlinear unknown input observer（NUIO） with an adaptive threshold, is proposed. NUIO can estimate the states of RSS asymptotically without any knowledge of external disturbance. An adaptive threshold is used for decision making which helps to reduce the influence of model uncertainty. Actuator and sensor faults that occur in RSS are considered both by simulation and experimental tests. The observer performance, robustness and fault detection capability are verified. Simulation and experimental results show that the proposed fault detection scheme is efficient and can be used for on-line fault detection.     

铁电薄膜平均极化性质的研究

是在热力学唯象理论的框架下,研究由两种铁电材料组成的铁电双层膜系统的极化性质.通过引入的两个参量:参量(描述铁电双层膜系统中两种铁电体的物理性能差异)和参量(描述铁电双层膜系统两种铁电体相变温度的差异),研究了不同温度和不同界面耦合系数条件下,铁电双层膜系统平均极化随这两个参量的变化情况.研究表明:参量增大时,铁电双层膜系统的平均极化随之增大.当取固定值时,平均极化随界面耦合系数增大而增大;随着温度t、参量的增大而减小.参量增大时,铁电双层膜系统的平均极化减小.当参量取固定值时,平均极化随着温度t的增大而减小;随着参量、界面耦合系数的增大而增大.     

渤海油田弱凝胶与泡沫复合调驱体系优化

采用流变、常规量筒法、扫描电镜及显微镜,研究了优选出的3种弱凝胶与SD发泡剂的复配体系的起泡性能、黏度、稳定性以及微观结构。结果表明,起泡剂与弱凝胶复配之后,体系的各项性能得到明显改善。复配体系半衰期增大,泡沫黏度增大,稳定性增强,明显优于单一体系。在弱凝胶与泡沫复合调驱体系中,凝胶易在气泡表面形成吸附膜,将泡沫包裹在内部,增强了气液界面的黏度,使得泡沫不容易发生聚并破裂,从而增强了泡沫的稳定性以及黏度,使得其半衰期也增大。     

地源热泵钻孔布置形式对土壤温度场的模拟研究

本文采用数值模拟的方法,通过模拟土壤源热泵井群不同的布置方式,比较相同孔间距时钻孔叉排和顺排布置时的区域热效率,得到在面积一定的条件下,相同的孔间距时,叉排布置更有利的结论.     

中小企业融资困境分析及对策研究

针对中小企业目前融资困难的现象,从企业、政府以及银行三个方面分析造成困境的原因并以此探析解决方法。提出一方面作为外部力量的政府和银行,要注重融资环境的改善,加大政策扶持,转向中小企业客户,另一方面中小企业利用强大的企业家个人能力在企业的社会关系网络中寻求多方融资渠道,以解决中小企业融资问题。     

一种前向安全的基于身份的非交互密钥分发协议

基于身份的非交互密钥分发协议（identity-based non-interactive key distribution,ID-NI-KD）允许通信双方在没有信息交互的情况下生成一个共享密钥.具有前向安全性的ID-NIKD一直是基于身份的非交互密钥分发协议这一研究方向的一个公开问题.文献[1]分析指出文献[2]给出的前向安全的ID-NIKD方案是不具有前向安全的,并给出了攻击方法.文章针对文献[1]提出的攻击,借鉴文献[2]的思想,给出了一个具有前向安全的ID-NIKD方案,并给出了新方案在文献[2]的安全模型下的安全性证明.