The nature and role of incoherent interphase interfaces in diffusional solid-solid phase transformations

In this article, some views on the nature of incoherent interphase interfaces, and their role in the nucleation and growth processes governing the evolution of microstructure in solid-state diffusional transformations (reconstructive transformations), are explored. It is argued that essentially incoherent interfaces can be involved in the initiation and propagation of polymorphic transformations and massive transformations as well as in various precipitation phenomena in metallic and ceramic systems. Similar views have already been advanced earlier in connection with studies of massive transformations. Faceting along the interphase interface during nucleation and growth can derive from thermodynamic, kinetic, and crystallographic factors independent of the bicrystallography of the conjugate phases. This idiomorphic behavior can be relevant to both intergranular and intragranular phase formation. The concept of one-dimensional (1-D) commensuration of phases through plane edge-to-edge/row matching is an interesting extension of the classic ideas of coherency and bicrystallography and potentially important in characterizing the behavior of certain types of boundaries. However, the general importance of these geometrical relations in real and reciprocal space will depend on the depth of the energy wells in orientation space associated with these special boundaries. This article is based on a presentation made in the “Hume-Rothery Symposium on Structure and Diffusional Growth Mechanisms of Irrational Interphase Boundaries,” which occurred during the TMS Winter meeting, March 15–17, 2004, in Charlotte, NC, under the auspices of the TMS Alloy Phases Committee and the co-sponsorship of the TMS-ASM Phase Transformations Committee.     

Synthesis of minerals using alternative energy sources

A technology for the synthesis of synthetic minerals (using the example of spinels) using a low-temperature plasma flame is developed. The diagnostic properties of spinels are identified.     

Recursive regularization filters: design, properties, andapplications

Least squares approximation problems that are regularized with specified highpass stabilizing kernels are discussed. For each problem, there is a family of discrete regularization filters (R-filters) which allow an efficient determination of the solutions. These operators are stable symmetric lowpass filters with an adjustable scale factor. Two decomposition theorems for the z-transform of such systems are presented. One facilitates the determination of their impulse response, while the other allows an efficient implementation through successive causal and anticausal recursive filtering. A case of special interest is the design of R-filters for the first- and second-order difference operators. These results are extended for two-dimensional signals and, for illustration purposes, are applied to the problem of edge detection. This leads to a very efficient implementation (8 multiplies+10 adds per pixel) of the optimal Canny edge detector based on the use of a separable second-order R-filter     

Effect of the magnetic-flux variations on SQUID stability

The oscillation dynamics of a nonhysteretic, one-contact superconducting quantum interferometer under low-frequency modulation of an external magnetic flux has been studied. It is shown that even in the case of adiabatic, equilibrium, and nonhysteretic operation modes of a superconducting ring enclosed by a weak link, there can appear chaotic oscillations. The conditions of chaos arising have been considered analytically and numerically; mechanisms and destruction scenarios of periodic oscillations have been studied. The stochastic instability could impose limitations on the increase in sensitivity of nonhysteretic SQUIDs, which was earlier predicted to be high enough.     

Kinetic aspects of deactivation of catalysts in prolonged use

A theoretical approach to the dynamic analysis of deactivation and aging of heterogeneous catalysts is proposed — analysis of the rate derivative in a kinetic equation of a given form. Methodology was demonstrated for the simplest kinetic equations — zero-and first-order. Regardless of the form of the kinetic equation for the dynamic model of deactivation, the rate constant is a function of an independent reaction coordinate. The method can also be used for solving reactivation problems and for explaining the dynamics of cation exchange in zeolite. __________ Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 1, pp. 3–34, January–February, 2006.     

俄罗斯极北地区的水电工程

俄罗斯极北地区的水电工程解决了许多在严寒条件和永冻土上进行施工的难题；表明水电站的修建是可行的，投入是很低的。这些水电站建成后都能在一定程度上满足北方地区的用电需求。     

Identification and modelling of aerobic hydrolysis – application of optimal experimental design

Hydrolysis mechanism plays a dominant role in the delicate balance of electron donor/electron acceptor ratios in BNR and EBPR systems as an important carbon source. In this study, the surface‐saturation‐type hydrolysis kinetics was investigated based on respirometric measurements, within the context of the theoretical and the practical identifiability of mathematical models. The identifiable parameters of a selected model were derived from respirograms. In addition, the information from the experiments was evaluated on the basis of Optimal Experimental Design (OED) methodology for different initial conditions of the batch respirometric experiment. © 2003 Society of Chemical Industry     

Tunneling recombination in spatially inhomogeneous structures

Methods for finding the parameters (energies and capture coefficients for electrons and holes) of the levels involved in the formation of the recombination flux are suggested. The temperature variation of these parameters for AlGaN/InGaN/GaN and InGaN/SiC structures is discussed. The parameters of the levels responsible for tunneling recombination are determined.