The Inhibition Performance of trans-Cinnamaldehyde as a Green Compound for Mild Steel in Acidic 1 M HCl Medium: Correlation between Experimental and Theoretical Studies

Protection of Metals and Physical Chemistry of Surfaces - Corrosion inhibition propriety of (2E)-3-phenylprop-2-enal, known as trans-cinnamaldehyde (TCA) for mild steel in 1 M HCl medium was...     

Low temperature synthesis of <Emphasis Type="Italic">Manganese tungstate</Emphasis> nanoflowers with antibacterial potential: Future material for water purification

Pure water is the fundamental requisite for human life. The water has been recycled naturally but not in an adequate amount for consumption. Nanotechnology with extraordinary applications provides competent ways for the decontamination of contaminated water. In the present study MnWO₄ nanoflowers endorsed with inherent antibacterial activity were successfully synthesized by facile hydrothermal approach. XRD, SEM, EDX spectroscopy and UVDRS were used to characterize the as-synthesized nanoflowers. Gram negative Escherichia coli ATCC 52922 bacterium was used as model organism to test antibacterial activity of as-synthesized MnWO₄ nanoflowers. This study was conducted to optimize minimum concentration of MnWO₄ nanoflowers and maximum contact time required to achieve complete inactivation of bacteria present in contaminated water. Minimum inhibitory concentration (MIC) of MnWO₄ nanoflowers was found to be 10 μg/ml. The assessment and interpretation of bacterial viability was done using dual fluorescent staining. The synthesized 3D-nanoflowers were found as potent bactericides. Thus, MnWO₄ nanoflowers emerged to be very good future material for disinfection of biological pollutants present in the contaminated water reservoirs and as an anti-biofouling agent.     

Perpendicular Weak Permanent Magnetic Field Effect on the Electrodeposited Nanostructured ZnO Film and its Kinetic Corrosion Behavior

Protection of Metals and Physical Chemistry of Surfaces - In this work the effect of the permanent weak magnetic field on the electrodeposited ZnO nanostructured film on the ITO substrate...     

Biosorption potential of the mediterranean plant (Posidonia oceanica) for the removal of Cu2+ ions from aqueous media : Equilibrium,kinetic, thermodynamic and mechanism analysis

The biosorption characteristics of copper(II) ions using Posidonia oceanica biomass were investigated. Experimental parameters affecting the biosorption process such as pH level, contact time, biosorbent dosage and temperature were studied. The equilibrium data were applied to the Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm models. The Langmuir model fitted very well the equilibrium data, and the maximum uptake of Cu(II) by Posidonia oceanica was found to be 76.92 mg/g. The mean free energy E (10.78 kJ/mol) from the D-R isotherm indicated a chemical ion-exchange mechanism. Kinetic results showed that the pseudo-second-order kinetic model was well fitted to the experimental data. Thermodynamic parameters depicted the exothermic nature of biosorption and the process was feasible and spontaneous. The results of FTIR (Fourier-transform infrared spectroscopy) revealed that carboxyl, amine, and hydroxyl groups on the biomass surface were involved in the biosorption of Cu(II) ions.     

Palyno‐morphological characteristics of gymnosperm flora of pakistan and its taxonomic implications with LM and SEM methods

The present study is intended to assess gymnosperms pollen flora of Pakistan using Light Microscope (LM) and Scanning Electron Microscopy (SEM) for its taxonomic significance in identification of gymnosperms. Pollens of 35 gymnosperm species (12 genera and five families) were collected from its various distributional sites of gymnosperms in Pakistan. LM and SEM were used to investigate different palyno‐morphological characteristics. Five pollen types (i.e., Inaperturate, Monolete, Monoporate, Vesiculate‐bisaccate and Polyplicate) were observed. Six In equatorial view seven types of pollens were observed, in which ten species were sub‐angular, nine species were Traingular, six species were Perprolate, three species were Rhomboidal, three species were semi‐angular, two species were rectangular and two species were prolate. While five types of pollen were observed in polar view, in which ten species were Spheroidal, nine species were Angular, eight were Interlobate, six species were Circular, two species were Elliptic. Eighteen species has rugulate and 17 species has faveolate ornamentation. Eighteen species has verrucate and 17 have gemmate type sculpturing. The data was analysed through cluster analysis. The study showed that these palyno‐morphological features have significance value in classification and identification of gymnosperms. Based on these different palyno‐morphological features, a taxonomic key was proposed for the accurate and fast identifications of gymnosperms from Pakistan.     

Removal of the persistent pollutant chlorobenzene by adsorption onto activated montmorillonite

The potential of activated bentonite was assessed for adsorption of chlorobenzene from aqueous solution. The bentonite used was treated by chemical and thermal activation over 100–500 °C. The thermal activation increased the adsorption capacity more strongly than chemical activation which consists to acid and hydrogen peroxide treatment. The removal is dominated by adsorption at low initial concentrations and low temperatures and favourable in acidic media. The dependence of the adsorption on pH appears to be related to the solubility of chlorobenzene. Thermodynamic parameters such as ΔH°, ΔS°, ΔG° and Ea have been calculated. The adsorption process is spontaneous and exothermic in nature. The Freundlich isotherm described the adsorption data over the concentration range (20–270 °C).     

New formulation of GNSS acquisition with CFAR detection

This paper deals with the analysis of the acquisition process performed by a global navigation satellite system (GNSS) receiver with a pilot and data channel or in case of GNSS hybrid receiver. Signal acquisition decides the presence or absence of GNSS signal by comparing signal under test with a fixed threshold and provides a code delay and a Doppler frequency estimation, but in low signal conditions or in a noisy environment; acquisition systems are vulnerable and can give a high false alarm and low detection probability. Firstly, we introduce a cell‐averaging‐constant false alarm rate (CFAR) then a data‐pilot cell‐averaging‐CFAR detector fusion based to deal with these situations. In this context, we use a new mathematical derivation to develop a closed‐form analytic expressions for the probabilities of detection and false alarm. The performances of the proposed detector are evaluated and compared with a non‐CFAR case through an analytical and numerical results validated by Mont Carlo simulations. Copyright © 2016 John Wiley & Sons, Ltd.     

Tracing the evolution of HCI patterns as an interaction design tool

Design patterns have been introduced as a medium to capture and disseminate the best design knowledge and practices. In the field of human–computer interaction, practitioners and researchers have explored different avenues to use patterns and pattern languages as design tools. This paper surveys these avenues—from individual pattern use for solving a specific design problem, to pattern-oriented design, which guides designers in building a conceptual design by leveraging relationships between patterns. One of our underlying goals is to investigate how patterns can be used, not only to foster the reuse of proven and valid design solutions, but also as a central artefact in the process of deriving a design from user experiences and requirements. We will present our investigations on pattern-based design, and discuss how user experiences can be incorporated in the pattern selection process through the use of user variables, pattern attributes and associated relationships.     

Passive mixing control for innovative air diffusion terminal devices for buildings

This paper presents an innovative concept for optimized air diffusion in buildings. The method uses passive control of air jet through lobed diffusers. An analysis is done experimentally at different scales for a lobed shaped geometry. A cross-shaped jet is characterized first through an isolated orifice and then at the scale of one perforated panel. An intermediary analysis of two coalescent and a row of cross-shaped jets is also proposed. All the results lead to the same conclusion. The lobed diffuser favors the self-induction compared to a reference conventional circular perforated diffuser. The air flow induced in the case of the lobed perforated panel is in average twice as the one of the circular perforated panel. Despite the consequent gain in air induction for the lobed perforated panel flow, the streamwise maximum velocities display comparable values in the far field which signifies comparable throws for the two flows. Consequently, the presented lobed perforated panel concept can be generalized to different type of diffusers to improve mixing ventilation in buildings.