The role of the experimental data base used to identify material parameters in predicting the cyclic plastic response of an austenitic steel

The first objective of this paper investigates the influence of the previous strain history on ratcheting. New tests were performed where different strain-controlled histories have been applied prior to ratcheting tests. It is demonstrated that under the same conditions, one can observe ratcheting, plastic shakedown or elasticity according to the prior strain-controlled history. The second objective points out the correlation between the experimental data base devoted to the identification of the material parameters and the quality of the predictions in cyclic plasticity. The results suggest that the choice of the tests should be closely linked to the capabilities of the model. In particular, the presence of non proportional strain-controlled tests in the data base may be not a good choice if the model itself is not able to represent explicitly such a character. All tests considered here were performed on 304L SS at room temperature.     

Adsorption of Alkanethiols on Gold Surfaces: PM-IRRAS Study of the Influence of Terminal Functionality on Alkyl Chain Orientation

The present paper focuses on a simplified method to study the orientation and the anisotropy of two different alkanethiols self-assembled monolayers on gold surfaces. The alkanethiols of interest vary only by their terminal functionalities (COOH and COOCH₃), thus allowing one to highlight the influence of these ending chemical groups on the final orientation of the adsorbed molecules. 11-Mercaptoundecanoic acid [HS-(CH₂)₁₀-COOH] and the methyl-11-mercaptoundecanoate [HS-(CH₂)₁₀-COOCH₃] were grafted under adequate conditions to obtain a high grafting density on gold substrates. These latter, before and after the alkanethiol adsorption, were analyzed mainly by the polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS) technique to access orientation angles, and by atomic force microscopy (AFM) to check the homogeneity of the grafted layer.

By applying an original PM-IRRAS simplified method, the results showed an orientation closer to the normal of the surface plane in the case of the acid thiol compared with the ester one, which is probably because of the lateral hydrogen bonds established between the adjacent COOH functions. This method offers a direct and simple way to quantify the orientation angles in the alkanethiol nanofilms.     

Theatre in the Sky: a ubiquitous broadband multimedia‐on‐demand service over a novel constellation composed of quasi‐geostationary satellites

To meet an ever‐growing demand for wideband multimedia services and electronic connectivity across the world, development of ubiquitous broadband multimedia systems is gaining a tremendous interest at both commercial and academic levels. Satellite networks will play an indispensable role in the deployment of such systems. A significant number of satellite communication constellations have been thus proposed using Geostationary (GEO), Medium Earth Orbit (MEO), or Low Earth Orbit (LEO) satellites. These constellations, however, either require a potential number of satellites or are unable to provide data transmission with high elevation angles. This paper proposes a new satellite constellation composed of Quasi‐GeoStationary Orbit (Quasi‐GSO) satellites. The main advantage of the constellation is in its ability to provide global coverage with a significantly small number of satellites while, at the same time, maintaining high elevation angles. Based on a combination of this Quasi‐GSO satellites constellation and terrestrial networks, the paper proposes also an architecture for building a global, large‐scale, and efficient Video‐on‐Demand (VoD) system. The entire architecture is referred to as a ‘Theatre in the Sky’. Copyright © 2006 John Wiley & Sons, Ltd.     

About the influence of temperature and matrix ductility on the behavior of carbon woven-ply PPS or epoxy laminates: Notched and unnotched laminates

Could thermoplastic-based composites be used to replace thermosetting-based composites in high-temperature secondary aircraft structures? The purpose of this work is to establish the ability of a material system to be used in aircraft engine nacelles when subjected to static loadings, with a key upper temperature of 120 °C. In order to provide answers to this question, the thermo-mechanical behaviors of carbon fiber fabric reinforced PPS or epoxy laminates have been compared specifically within the temperature change with 120 °C at the upper bound. The temperature-dependent ductile behavior of laminates is more or less exacerbated, depending on polymers glass transition temperature, and laminates stacking sequence. For both materials, the degree of retention of tensile mechanical properties is quite high in notched and unnotched quasi-isotropic laminates. A Digital Image Correlation technique has been used in order to understand the influence of temperature and matrix ductility on the mechanisms of overstresses accommodation near the hole. In fabric reinforced laminates, the high-temperature results suggest a competition between the mechanisms of damage, and the mechanism of plasticization, enhanced in angle-ply lay-ups. Thus, the highly ductile behavior of TP-based laminates, at temperatures higher than their T_g, is very effective to accommodate the overstresses near the hole.     

Single molecule magnets on a gold surface: in situ electrospray deposition, x-ray absorption and photoemission

Single molecule magnets based on the dodecamanganese (III, IV) cluster with two different types of ligand (acetate and benzoate) have been studied on the Au(111) surface. Due to the non-volatile and fragile nature of the molecules, we have used ultra-high vacuum electrospray deposition to produce a series of surface coverages from a fraction of a monolayer to multilayer films in both cases. Synchrotron radiation based electron spectroscopy has been used to study the adsorption of the molecules on the Au(111) surface and the effect that this has on the oxidation states of the manganese atoms in the core. In both cases, reduction of the core is observed due to the interaction with the surface, to essentially the same extent despite substantial differences in the size and nature of the ligand shell.     

Operation of quantum-dot semiconductor optical amplifiers under nonuniform current injection

The influence of nonuniform current injection along the active region, on the linear operation of a quantum-dot semiconductor optical amplifier (QD-SOA) is investigated. For this purpose, we have utilized some functions to generate various nonuniform current injection profiles. These profiles have been considered in our numerical calculations, where the rate equation model is employed to construct different characteristics of the QD-SOA. We have found that the gain, as well as the crosstalk, of a QD-SOA is closely associated to the variance of the carrier density along the cavity. Simulation results show that nonuniform current injection can be used as a technique for gain enhancement as well as crosstalk suppression.     

A comparison of three turbulence models for the prediction of parallel lobed jets in perforated panel optimization

The general context of the present study is the design of high induction HVAC air diffusers by means of passive jet control. When the diffuser is a perforated panel with lobed orifices (Meslem et al. 2010), the optimization of jet induction consists in improving the orifice’s geometry, the spacing between orifices and their arrangement on the panel. In this study, the flow field of a turbulent twin cross-shaped jet is investigated numerically using the standard k-ε model, the Shear Stress Transport (SST) k-ω model and the Reynolds Stress Model (RSM). The results are compared with PIV measurements. The objective is to assess their capability and limitations to predict the significant features of twin jet flow when the flow is numerically resolved through a lobed diffuser. It is shown that the k-ε and RSM models are more appropriate for predicting potential jet core length, the change in jet centreline streamwise velocity, and flow expansion in the symmetry plane of the twin jet flow. However, these models overestimate the overall flow expansion and the jet volumetric flow rate. The SST k-ω model seems more appropriate for the prediction of such dynamic integral quantities. A high level of turbulent kinetic energy predicted by the k-ε and RSM models in the near field of jets is probably the reason for this overestimation of jet induction. The SST k-ω model would appear to be the most appropriate tool for optimizing orifice design, orifice to orifice spacing and relative orifice orientation on a perforated panel diffuser.