Zur Desorption von mit leichtflüchtigen chlorierten Kohlenwasserstoffen (LCKW) beladenen Adsorberpolymeren

To verify the regeneration of novel crosslinked polymeric adsorbents the desorption of VCHC loaded polymeric adsorbents was investigated and compared to activated carbons. Desorption methods used were thermal analysis, steam regeneration, hot inert gas and solvent regeneration. It was proven that the novel crosslinked polymeric adsorbents were effectively desorbed both by thermal desorption methods and by organic solvents. Thereby, the desorption of the polymeric adsorbents proceeds faster and more complete than of the activated carbons.     

First experiences with the new W7-X like control system at the WEGA stellarator

The new quality of the superconducting fusion device Wendelstein 7-X (W7-X) is its capability of steady state operation. Additionally the fusion device W7-X is a very complex technical system. The modular and strongly hierarchical control system has been designed to cope with these two requirements unique for fusion devices.To minimize the risks before commissioning the control and data acquisition system at W7-X it will be thoroughly tested in a prototype installation at the WEGA stellarator. WEGA is a classical stellarator which allows steady state plasma pulses at a magnetic field of 0.5 T. Despite its lesser complexity WEGA has the same main components, e.g. magnetic coil systems, ECRH, and diagnostics as W7-X and is therefore considered to be a suitable test-bed for the control system.The installation of the new W7-X like control and data acquisition system has been finished in March this year. Individual components of the control system have already been commissioned during the installation phase. In April final commissioning and testing of the complete system took place. First discharges fully controlled by the prototype control system have been realized.The contribution will focus on first discharges controlled by the new system. Furthermore it presents first experiences that will incorporate into the further development of the control system and the tools for planning, preparation, and realization of plasma discharges.     

Common browsing and retrieval of technical and experimental data for steady state experiments

Steady state experiments like Wendelstein 7-X have to deal with large amounts of data of different kind. Discharge lengths may last from less than a second up to 30 min. During this time diagnostics will measure data in different discharge phases with different rates depending on the physical program. Furthermore the technical configuration of all devices must be logged during the discharge as well as between experiment phases. This is necessary to allow supervision of constantly running devices. All measured data must be stored together in a common database to make it easily accessible and reduce the effort to combine data. Because of these requirements a continuous data acquisition system must be provided where data may exist at any time. Intelligent methods for browsing and retrieval of the acquired data from the common database are desired. This includes calendar-based time interval selection, overview plots for intervals that cover several days and online views of the last stored data. The contribution will explain the challenges and the advantages induced by this kind of data access methods. Existing and planned solutions for Wendelstein 7-X will be depicted. Particularly the “Data Browser” – a graphical tool specially designed to fulfil these tasks at W7-X – will be presented.     

A reference inventory for aquatic fauna of the Laurentian Great Lakes

The Laurentian Great Lakes encompass an expansive and diverse set of freshwater ecosystems that contain a concordantly large and diverse vertebrate and invertebrate fauna. Although numerous publications exist concerning the composition and distribution of this fauna, there is at present no single readily available resource that brings all this information together. Here, we present and describe the compilation process for a comprehensive Great Lakes aquatic fauna inventory covering fishes, reptiles, amphibians, zooplankton, mollusks, annelids, insects, mites, and various other aquatic invertebrates. Inventory entries were developed via an extensive search of literature and internet sources and are attributed with detailed nomenclature information, general lake and habitat occurrences, and supporting citations and links to life history and genetic marker information. The inventory scope is the Laurentian Great Lakes proper and their connecting rivers, and their fringing coastal wetlands and lower tributaries. Over 2200 unique taxa are contained in the inventory – 85% resolved to species and 14% to genus. The listing substantially expands previous richness estimates for invertebrates in the Great Lakes, but taxonomic resolution and spatial distribution information for them remains quite uneven. Example pattern analyses for fauna in this inventory show that aquatic vertebrates are generally more widely distributed than invertebrates, and that biodiversity is concentrated in the coastal margins. The inventory is being packaged into a public, searchable database that showcases the biodiversity of the Great Lakes aquatic fauna and can assist the research and management community in their biological investigations.     

Model experiments mimicking the human intestinal transit and metabolism of D-galacturonic acid and amidated pectin

In order to study the human intestinal transit and metabolism of D-galacturonic acid and amidated pectin a number of model experiments were carried out. Both substrates were incubated under aerobic conditions at 37 degrees C using saliva (2 min) and simulated gastric juice (4 h). Under anaerobic conditions the substrates were incubated at 37 degrees C using human ileostomy and colostomy fluids, each obtained from three different donors, for 10 and for 24 h, respectively. D-Galacturonic acid, SCFA (acetic acid, propionic acid, and butyric acid), as well as methanol were analyzed photometrically after carbazole reaction, GC-flame ionization detection (GC-FID), and headspace solid-phase microextraction GC/MS (HS-SPME-GC/MS), respectively. D-Galacturonic acid and amidated pectin were found to be stable during incubations with saliva and simulated gastric juice, whereas both substrates underwent degradation in the course of human ileostomy and colostomy fluid incubations. D-Galacturonic acid was practically completely decomposed within 10 h and SCFA, with acetic acid as the major representative, were formed up to 98% of the incubated substrate in colostomy effluent. The amidated pectin was only degraded in part, revealing stable amounts of 22-35% and 3-17% in ileostomy (after 10 h) and colostomy fluid (after 24 h), respectively. SCFA were generated up to 59% of the applied amidated pectin. In parallel, 19-60% and 52-67% of the available methyl ester groups were cleaved in the course of incubations with ileostomy and colostomy fluids, respectively. The results demonstrate for the first time that D-galacturonic acid and amidated pectin are stable in human saliva and simulated gastric juice. The degradation of both compounds during incubation with ileostomy effluent is highlighted, providing evidence for a considerable metabolic potential of the small intestine.     

Novel transparent hybrid polymer working stamp for UV-imprinting

Transparent stamps are an integral and crucial part of the UV-imprinting. Time consuming fabrication of quartz stamps increases the price of the technology. In the presented work a thermally stable transparent imprint stamp made of a novel hybrid polymer system is demonstrated. As a low-cost and highly efficient alternative the hybrid polymer stamp contributes to the acceptance and application of the nanoimprint technology. By using the UV-patternable inorganic–organic hybrid polymer quartz stamps might become superfluous in the UV-imprint process entirely, because transparent working stamps can be manufactured also with use of opaque silicon master stamps.     

Photostability and toxicity of pentachlorophenol and phenanthrene

Fate of organic contaminants under UV irradiation as environmental variable was studied. Aqueous solutions of pentachlorophenol and phenanthrene were subjected to simulated solar radiation and monitored during ≤ 93 h. Immobilization tests were conducted using Daphnia magna neonates in pre-irradiated water for the assessment of photoproduct-mediated toxicity. We observed a time-dependent decrease in exposure concentrations following irradiation, which correlated positively with reduced immobilization of the animals. A complete disappearance of the lowest and highest concentrations of pentachlorophenol was noted after 25 h and 75 h, respectively. Survivorship of the animals increased until 100% and correlated positively with irradiation time. However, phenanthrene was rather persistent under irradiation, with less than 25% decline in exposure concentrations after 93 h. Neonates were not immobilized at maximum aqueous solubility of phenanthrene. Rate constants (k) for the photodegradation of pentachlorophenol at 0.41, 0.59, 1.1, and 2.1 mg l(-1) were in the range of 7.2 × 10(-2) and 4.9 × 10(-2)h(-1), showing a slight decrease with increasing initial pentachlorophenol concentration. Nonetheless, pentachlorophenol degradation in the studied concentration range could still be described by the pseudo-first-order kinetics. K values for phenanthrene at 0.12 and 0.22 mg l(-1) were 2.9 × 10(-3)h(-1) and 4.2 × 10(-3)h(-1), respectively.     

Partitioning of organic chemicals to storage lipids: elucidating the dependence on Fatty Acid composition and temperature

Lipids serve as important compartments in partitioning of neutral organic chemicals into organisms. Storage lipids, made up of triglycerides with various fatty acids, are among the major classes of lipids. Here, we present experimental equilibrium partition data for diverse chemicals in fish oil, linseed oil, and goose fat at 37 °C. These data, in combination with data from the literature for olive oil and milk fat, show that the fatty acid composition of triglycerides has no significant influence on the partition coefficient. This result allows the derivation of a general predictive model for partitioning into storage lipids. We have collected storage lipid/water partition coefficients for 247 compounds to calibrate polyparameter linear free energy relationships (pp-LFERs) for 37 °C, which achieved a model fit with a root mean squared error of 0.20 log units. To extend the applicability of this model toward the aquatic food chain, we also measured fish oil partition data at 7 °C. The resulting enthalpies were used to calibrate an additional pp-LFER for the temperature dependence of storage lipid/water partitioning. This model allows us to estimate partition coefficients at desired temperatures that occur under typical ambient conditions.     

Social environment and reproduction in female European rabbits (Oryctolagus cuniculus): Benefits of the presence of litter sisters.

The authors investigated in an observational study the consequences of the presence of litter sisters on the social interactions and on reproductive performance of young female European rabbits (Oryctolagus cuniculus) from a population living under seminatural conditions. In early winter, when all young females were settled in a social group, they were characterized by the presence or absence of litter sisters in their groups. Females with litter sisters in their groups displayed significantly more positive social interaction with females of their social group compared to females without sisters, whereas this difference was mainly due to the high frequency of positive social interactions among the respective sisters. Such differences between the females of both categories were already apparent during the animals' juvenile phase, before the females integrated into a particular group: females which later had litter sisters in their group showed more positive social behavior than females which later no longer had litter sisters. During their first breeding season, females with litter sisters present generally started to breed earlier by an average of 14 days. A more favorable social environment might have possibly facilitated the earlier onset of breeding in females with present litter sisters by attenuating the negative consequences of stress. (PsycINFO Database Record (c) 2010 APA, all rights reserved)