柴油机铸铝活塞碎裂失效分析

通过对失效件整体形貌、断口、内部质量及显微组织的全面检验和试验分析 ,确定工件内部存在严重的质量问题 ,铸造冷裂纹、大型疏松孔洞和未经变质处理的缺陷组织 ,是导致构件在服役时早期失效碎裂的主要原因。     

P2P网络中的匿名电子拍卖协议研究*

在P2P网络中实现电子拍卖的功能对于P2P技术具有重要意义,这将意味着电子商务同样可以在P2P网络中广泛应用.然而,匿名性、投标价保密性、抗勾结性等安全问题一直是电子拍卖研究的难点问题,一种合理的解决方法是将盲签名、知识证明、可验证的数字签名加密算法引入到电子拍卖协议中.这样不仅可以很好地解决P2P网络无中心服务器的不足,还使得系统的安全性能得到显著提高.     

支持上下文感知服务的中间件原型*

提出了基于传感器网络环境的上下文感知应用开发中间件原型的体系结构MidCASE,重点阐述了中间件的体系结构设计和软件运行时基于服务的分布式运行架构.讨论了上下文感知过程中的两个关键问题,包括上下文信息建立的方法和感知过程中上下文信息与高层通信的调度模型.最后,以该中间件原型为基础,通过在医疗护理的场景下实现上下文感知应用并证明了其易用性与支撑作用.     

大空间结构钢屋盖火灾下温度场计算方法研究

为了研究大空间结构屋面钢构件火灾下温度场的简化计算方法,把国内外现有用于“室内火灾”温度场的简化计算公式和方法,应用于典型尺寸的大空间结构模型,并与数值模拟结果进行比较。给出了对各种方法的计算准确性的分析结果,并从理论和原理的角度对各种方法的优劣进行了综合评价,提出了进一步修正的方向。     

微晶纤维素在稀硫酸中的热解机制研究

以微晶纤维素为原料,通过热转化可以得到葡萄糖、乙酰丙酸等多种用途广泛的有机化合物,在此过程中也存在脱水碳化竞争反应,得到生物碳副产物.分别以酸浓度和温度为实验变量,采用高效液相色谱(HPLC)对样品的液体产物进行表征,探索微晶纤维素在稀硫酸溶液中的热分解转化机制.结果表明:微晶纤维素的热分解转化是连续反应和竞争反应同时存在的复杂反应过程;控制温度在180～200℃,酸浓度在0.05～0.1 mol/L时,可获得最大产率的葡萄糖(约21.90％);若温度为200℃,酸浓度为0.2 mol/L时,则主要产物为乙酰丙酸.     

等温核酸放大技术在重金属检测方面的应用

等温核酸放大技术是一种可以实现重金属污染物痕量分析的高灵敏性检测方法,在分析检测中有着广泛且重要的作用。本文综述了几种不同的等温核酸放大技术及其在重金属检测方面的应用,阐述分析了各方法的检测原理,为之后建立更加灵敏、快速、准确的检测方法提供了参考。虽然等温核酸放大技术目前主要停留在实验室阶段,并且检测目标有限,但是由于该技术的高灵敏性、特异性以及与其他学科紧密的联系性,具有潜在的应用前景。     

Efficient photodegradation of phenol assisted by persulfate under visible light irradiation via a nitrogen-doped titanium-carbon composite

To realize the utilization of visible light and improve the photocatalytic efficiency of organic pollutant degradation in wastewater, a nitrogen-doped titanium-carbon composite (N-TiO₂/AC) prepared by sol-gel methods was applied in the photodegradation of phenol assisted by persulfate under visible light irradiation (named N-TiO₂/AC/PS/VIS). The results show that a synergistic effect exists between visible-light photocatalysis and persulfate activation. Compared with TiO₂/PS/VIS, the phenol degradation rate was found to be observably improved by 65% in the N-TiO₂/AC/PS/VIS system. This significant increase in degradation rate was mainly attributed to the following two factors: 1) The N and C doping can change the crystal structure of TiO₂, which extends the TiO₂ absorption wavelength range to the visible light region. 2) As an electron acceptor, PS can not only prevent electrons and holes from recombining with each other but can also generate strong oxidizing radicals such as ∙SO₄^– and ∙OH to accelerate the reaction dynamics. The process of phenol degradation was found to be consistent with the Langmuir pseudo-first-order kinetic model with an apparent rate constant k of 1.73 min^–1. The N-TiO₂/AC/PS/VIS process was proven to be a facile method for pollutant degradation with high pH adaptability, excellent visible-light utilization and good application prospects.     

片状变燃速发射药燃烧性能的数值计算

为研究包覆方式对片状发射药燃烧性能的影响,建立了不同包覆方式下多层片状发射药的物理模型,并推导了形状函数和燃气生成猛度表达式,利用Matlab软件对不同的宽厚比、长厚比及多层结构的片状发射药进行了数值计算;制备了不同长厚比的片状变燃速发射药,并进行了密闭爆发器实验。结果表明,四面包覆和全包覆可以很好地消除临界宽厚比对片状发射药燃烧性能的影响;与两面包覆的片状发射药相比,四面包覆和全包覆的片状发射药能够延缓内层药减面燃烧的时间,其燃气生成猛度的阶跃程度分别提高了1.17%和1.23%,呈现出良好的燃烧渐增性。     

带式输送机回程空段双向清扫器研究与设计

针对北方某燃煤发电厂输煤系统带式输送机工作表面粘煤和结冰问题,设计了一种带式输送机回程双向空段清扫器.该双向清扫器由刮扫部分和双向转换部分组成.刮扫部分的多个刮刀单元在刮刀安装板上错落排布,形成一个垂直于输送胶带运行方向的完整刮扫面;为降低相邻刮刀之间的物料漏扫率,其横向装配尺寸小于刮刀片宽度.清扫器双向转换部分由四连杆机构实现,通过设定驱动电机转动合适的角度,可以保证清扫器刮扫单元移动到目标位置,从而实现正反向清扫状态的转换.本装置结构精简、加工方便、易于安装,很好地保证胶带输送机的正常运行.     

One-step fabrication superhydrophobic sand filter for capillary-driven separation of water-in-oil emulsions

The efficient separation of water-in-oil emulsion is of significance in environment and energy filed, and it has become a world-wide challenge. Herein, we have presented a one-step, facile and low-cost approach to prepare superhydrophobic sands for efficient separation of water-in-oil emulsion. The as-prepared sand layers possessed a water contact angle higher than 151°, demonstrating their superior superhydrophobic property. Besides, the as-prepared sand layers could separate water-in-emulsions with separation efficiency up to 99.7%, which is superior to both traditional and superwettable filtration membranes. The effect of thickness of sand layer on separation performance was also investigated. The results showed that the filtration flux decreased with the increased of filtration thickness while the separation efficiency increased. The as-prepared sand layer proposed by this study is a processing candidate for separating water-in-oil emulsion in practical industry. Additionally,the as-prepared superhydrophobic sand fabrication method also provides an alternative for desert water storage.