Effect of coagulation temperature on structures and properties of poly(p-phenylene benzobisoxazole) (DHPBO) fibers during dry-jet wet-spinning process

The effect of coagulation temperature on the morphology, microstructures and mechanical properties of dihydroxy poly(p-phenylene benzobisoxazole) (DHPBO) fibers was investigated during dry-jet wet- spinning process, in which the coagulation bath concentration and drawn ratio were kept as 10 wt% of PPA in water and 1.7, respectively. The structures and mechanical properties of the as-spun DHPBO fibers were characterized by FTIR, XRD, SEM, and single fiber tensile testing. The results indicated that in PPA/H2...     

Mold deformation in soft UV-nanoimprint lithography

UV-nanoimprint lithography (UV-NIL) using a soft mold is a promising technique with low cost and high throughput for producing the submicron scale large-area patterns. However, the deformations of the soft mold during imprinting process which can cause serious consequences have to be understood for the practical application of the process. This paper investigated the deformation of the soft mold by theoretical analyses, numerical simulations, and experimental studies. We simulated the mold deformation using a simplified model and finite element method. The simulation and the related experimental results agree well with each other. Through the investigation, the mechanism and affected factors of the mold deformation are revealed, and some useful conclusions have been achieved. These results will be valuable in optimizing the imprinting process conditions and mold design for improving the quality of transferred patterns.     

Introduction of fluorin into PBO polymer chains: Toward higher thermal stability and lower dielectric constant

A series of novel fluorinated benzoxazole polymers (6FPBO's) with high thermal stability and low dielectric constant were synthesized by copolymerization of 1,3-diamino-4, 6-dihydroxybenzene dihy-drochloride (DAR), 1,4-benzenedicarboxylic acid (PTA) and various amount of 4'4- (hexafluoroisopro-pylidene) bis (benzoic acid) (BIS-B-AF) in the medium of polyphosphoric acid (PPA). 6FPBO fibers were then obtained via dry-jet wet-spinning technique and characterized by means of Fourier transform infrared (FTIR) spectra, thermogravimetric analysis (TGA), single fiber tensile testing machine and scanning electron microscopy (SEM). FTIR spectrum of 6FPBO fibers indicated that the fluorine groups had been incorporated into PBO molecular chains successfully. TGA curves revealed that 6FPBO fibers possessed high thermal stability just as pure PBO fibers. Moreover, dielectric constant spectrum of 6FPBO exhibited that the polymers had low dielectric constant, especially in the range of high- frequency.     

The effect of hydrogen on the electronic structure of kink in bcc iron

The electronic structures of kinks in the [100](010) and 1/2[111](−110) edge dislocations in bcc iron containing hydrogen are investigated by means of the first-principles DMol method and the discrete variational method. The effects of hydrogen on the kinks are discussed. The results show that hydrogen forms weak bonding states with its neighboring host atoms, and since hydrogen draws charge from its neighboring host atoms, the interactions between most of the host atoms are weakened compared with those of the corresponding atomic pairs in the clean kinks. This indicates that the migration of kink, i.e. the motion of dislocation, is easier in the doping hydrogen kink than in the clean kink, which may be the solid solution softening effect resulting from the impurity hydrogen. Supported by the National Basic Research Program of China (Grant No. 2006CB605102) and Science Foundation of Central South University of Forestry & Technology (Grant No. 06y016)     

基于本体的FMEA知识库的构建方法研究

为合理有效地利用失效模式与后果分析(potential failure mode and effects analysis,FMEA)知识,针对在解决制造过程中进行质量问题的分析和处理时,由于受现场人员知识和经验水平的制约而使分析结果具有极大的不确定性问题,提出了基于本体论构建的FMEA知识库,对FMEA过程形成的知识进行有效提取和集成.研究了FMEA知识的获取和分类,建立了一个基于本体的FMEA知识表示模型,并给出了一个基于本体的FMEA知识库框架结构,讨论了基于本体的FMEA知识检索和知识库的维护.通过FMEA知识库的建立,为质量问题的处理和分析提供了一个有效的决策支持途径.     

基于模糊层次分析法综合评判工会竞赛成绩

为综合评判工会组织的各项竞赛活动的成绩,提出了基于模糊层次分析法的综合评判措施,主要包括竞赛项目权重的确定、竞赛成绩的量化和综合评判等过程.实际应用表明,模糊层次分析法可以最大限度减少主观因素对评价结果的影响,合理地确定各项赛事在工会竞赛活动中的权重,结合竞赛成绩的量化矩阵,使得综合评价结果科学、可信.     

光源谱宽通过光纤色散对AOCS输出的影响

基于光纤色散引起的脉冲展宽效应,在理论和实验上研究了有源光学电流传感器（AOCS）中宽带光源对系统输出的影响．理论结果表明：对于长度为500m的光纤,当光源谱宽在40—60nm之间变化时,多模光纤传输下的脉冲展宽范围在0．5～0．8ns,单模光纤传输下的脉冲展宽范围在2×10^-5～4×10^-5,信号衰减量对系统输出影响很小,且随光源谱宽的增加而有微弱的增加,实验与理论相符合．     

RP/RE技术与比例式设计

RP/RE制造技术与设计美学的有机结合,形成了具有竞争力和规模化的设计业,提高了企业创新设计和产品市场开发的能力.运用RP/RE技术得到实体模型,再以设计美学原则对其进行分析、数据处理、美化形态,促进产品开发、研制和销售.工业产品的形态比例关系,受诸多因素的制约.分析了传统的比例设计方法的缺陷与不足,介绍比例式设计的原理、方法及其具体应用.表明比例式设计具有数理性强,计算方便、简捷,容易掌握的特点.而且能根据功能要求、技术参数和使用对象等因素,迅速找出产品的最佳比例值,有效地解决功能和形式之间的协调关系.     

膨胀石墨的饱和吸附量与微观结构的关系

采用不同的方法测定膨胀石墨对不同油质的饱和吸附量,来探讨膨胀石墨的结构与饱和吸附量的关系.由扫描电镜可知,膨胀石墨具有较大的比表面积,其孔结构是以中、大孔为主;蠕虫石墨的表面结构与其内部结构不同,其内部为典型的片层结构.通过观察石墨内部孔结构特征变化,可以分析膨胀石墨对油的去除效率以及影响因素.     

基于光纤像面全息的金属构件微位移测量

针对激光全息技术能处理常规方法难以解决的问题以及光纤具有环境适应性的特点,设计了一种基于光纤像面全息干涉计量对金属材料构件微小位移测量的方法.通过对不同芯径传像光纤束情况下的成像结果分析,得出了与材料力学相符合的结论.实验结果表明,提出的方案适用于对金属材料特性的高精度测量,可以解决阻碍激光全息技术推广应用和发展的环境要求.