Porous Iron–Cobalt Alloy/Nitrogen‐Doped Carbon Cages Synthesized via Pyrolysis of Complex Metal–Organic Framework Hybrids for Oxygen Reduction

Efficient and stable nonprecious metal electrocatalysts for oxygen reduction are of great significance in some important electrochemical energy storage and conversion systems. As a unique class of porous hybrid materials, metal–organic frameworks (MOFs) and their composites are recently considered as promising precursors to derive advanced functional materials with controlled structures and compositions. Here, an “MOF‐in‐MOF hybrid” confined pyrolysis strategy is developed for the synthesis of porous Fe–Co alloy/N‐doped carbon cages. A unique “MOF‐in‐MOF hybrid” architecture constructed from a Zn‐based MOF core and a Co‐based MOF hybrid shell encapsulated with FeOOH nanorods is first prepared, followed by a pyrolysis process to obtain a cage‐shaped hybrid material consisting of Fe–Co alloy nanocrystallites evenly distributed inside a porous N‐doped carbon microshell. Of note, this strategy can be extended to synthesize many other multifunctional “nanosubstrate‐in‐MOF hybrid” core–shelled structures. Benefiting from the structural and compositional advantages, the as‐derived hybrid cages exhibit superior electrocatalytic performance for the oxygen reduction reaction in alkaline solution. The present approach may provide some insight in design and synthesis of complex MOF hybrid structures and their derived functional materials for energy storage and conversion applications.     

无线传输移动视频监控系统设计探究

近年来,网络视频监控在各个领域得到了广泛的应用,通过网络监控系统应用,能够为大众提供更好的服务,同时还可以维护社会的稳定,促进我国社会经济的持续发展.本文阐述了网络视频监控系统设计构思,在此基础上,针对网络视频监控系统设计中相关要点及应用效果进行了分析,以供读者参考.     

移动互联网用户标识管理技术的研究

移动互联网业务中,网络地址转换(NAT,Network Address Translation)技术使得公网增值服务提供商(SP)无法获取用户标识及其基础信息、业务使用信息,因此无法实现业务使用计费及用户管理,极大地限制了移动互联网业务的发展。文章针对这一问题,提出一种全新的移动互联网用户标识解决方案,运营商通过对用户转换前、后标识信息的匹配及对用户的统一管理,形成用户访问信息的完整记录,实现公网SP对移动互联网用户信息的识别和管理。     

偏振正交误差对偏振光导航定位系统测量精度的影响

偏振正交误差是影响四通道时分复用大气偏振检测系统精度的主要因素。通过建立检偏器阵列偏振正交误差对偏振光导航系统定位精度的影响模型,分析了该误差对大气偏振测量精度与导航定位精度的影响,并进行了实验验证。理论与实验结果表明,降低检偏器阵列偏振正交误差,可以显著提高系统大气偏振测量精度与导航定位精度。当检偏器阵列偏振正交误差无法消除时,调整定位初始角可以明显提高系统测量精度与导航定位精度。     

沟道应力对GaAs PHEMT材料电性能的影响

设计并用分子束外延(MBE)法制备了不同沟道结构的GaAs PHEMT材料,采用高分辨率X射线双晶衍射仪(DCXRD)、应力测试仪和霍尔测试仪对样品的结晶质量、薄层组分和厚度偏差、应力以及电子迁移率进行了分析表征。探讨了外延片应力与沟道结构的相关性,研究了沟道失配应力对电性能的影响机理。建立了GaAs PHEMT材料热应力引起电子传输特性退化的试验方法,进行了高温和低温存储后材料电性能的演化行为测试,并归纳了热应力引起材料电特性退化的实验结果。结果表明GaAs PHEMT材料经高、低温存储并恢复室温后仍能保持原有电性能,沟道应力对材料电性能的影响主要表现为失配应力。     

UHV/CVD外延生长SiGe/Si表面反应动力学

利用 Si H4 和 Ge H4 作为源气体 ,对 UHV/CVD生长 Si1- x Gex/Si外延层的表面反应机理进行了研究 ,通过 TPD、RHEED等实验观察了 Si( 1 0 0 )表面 Si H4 的饱和吸附、热脱附过程 ,得出 Si H4 的分解应该是每个 Si H4 分子的 4个 H原子全部都吸附到了 Si表面 ,Si H4 的吸附率正比于表面空位的 4次方 ,并分析了 Ge H4 的表面吸附机制 .在此基础上建立了 UHV/CVD生长Si1- x Gex/Si的表面反应动力学模型 ,利用模型对实验结果进行了模拟 ,二者符合得很好     

基于光散射的实时气溶胶粒子形状识别技术研究

利用米氏散射理论和时域有限差分(FDTD)软件计算了不同大小、形状和折射率粒子的前向散射光场分布,分析了通过光强度分布和非对称因子反演粒子相关信息、区分粒形的可行性。研制了一台利用增强型CCD相机在线采集单个气溶胶粒子在5°~19°前向散射角范围内光场图样的装置。8μm粒径的聚苯乙烯球形粒子散射图样实验结果与理论计算对比较为吻合,验证了该装置的有效性。应用该装置对不同形状的气溶胶粒子进行检测,结果表明能够从散射图像和反演计算结果区分出球形、杆状和其他形状粒子。     

三网融合下PON网络维护管理方法探讨

目前三网融合在我国已经进入了实施启动阶段。本文介绍了在三网融合进程中电信运营商PON网络的状况,分析了电信运营商PON网络维护管理工作的现状和问题,提出了基于网络资源管理系统的PON网络维护管理模式。     

激光波长对含能材料起爆阈值的影响

为了解激光波长对含能材料起爆阈值的影响,降低含能材料的激光起爆能量,提高激光激励源的小型化程度,采用飞行时间质谱技术和Bruccton升降法,测试了波长1 064 nm和532 nm两种激光对泰安(PETN)的解离谱图和起爆阈值,分析了波长对起爆机理的影响。结果表明:含能材料激光起爆对波长具有选择性,每种含能材料均具有一些有利于起爆的特征吸收波长;不同波长(1 064 nm和532 nm)激发时PETN存在不同的解离机理。相对于532 nm激光,接近特征吸收的1 064 nm激光能够加速PETN的解离,并使其50%发火能量降低14%。因此,采用含能材料特征吸收波长激光作为起爆激励源,能有效的减少含能材料的起爆阈值。     

Bio‐Inspired Preparation of Fibrin‐Boned Bionanocomposites of Biomacromolecules and Nanomaterials for Biosensing

Learning from nature is one of the most promising ways to develop advanced functional materials. Here, inspired by blood coagulation, novel fibrin‐boned bionanocomposites are reported as efficient immobilization matrices of biomacromolecules and nanomaterials for biosensing. Glucose oxidase (GOx), Au nanoparticles (AuNPs), and Fe₃O₄ magnetic nanoparticles (MNPs) are adopted as the model biomacromolecules and nanomaterials. By integrating the thrombin‐triggered coagulation of fibrin with advanced surficial modification techniques, four kinds of immobilization strategies are developed and evaluated. Digital imaging, UV‐vis spectroscopy, scanning/transmission electron microscopy, electrochemical methods, and N₂ adsorption‐desorption isotherms are used to investigate the formation, immobilization efficiency, and performance of various bionanocomposites. The fibrin‐boned networks show inherent biocompatibility, excellent adsorbability, porosity, and functionalization ability, endowing the bionanocomposites with high efficiencies in capturing AuNPs, MNPs and GOx (99%, 98%, and 57% captured under the given conditions, respectively), as well as significant mass‐transfer and biocatalysis efficiencies. Therefore, the fibrin‐boned bionanocomposites show great potential for biosensing, for example, a fibrin‐AuNPs‐GOx‐glutaraldehyde bionanocomposites modified Au electrode is highly sensitive to glucose (145 μA cm^?2 mM^?1) allowing for a limit of detection down to 25 nM, being much superior to those of the reported analogues. The presented experimental platform/strategy may find wide applications in the development of other bio/nano‐materials/devices.