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901.
902.
Hyun Min Shim Joon Soo Lee Hong Yue Wang Seung Hak Choi Jeong Hoon Kim Hyung Taek Kim 《Korean Journal of Chemical Engineering》2007,24(3):537-541
The main purpose of the study was to develop a model using ASPEN and Excel simulation method to establish optimum CO2 separation process utilizing hollow fiber membrane modules to treat exhaust gas from LNG combustion. During the simulation,
optimum conditions of each CO2 separation scenario were determined while operating parameters of CO2 separation process were varied. The characteristics of hollow fibers membrane were assigned as 60 GPU of permeability and
25 of selectivity for the simulation. The simulation results illustrated that 4 stage connection of membrane module is required
in order to achieve over 99% of CO2 purity and 90% of recovery rate. The resulted optimum design and operation parameters throughout the simulation were also
correlated with the experimental data from the actual CO2 separation facility which has a capacity of 1,000 Nm3/day located in the Korea Research Institute of Chemical Technology. Throughout the simulation, the operating parameters of
minimum energy consumption were evaluated. Economic analysis of pilot scale of CO2 separation plant was done with the comparison of energy cost of CO2 recovery and equipment cost of the plant based on the simulation model.
This work was presented at the 6
th
Korea-China Workshop on Clean Energy Technology held at Busan, Korea, July 4–7, 2006. 相似文献
903.
Josianne Lefebvre Federico Galli Claudia L. Bianchi Gregory S. Patience Daria C. Boffito 《加拿大化工杂志》2019,97(10):2588-2593
X‐ray photoelectron spectroscopy (XPS) is a quantitative surface analysis technique used to identify the elemental composition, empirical formula, chemical state, and electronic state of an element. The kinetic energy of the electrons escaping from the material surface irradiated by an x‐ray beam produces a spectrum. XPS identifies chemical species and quantifies their content and the interactions between surface species. It is minimally destructive and is sensitive to a depth between 1–10nm. The elemental sensitivity is in the order of 0.1 atomic %. It requires ultra high vacuum ( Pa) in the analysis chamber and measurement time varies from minutes to hours per sample depending on the analyte. XPS dates back 50 years ago. New spectrometers, detectors, and variable size photon beams, reduce analysis time and increase spatial resolution. An XPS bibliometric map of the 10 000 articles indexed by Web of Science[1] identifies five research clusters: (i) nanoparticles, thin films, and surfaces; (ii) catalysis, oxidation, reduction, stability, and oxides; (iii) nanocomposites, graphene, graphite, and electro‐chemistry; (iv) photocatalysis, water, visible light, and ; and (v) adsorption, aqueous solutions, and waste water. 相似文献
904.
Oomen Raymond P.; Young N.Martin; Bundle David R. 《Protein engineering, design & selection : PEDS》1991,4(4):427-433
A molecular model of the binding site of an anti-carbohydrateantibody (YsT9.1) has been developed using computer-assistedmodeling techniques and molecular dynamics calculations. Sequencehomologies among YsT9.1 and the Fv regions of McPC603, J539and human Bence-Jones protein REI, all of which have solvedcrystal structures, provided the basis for the modeling. Thegroove-type combining site model had a topography which wascomplementary to low energy confonners of the polysaccharide,a Brucella O-antigen, and the site could be almost completelyfilled by a pentasaccharide epitope in either of two dockingmodes. Putative interactions between this epitope and the antibodyare consistent with the known structural requirements for bindingand lead to the design of oligosaccharide inhibitors that probethe veracity of the modeled docked complex. Ultimately boththe Fv model and the docked complex will be compared with independentcrystal structures of YsT9.1 Fab with and without pentasaccharideinhibitor, currently at the stage of refinement. 相似文献
905.
To understand the smart (i.e., good memory) characteristics of hybrid composites of carbon fibers (CFs) and glass fibers (GFs) with epoxy resin as a matrix, the changes in the electrical resistance of composites with tension and on bending were investigated. The electrical resistance behavior of composites under tension changed with the composition of the CF/GF, as well as with the applied strain. The fractional electrical resistance increased slowly with increasing strain within a relatively low strain region. However, with further loading it increased stepwise with the strain according to the fracture of the CF layers. The strain sensitivity of the samples increased with increasing CF weight percentage, and the samples incorporating more than 40 wt % CF showed a strain sensitivity higher than 1.54 for a single CF. The changes in the fractional electrical resistance with bending were not so dominant as those with tension. This difference was attributed to the action of two cancelling effects, which are the increasing and decreasing fractional electrical resistance due to tension and compression with bending, respectively. On recovery from a large applied bending, the fractional electrical resistance decreased slowly with unloading because of the increase of contacts between the fibers that resulted from the reorganization of ruptured CFs during the recovery. Even the composites incorporating a relatively small CF content showed an irreversible electrical resistance with both tension and bending. However, the strain sensitivity being larger with tension than with bending is ascribed to the difference in their mechanical behaviors. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2447–2453, 2002 相似文献
906.
Jim D. Earls Jerry E. White Marvin L. Dettloff Marty J. Null 《Journal of Coatings Technology and Research》2004,1(3):243-245
Epoxidized 10-undecenoic acid triglyceride, an experimental seed oil derivative that has a terminal epoxy group on each of
the three acyl glyceride segments, has been found to have good reactivity with amine curatives and allows room temperature
cures to be obtained. Coatings based on epoxidized 10-undercenoic acid triglyceride have also shown excellent UV stability.
As an example, coatings samples placed in a QUVA chamber exhibit no loss in gloss after 3000 hr of a cycled exposure to high
intensity UV lamps and moisture at temperatures of 50–60°C. In comparison, coatings based on standard liquid epoxy resins
(LERs) and commercially available hydrogenated LERs lose gloss due to chalking/decomposition within 200–800 hr.
Presented at the 81 st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia,
PA. 相似文献
907.
The pulsed arc discharge to the surface of wastewater was applied to the degradation of a textile azo dye (Acid Red 27). A
high-voltage electrode (discharging electrode) was vertically placed above the surface of the wastewater while the wastewater
itself was grounded. The pulsed arc discharge occurred between the tip of the discharging electrode and the surface of the
wastewater, producing various oxidative species. Oxygen was used as the working gas instead of air to prevent nitrogen oxides
from forming. The effect of several parameters on the chromaticity and chemical oxygen demand (COD) removal was examined.
The results obtained showed that the chromaticity of the wastewater was completely removed by this process and the COD also
decreased significantly. It has been found that ozone formed in the gas phase mainly affects the removal of the dye. The contribution
of other effects such as ultraviolet light emission and OH radical formation during the arc discharge to the degradation of
the dye was found to be less than 15%. For the present reactor system, the optimum pH, pulse repetition rate and agitation
speed were found to be 3.0, 110 Hz and 300 rpm, respectively. 相似文献
908.
Condensed tannins have been considered to be important inducible defenses against mammalian herbivory. We tested for differences in condensed tannin defenses in Acacia drepanolobium in Kenya over two years among different large mammalian herbivore treatments [total exclusion, antelope only, and megaherbivore (elephants and giraffes) + antelope] and with four different ant symbiont species on the trees. We predicted that (1) condensed tannin concentrations would be lowest in the mammal treatment with the lowest level of herbivory (total exclusion), (2) trees occupied by mutualist ants that protect the trees most aggressively would have lower levels of tannins, and (3) if chemical defense production is costly, there would be a trade-off between tannin concentrations, growth, and mechanical defenses. Mean tannin concentrations increased from total exclusion treatments to wildlife-only treatments to megaherbivore + antelope treatments. In 1997, condensed tannin concentrations were significantly lower in trees occupied by the ant Crematogaster nigriceps, the only ant species that actively removed axillary buds. Contrary to our prediction, trees occupied by ant species that protect the trees more aggressively against mammalian herbivores did not have lower overall levels of condensed tannins. There was no consistent evidence of a trade-off between tannin concentrations and growth rate, but there was a positive correlation between mean thorn length and mean tannin concentrations across species of ant inhabitants and across herbivore treatments in 1997. Contrary to our expectation, trees had higher tannin concentrations in the upper parts of the canopy where there is little herbivory by mammals. 相似文献
909.
Crop residue,manure and fertilizer in dryland maize under reduced tillage in northern China: I grain yields and nutrient use efficiencies 总被引:4,自引:0,他引:4
Xiaobin Wang Dianxiong Cai Willem B. Hoogmoed Udo D. Perdok Oene Oenema 《Nutrient Cycling in Agroecosystems》2007,79(1):1-16
The rapidly increasing population and associated quest for food and feed in China has led to increased soil cultivation and
nitrogen (N) fertilizer use, and as a consequence to increased wind erosion and unbalanced crop nutrition. In the study presented
here, we explored the long-term effects of various combinations of maize stover, cattle manure and nitrogen (N) and phosphorus
(P) fertilizer applications on maize (Zea mays L.) yield and nutrient and water use efficiencies under reduced tillage practices. In a companion paper, we present the effects
on nutrient balances and soil fertility characteristics. The ongoing factorial field trial was conducted at Shouyang Dryland
Farming Experimental Station in northern China from 1993 onwards. The incomplete, determinant-optimal design comprised 12
treatments, including a control treatment, in duplicate. Grain yields and N, P, and potassium (K) uptakes and N, P and K use
efficiencies were greatly influenced by the amount of rain during the growing season (GSR), and by soil water at sowing (SWS).
There were highly significant interactions between GSR and added stover and manure, expressed in complex annual variations
in grain yield and N, P and K use efficiencies. Annual mean grain yields ranged from 3,000 kg ha−1 to 10,000 kg ha−1 and treatment mean yields from 4,500 kg ha−1 to 7,000 kg ha−1. Balanced combination of stover (3,000–6,000 kg), manure (1,500–6,000 kg) and N fertilizer (105 kg) gave the highest yield.
Stover and manure were important for supplying K, but the effects differed greatly between years. Overall mean N recovery
efficiency (NRE) ranged from 28% to 54%, depending on N source. NRE in wet years ranged from 50% to 90%. In conclusion, balanced
combinations of stover, manure and NP fertilizer gave the highest yield and NRE. Reduced tillage with adding stover and manure
in autumn prior to ploughing is effective in minimizing labor requirement and wind erosion. The potentials of split applications
of N fertilizer, targeted to the need of the growing crop (response farming), should be explored to further increase the N
use efficiency. 相似文献
910.
Prakorn Ramakul Milan Hronec Ura Pancharoen 《Korean Journal of Chemical Engineering》2007,24(2):282-287
−Purification of 2-mercaptobenzothiazole (91.9% purity) by solvent extraction was studied. The extraction of impurities present
in crude 2-MBT (e.g. benzothiazole, sulfides and sulfur containing compounds) was carried out at temperatures between 70-180°C
using various solvents and their mixtures of different polarity. The highest purity of 2-MBT, above 99% was obtained using
nitrobenzene, toluene and ethanol, even at a concentration of 2-MBT above 50 wt%. Increasing temperature and decreasing concentration
of the raw material have a positive influence on the purification process. A comparable efficiency of purification was observed
also with mixed solvents, (toluene with ethanol, acetone and aniline) possessing the same polarities. A correlation between
the polarity indexes (PI) of mixed solvents and experimentally obtained purity of 2-MBT was found. The highest purity of 2-MBT
provides extraction of the raw material with mixed solvents having PI 3.8-4.4. 相似文献