Bioderived Bilayer Shell Modification β-FeOOH Nanorods via Self-Assembly Technique as Sustainable Flame Retardants for Enhancing Flame Retardancy of Epoxy Resin

The design and application of bioderived flame retardants have been widely conducted to meet the concept of green and sustainable development. Here, self-assembly technique is used to prepare core–shell bioderived additives by using β-FeOOH as the core and polydopamine (PDA)/tannic acid (TA) bilayer as the shell, following adsorption of nickel ions to enhance the thermal stability, flame retardancy, and mechanical properties of epoxy resin (EP). The molecular structure of biobased resources is rich in hydroxyl groups and carbon content, which can be dehydrated and carbonized during combustion and promote the formation of robust protective char layer. With the addition of 5 wt% β-FeOOH@PTNi, the EP composites can pass V-0 rating in the UL-94 test. The peak heat release rate and total heat release decrease by 28.4% and 17.4% compared with pure EP. The bioderived nanorods can capture the oxygen free radicals, contributing to flame retarding in gaseous phase. Thus, the release of high-toxic CO and flammable gaseous is significantly suppressed. Besides, the storage modulus of EP composites increases by 16.0% with the addition of 5% β-FeOOH@PTNi compared with pure EP. This work provides a sustainable methodology for the design of bioderived flame retardants for EP.     

Crude Wax Extracted from Rice Bran Oil Improves Oleogel Properties and Oxidative Stability

Crude wax extracted from rice bran oil (RBO) is used to improve the oleogel properties and oxidative stability of RBO. The effect of crude rice bran wax (CrBW) on the formation characteristics and oxidative stability of oleogels is discussed. The results show that oleogels can be formed with 7.0 wt% CrBW at 20 °C. As the concentration of CrBW increases from 7.0 to 11.0 wt%, the hardness and solid fat content (SFC) of the oleogels increase significantly, and the oleogels are primarily β' crystals. Moreover, oleogel crystals formed with 5 and 7 wt% CrBW are flocculent; when the amount included is 9%, the oleogel crystals are transformed into long dendrites, and the density rises. After 90 days of storage at 20 °C, the peroxide value of oleogels formed with 9.0 wt% CrBW slowly rises from 3.21 to 6.52 mmol kg⁻¹. Practical Applications: Oleogels prepared here by CrBW and RBO are an innovative structural lipid without trans fats. Useful information on the rich fats and nutrients in CrBW is provided, which reduces the production cost and improves the industrial production capacity.     

DD—921钢铁常温发黑剂的研制和应用

研究了钢铁常温发黑过程的成膜机理,各组分之间的作用以及相互之间的影响,着重分析了常温发黑的优缺点,工艺控制参数以及经济性。     

DECOMPOSITION AND PRECIPITATION OF CARBIDES IN HOT-ROLLED Si-Fe SHEETS

在高温金相显微镜下,直接观察碳化物在热轧硅钢中的分解与析出过程。指出冷却速度对碳化物析出形态有很大影响。用差热分析确定了碳化物的分解与析出温度。所得结果为改进热轧硅钢生产工艺提供了重要的依据。     

大型钛合金压气机盘超塑性等温锻造模具结构及工艺参数实验研究

通过超塑拉伸和压缩试验，用金属铅进行模拟实验，探讨了大型ＴＣ１１合金压气机盘超塑性等温锻造的工艺参数，模具结构，锻坯形状尺寸及润滑剂的选择、并讨论了其模具材料及加热方式的选择。     

LD7铝合金时效工艺的研究

通过试验系统地研究了ＬＤ７铝合金的单级和两级时效工艺。结果表明，与传统的单级时效相比，两级时效在不降低室温强度，硬度的前提下，可显著提高合金的电导率及高温性能。     

全军表面工程推广网表面技术应用实例

本文根据96年各表面工程推广站技术工作总结中反映的情况，整理出各站在主要表面技术：电刷镀、热喷涂和粘接粘涂方面的应用实例．反映建站以来各站在装备维修中推广应用表面工程技术的实际状况和取得的主要成绩。     

TRIZ理论中物质-场的不同应用

通过对飞机发动机机罩概念设计中的物-场分析，简要概括了在实际的概念设计中应该如何应用和把握物质-场分析的侧重点。     

均相催化水合法合成乙二醇动力学研究

在反应温度为45～75℃,NY 健化剂浓度为0.093mol/L,水比为6～10的反应条件下,对均相催化水合法合成乙二醇动力学进行了研究。测定了反应速率常数及反应过程中溶液 pH 值的变化。依据实验结果,提出了反应机理,建立了反应动力学方程,并利用 Levenberg-Marquardt 方法回归了动力学参数。研究结果表明:在 NY 催化剂存在下,均相催化水合法合成乙二醇反应对环氧乙烷浓度是一级反应,其表观活化能为71113.8 J/mol 和指前因子3.05×10~9 min~(-1)。相对直接水合法而言,NY 催化剂降低了反应的活化能,大大提高了反应速度。     

不同形貌氢氧化镁的化学合成及影响因素

对不同形貌氢氧化镁的化学合成及外部生长环境进行了综述。尤其对影响氢氧化镁结晶性能和形貌起关键作用的因素，如碱性沉淀剂的选择、合成温度的确定、不同镁盐的影响、碱和镁盐的初始浓度及配比、水热处理、反应物的混合方式、晶形控制剂的加入等，进行了详细的阐述。