7-（3-氨基-3-芳基丙酰）-3-三氟甲基-5,6,7,8-四氢[1,2,4]三唑并[4,3-α]哌嗪的合成

以2-氯吡嗪和3-氨基-3-芳基丙酸为原料,经肼解、三氟乙酰化、闭环、氢化、缩合、脱保护等一系列反应合成了标题化合物,通过IR、1HNMR、13CNMR、MS对所得化合物的结构进行了表征.     

Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

Passively Q -switched Ytterbium-Doped Double-Clad Fiber Laser With a Cr4+:YAG Saturable Absorber

A high-power and high-repetition-rate passively Q -switched ytterbium-doped single-mode double-clad fiber laser was built using a Cr⁴⁺:YAG saturable absorber (SA). Two different SAs with initial transmissions of T_omicron = 30% and T_omicron = 50% were studied. At the maximum coupled pump power of 9.8 W, an output power of 4.7 W, pulse duration of 143 ns, pulse repetition rate of 253 KHz, pulse energy of 18.5 muJ, and slope efficiency of 49% were obtained with the T_omicron = 30% SA.     

俄罗斯减速器涡轮钻具驱动PDC钻头在西西伯利亚油田的成功应用

涡轮钻具由前苏联研制出来以后，得到了迅速发展，目前已发展到减速器涡轮钻具阶段。现在，俄罗斯西西伯利亚地区普遍使用减速器涡轮钻具钻井，而减速器涡轮钻具驱动PDC钻头的使用还是空白。采用俄罗斯生产的几种不同型号的减速器涡轮钻具，在西西伯利亚进行了驱动PDC钻头钻井的阶段性试验。试验结果表明，在优选PDC钻头结构的情况下，用减速器涡轮钻具驱动PDC钻头，钻头进尺和机械钻速都较牙轮钻头有显著的提高，经济和社会效益显著。介绍了试验中使用的3种俄罗斯减速器涡轮钻具(TPM-195，TPⅢ-195和TPO3—195)的结构特点和主要技术参数。     

一台循环流化床锅炉U型二次分离的改进对过热器爆管的影响

文章通过对一台循环流化床锅炉U型二次分离装置的改进，减少了过热器爆管的介绍，给出了采用多次离心分离技术，改善和提高烟尘分离效率，从而改善过热器外部工作条件，达到减少爆管发生的措施，相应提出了一些有关的建议。     

"What is in a word? No versus Yes differentially engage the lateral orbitofrontal cortex": Correction.

Reports an error in "What is in a word? No versus Yes differentially engage the lateral orbitofrontal cortex" by Nelly Alia-Klein, Rita Z. Goldstein, Dardo Tomasi, Lei Zhang, Stephanie Fagin-Jones, Frank Telang, Gene-Jack Wang, Joanna S. Fowler and Nora D. Volkow (Emotion, 2007[Aug], Vol 7[3], 649-659). The supplemental materials link should appear as follows: http://dx.doi.org/10.1037/1528-3542.7.3.649.supp. (The following abstract of the original article appeared in record 2007-11660-018.) The words "No" and "Yes" are involved in conditioning to prohibit or encourage behavior, respectively. The authors, therefore, hypothesized that these words would be attributed to endogenous valence, activating neuronal circuits involved with valence and emotional control. Functional MRI (fMRI) at 4 Tesla was used to record regional brain activity while participants were exposed to emphatic vocalizations of the words. Results showed that No and Yes were associated with opposite brain-behavior responses; while No was negatively valenced, produced slower response times, and evoked a negative signal in the right lateral orbitofrontal cortex (OFC), Yes was positively valenced, produced faster response times, and evoked a positive signal in a contiguous region of the OFC. Attribution of negative valence to No and trait anger control were associated with increased responsivity of the OFC to No. Inasmuch as sensitivity to the prohibitive command No develops during childhood through interaction with primary caregivers as the first social objects, our findings may implicate the lateral OFC in the neurobiology of emotion regulation and subsequent social development. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

均匀设计法分析制备过程对钴钼硫化物催化剂机械强度的影响

建立了CoMoP/Al2O3加氢精制催化剂机械强度及其可靠性在制备过程中的数学模型,采用均匀设计考察了浸渍、干燥、煅烧、硫化4个制备过程中,浸渍时间、干燥温度、干燥时间、煅烧温度、煅烧时间、硫化温度和硫化升温速率7个实验因子对催化剂强度均值、Weibull模量的影响,同时考察了这些因素对颗粒密度的影响。方差分析表明所有模型都是充足的。实验结果表明,硫化过程是影响催化剂强度均值的主要过程。在实验范围内提高硫化温度、降低硫化时的升温速率有利于提高催化剂的强度。影响催化剂Weibull模量的因素主要为各个制备过程的交互效应。要提高催化剂强度的可靠性就必须全面考虑催化剂制备的各个过程,特别是各个制备过程的交互效应。     

新型刮刀钻头的设计及现场试验研究

在理论分析的基础上，综合PDC钻头和刮刀钻头的优点，设计了一种新型的刮刀钻头，并进行了现场试验。现场试验结果表明，该钻头运转平稳，采用低钻压、高转速，钻进速度快，井眼规则通畅，有较明显的防斜作用，该种钻头的推广应用对提高钻井工程的整体效益具有十分重要的意义。     

铣制三元流叶轮时产生误差的原因分析及解决方法

对在五坐标数控加工中心上铣制三元流叶轮时出现的叶轮附面尺寸误差问题，进行了详细分析，并提出了问题的解决方法，有效地避免了加工中产生的超差。     

S135钻杆钢在钻井液中的氧腐蚀行为

基于系统的理论分析和现场腐蚀产物的XRD分析,揭示了S135钻杆钢在3%NaCl溶液中的氧腐蚀机理。为研究腐蚀因素与腐蚀速率的关系,通过室内高压釜动态模拟实验,分别研究了钻井液中含氧量、钻井液温度、钻井液流速和钻井液盐浓度对S135钻杆钢的氧腐蚀速率影响规律。实验研究结果表明(1)3%NaCl盐水钻井液对S135钻杆钢的腐蚀主要是氧去极化作用所致;(2)钻井液含氧量和钻井液流速的增加会加快钻杆钢的氧腐蚀速率,而钻井液温度和含盐量对钻杆钢的氧腐蚀速率具有双重作用。