增塑剂对纤维素膜表面结构和性能的影响

天然纤维素膜不经任何处理直接干燥,膜发脆、卷曲,作用不大.采用甘油做增塑剂来改变纤维素膜的柔顺性,研究了不同的增塑条件对纤维素膜表面结构和性能的影响及甘油的塑化机理.通过力学性能测试、表面形态的观察及红外光谱分析,研究表明,甘油在一定程度上改变了纤维素膜的柔顺性,但同时却使纤维素膜的力学性能变差,并且增塑的膜经水洗后,甘油易流失,增塑效果减弱.     

一段转化炉竖琴管排吊簧改造及调整

针对一段蒸汽转化炉厚壁型炉管(HK-40)改薄壁型炉管(HP-Nb+M)后,因单根炉管重量减少近30%,受压恒力吊簧无调节功能,不能满足新载荷工况下的使用要求问题,于1996年和2007年两次对弹簧K(弹性系数)值进行校验。鉴于校验值与设计值无明显变化,弹簧特性还处于良好状态,从降低设备改造成本考虑,对竖琴管排承重吊簧进行改造使用,由新核定的工作载荷确定新工况下A、B吊簧改造后的冷态"O"值,并确定管排安装方法和吊簧的冷、热态调整要求。     

压力指标法测定顺层钻孔有效抽放半径研究

为了测定申家庄煤矿顺层钻孔在合理抽采时间内的有效抽放半径,将瓦斯压力作为测定考察指标,利用灰色关联度分析验证有效压力降低钻孔,并利用曲线拟合抽放半径与抽放时间的关系。结果表明:当抽放钻孔为Ф94 mm时,合理抽放时间为60 d的有效抽放半径为5.5 m。     

埃索美拉唑钠的波谱学数据和结构确证

建立利用分析仪器确证埃索美拉唑钠化学结构的方法。利用UV、IR、NMR、MS对埃索美拉唑钠进行了结构分析。对埃索美拉唑钠的红外吸收光谱(IR)、核磁共振氢谱(1H NMR)、氢-氢相关谱(1H-1H COSY)、核磁共振碳谱13C NMR、DEPT谱、碳氢相关谱(HMQC)、碳氢远程相关谱(HMBC)及质谱(MS)进行了解析,对其所有的NMR谱信号进行了归属;讨论了红外光谱特征吸收峰所对应的官能团的振动形式,确证了埃索美拉唑钠的结构为S-5-甲氧基-2-{[(4-甲氧基-3,5-二甲基-2-吡啶基)甲基]亚磺酰基}-1H-苯并咪唑钠。本研究为埃索美拉唑钠的结构鉴定提供了依据。     

Metal‐Free Autoxidative Nitrooxylation of Alkenyl Oximes with Molecular Oxygen

A metal‐free aerobic autoxidative nitrooxylation of alkenyl oximes mediated by tert‐butyl nitrite is described. Molecular oxygen is used as the oxidizing reagent, avoiding use of organic trapping reagents such as 2,2,6,6‐tetramethylpiperidine 1‐oxyl (TEMPO). The desired products were obtained in generally high yields.

     

Enhanced mechanical,thermal and dielectric properties of polyimide nanocomposites containing SiCp (SiCw) nanofillers for high energy-storage applications

Journal of Polymer Research - In this paper, we aimed to develop the nanocarrier based on poly (N-isopropyl acrylamide)—allyl acetoacetate grafted MoS2 nanosheets. The obtained polymer...     

Preparation of lightweight and hydrophobic natural biomass-based carbon aerogels for adsorption oils and organic solvents

Journal of Porous Materials - In the present work, an excellent carbon aerogel (PCA) with low density, hydrophobicity and porous structure has been successfully prepared by hydrothermal...     

镀铜钢纤维表面改性及其耐腐蚀性能和黏结性能

为了改善镀铜钢纤维与水泥基体的黏结强度,用γ-甲基丙烯酰氧基丙基三甲氧基硅烷(MPS)和γ-巯基丙基三甲氧基硅烷(MPTS)对镀铜钢纤维进行表面处理.采用红外光谱、扫描电子显微镜(SEM)、氯化钠溶液浸泡腐蚀试验和黏结强度测试来评价处理后镀铜钢纤维的性能.结果表明:MPTS与镀铜钢纤维表面发生了化学键合,提升了钢纤维表面粗糙度;经过MPS处理和MPTS/MPS组合处理的钢纤维腐蚀溶液的吸光度积分只有未处理组的91%和45%;经过MPS处理和MPTS/MPS组合处理的钢纤维从水泥基体中拔出时所做的功相对于未改性组分别提升了43%和224%,与水泥基体的黏结强度得到了相应提高.     

Numerical modeling of the 2008 Wenchuan earthquake-triggered Niumiangou landslide considering effects of pore-water pressure

Bulletin of Engineering Geology and the Environment - Ring-shear experiments are commonly conducted to analyze the kinematic mechanisms of landslides triggered by earthquakes, particularly for...     

Analysis of stress evolution characteristics during TBM excavation in deep buried tunnels

Bulletin of Engineering Geology and the Environment - Full-face tunnel boring machines (TBMs) are widely used in tunnel engineering projects as an efficient, safe and economical tunneling method....