Bimetal cup hydroforming of Al/St and Cu/St composites: Adaptive finite element analysis and experimental study

Journal of Mechanical Science and Technology - An adaptive Finite element analysis (FEA) was proposed in this paper for the industrial design of bimetal conical-cylindrical cup hydroforming....     

Investigation of poly(methyl acrylate) grafted chitosan as a polymeric drug carrier

The graft copolymerization of methyl acrylate (MA) onto chitosan in aqueous medium was investigated using potassium persulfate (KPS) as initiator. The grafting conditions were optimized by studying the effects of the polymerization variables (the initiator concentration, the ratio of monomer to chitosan, and reaction temperature) on the percentage of grafting (PG). PG was found to depend on these variables, and the highest grafting percentage (256 %) could be obtained at chitosan = 1 g, KPS = 4.5 × 10^?3 M, methyl acrylate monomer = 6 g, T = 60 °C and t = 180 min. The graft copolymer was characterized by Fourier transform infrared spectra analysis, thermogravimetry (differential thermogravimetry, differential scanning calorimetric), X-ray powder diffraction as well as CP-MAS ¹³C NMR spectroscopy. These analyses are highly confirmed the formation of poly(methyl acrylate) grafted chitosan (PMAGC). Furthermore, the gelation of the grafted polymers (PG 68, 122, 218 and 256 %) in distilled water has been studied, and the results revealed that the percentage of swelling number increase with increasing PG of the polymers. Controlled release of niacin (vitamin B₃) from the hydrogel of the grafted polymers (PG 68, 122 and 256 %) in aqueous medium has been studied using ultraviolet absorption to follow quantities released at different times (for each experiment: PMAGC 100 mg, niacin 2.46 mg, distilled water 100 ml). The study was repeated again with same conditions except the using of 4.92 mg of niacin instead of 2.46 mg (PG of the grafted polymer is 256 %). The diffusion coefficient (D, cm²/h) of niacin from the hydrogel of the grafted polymer (PG 256 %) was calculated depending on Higuchi model (diffusion coefficient of the first load is 0.00194 cm²/h while 0.00255 cm²/h of the second load).     

Preparation of 2-Aroyl-3-methyl-1H-1,4-benzothiazines. ESR Study of 2-benzoyl-1,3-dimethyl-1H-1,4-benzothiazine

2-Aroyl-3-methyl-1 H-1,4-benzothiazine ylids ( 2a – k ) were prepared by alkylation of the corresponding 4H-benzothiazines 1 . The ylids 2 are labile at room temperature; proper analytical and ¹H-n.m.r. data were obtained for their picrates. E.s.r. studies of u. v. irradiated polycrystalline form of ( 2 ; R¹ = Me, R² = H) gave evidence for a long-lived benzothiazinyl radical with the odd electron residing on nitrogen 6 .     

Investigation of synergistic effect of nano sized Ag/TiO2 particles on antibacterial,physical and mechanical properties of UV-curable clear coatings by experimental design

The synergistic effect of nano titanium dioxide (10 and 30 nm) and nano silver (10 nm) as antibacterial agents were investigated on UV curable clear coating. Antibacterial and physical–mechanical properties of coating were optimized using experimental design in response surface method. Twenty different samples of nano Ag and nano TiO₂ were prepared in this method. Antibacterial properties on Gram-negative bacteria (Escherichia coli) were investigated. The results revealed that using equal amounts of two sizes of nano TiO₂ promote the antibacterial activity of nano Ag. So, the coating shows strong activity against E. coli. Physical–mechanical properties such as surface hardness, abrasion resistance, scratch resistance and gloss of the coating were evaluated. The results depicted appropriate physical–mechanical properties. Also, scanning electron microscope (SEM), atomic force microscope (AFM) and Fourier transform infrared (FT-IR) spectroscopy were used to study the effect of nano particles on coating properties.     

基于耗散函数的叶顶泄漏流动非定常数值模拟

更进一步的改善间隙泄漏流动需要对其复杂的流动结构作深入的认识，若不能给出间隙泄漏流动影响更真实的表述将导致对其研究无法进行。为了更深入的认识涡轮叶栅流动粘性耗散的细节及分布，作者采用商用N-S求解器对具有动叶顶部间隙的涡轮级非定常流场进行了数值模拟和研究。本文引入耗散函数对间隙泄漏流动的粘性耗散进行评估，这种方法是对粘性影响带来的粘性耗散的最简单也是最直接模拟和计算方法。     

Geoenvironmental assessment of the formation and expansion of earth fissures as geological hazards along the route of the Haram-to-Haram Highway,Iran

This study assessed the mechanisms and agents that have contributed to the formation and expansion of earth fissures along the route of the Haram-to-Haram Highway in Iran. To this end, several geological and geotechnical approaches were used, including comprehensive field investigations, in situ tests, soil sampling, and laboratory assessments. Results showed that a combination of shallow and deep mechanisms and various geoenvironmental agents contributed to fissure formation and expansion in the study area, with soil characteristics playing a significant part in the fissuring. This study indicated that earth fissuring is an ongoing problem in the study area that endangers the safety of highway traffic. However, some applicable remedial measures that could mitigate the problem and protect the highway from the adverse consequences of the earth fissuring are also proposed herein.     

A parsimonious SVM model selection criterion for classification of real-world data sets via an adaptive population-based algorithm

This paper proposes and optimizes a two-term cost function consisting of a sparseness term and a generalized v-fold cross-validation term by a new adaptive particle swarm optimization (APSO). APSO updates its parameters adaptively based on a dynamic feedback from the success rate of the each particle’s personal best. Since the proposed cost function is based on the choosing fewer numbers of support vectors, the complexity of SVM model is decreased while the accuracy remains in an acceptable range. Therefore, the testing time decreases and makes SVM more applicable for practical applications in real data sets. A comparative study on data sets of UCI database is performed between the proposed cost function and conventional cost function to demonstrate the effectiveness of the proposed cost function.

     

Highly-efficient technique for automatic segmentation of X-ray bone images based on fuzzy logic and an edge detection technique

Multidimensional Systems and Signal Processing - Development of medical image segmentation techniques has become one of the most important challenges in many applications that employ...     

Synthesis and structural characterization of a liquid polyisoprene bearing amidoxime end groups

Azo-bis(isobutyroamidoxime) was synthesized and used as functionalized initiator to prepare a liquid isoprene bearing amidoxime end groups via radical polymerization. The polymer was characterized by FT-IR, Gel Permeation Chromatography and NMR. In particular, the structure of the polymer was investigated using 1D and 2D NMR techniques. The distribution of the different isoprene units (1,4-trans, 1,4-cis, 1,2 and 3,4), as well as the structure of the amidoxime end-groups was determined. It was found that the structure of the end groups was governed by the steric hindrance of the initiator. Only 1,4 and 4,1 functionalized end units were evidenced, with a majority of 4,1 end units.     

Synthesis and dissolution behavior of nanosized silicon and magnesium co-doped fluorapatite obtained by high energy ball milling

Nanosized hydroxyapatite (HA) powders exhibit a greater surface area than coarser crystals and are expected to show an improved bioactivity. In addition, properties of HA can be tailored over a wide range by incorporating different ions into HA lattice. The aim of this study was to prepare and characterize silicon and magnesium co-doped fluorapatite (Si–Mg–FA) with a chemical composition of Ca_9.5Mg_0.5 (PO₄)_5.5(SiO₄)_0.5F₂ by the high-energy ball milling method. Characterization techniques such as X-ray diffraction analysis (XRD), Fourier transformed infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX) and transmission electron microscopy (TEM) were utilized to investigate the structural properties of the obtained powders. Dissolution behavior was evaluated in simulated body fluid (SBF) and physiological normal saline solution at 37 °C for up to 28 days. The results of XRD and FTIR showed that nanocrystalline single-phase Si–Mg–FA powders were synthesized after 12 h of milling. In addition, incorporation of magnesium and silicon into fluorapatite lattice decreased the crystallite size from 53 nm to 40 nm and increased the lattice strain from 0.220% to 0.296%. Dissolution studies revealed that Si–Mg–FA in comparison to fluorapatite (FA), releases more Ca, P and Mg ions into SBF during immersion. 175 ppm Ca, 33.5 ppm P and 48 ppm Mg were detected in the SBF containing Si–Mg–FA after 7days of immersion, while for FA, it was 75 ppm Ca, 21.5 ppm P and 29 ppm Mg. Release of these ions could improve the bioactivity of the obtained nanopowder. It could be concluded that the prepared nanopowders have structural properties such as crystallite size (~40 nm), crystallinity degree (~40%) and chemical composition similar to biological apatite. Therefore, prepared Si–Mg–FA nanopowders are expected to be appropriate candidates for bone substitution materials and also as a phase in polymer or ceramic-based composites for bone regeneration in tissue engineering applications.