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51.
Horacio Toniolo Jeff Derry Ken Irving William Schnabel 《Canadian Metallurgical Quarterly》2010,136(11):935-939
Rivers located on the North Slope of Alaska’s Brooks Range are typically not well characterized with respect to basic hydraulic and sedimentological data. In order to obtain basic hydrosedimentological information on the Anaktuvuk River, a pristine stream located in the Colville River basin, we conducted an extensive field campaign from late May to early June 2009. The study reach was located at N69°27.785′, W151°09.858′, latitude and longitude, respectively. The Anaktuvuk River flows north from the Brooks Range to the Colville River, drains an area of 7,058?km2, and encompasses 2,063 m of vertical relief. During the field campaign, the field crew measured discharge and water-surface slope, collected water samples, and characterized bed sediment. As a result of fieldwork and laboratory work, we present an initial rating curve for the Anaktuvuk River, as well as the calculated roughness coefficient and suspended sediment concentrations. In addition, we compare the observed bankfull discharges with the bankfull discharge predicted by a recently published model. 相似文献
52.
Bernal RA Agrawal R Peng B Bertness KA Sanford NA Davydov AV Espinosa HD 《Nano letters》2011,11(2):548-555
We characterized the elastic properties of GaN nanowires grown along different crystallographic orientations. In situ transmission electron microscopy tensile tests were conducted using a MEMS-based nanoscale testing system. Complementary atomistic simulations were performed using density functional theory and molecular dynamics. Our work establishes that elasticity size dependence is limited to nanowires with diameters smaller than 20 nm. For larger diameters, the elastic modulus converges to the bulk values of 300 GPa for c-axis and 267 GPa for a- and m-axis. 相似文献
53.
54.
Bao Zhang Serge Gavras Anumalasetty V. Nagasekhar Carlos Horacio Cáceres Mark A. Easton 《Metallurgical and Materials Transactions A》2014,45(10):4386-4397
3D numerical images of the intergranular percolating eutectic of two binary alloys, Mg-0.62 at. pctLa and Mg-0.60 at. pctNd, created using dual beam FIB tomography, were incorporated into an FEM code to model their tensile behavior. Due to its high volume fraction (29.9 pct), the behavior of the Mg-La network was akin to that of a stretch-dominated micro-truss structure, whereas the Mg-Nd’s, with a relatively low volume fraction (7.5 pct), mimicked that of a bending-dominated structure. The 3D network contributed some 37 MPa to the strength of the Mg-La alloy casting, whereas it only added about 1.4 MPa to the Mg-Nd’s. The model predictions based on the binary alloys were verified using cast-to-shape specimens of the Mg-La and two ternary Mg-La-Nd alloys, subjected to a flash-annealing aiming at breaking up the continuity of the 3D network, while preserving the rest of the microstructure unchanged. The flash-annealed specimens exhibited a decrease in strength that matched closely the computed values. Implications regarding alloy design involving the eutectic network and solid solution hardening of more complex alloys are discussed. 相似文献
55.
Virginia Melo-Ruiz Yomas Quirino-Barreda Concepcion Calvo-Carrillo Karina Sanchez-Herrera Horacio Sandoval-Trujillo 《化学与化工:英文版》2013,(12):1181-1187
Edible insects, escamoles ant eggs of the Formicidae family are consumed by cultural tradition at rural communities and by sensory characteristics at high class restaurants of Mexico; however, people ignore the importance of insect consumption in the nutrition of humans. Laboratory spectroscopy methods in food analysis represent benefits in time and precision. The aim of this study is to assess macronutrients and micronutrients of escamoles and eggs by spectroscopic methods to inform population the benefits they provide in health and to mention the advantage in the use of these techniques at laboratory work. Samples were gather the second week of March and April 2012, at Hidalgo State and analyze moisture and macronutrients by AOAC (Association of Official Analytical Chemistry) methods, amino acids by cation exchange chromatography, tryptophan was determined by a colorimeter method, fatty acids by GC (gas chromatography) using helium as a carrier (AOAC), fat soluble vitamins A, D and E by HPLC (high performance liquid chromatography), and minerals by atomic absorption spectrophotometers and phosphorus by colorimeter (AOAC). Data showed high amount in proteins, lipids and minerals; low in fiber and soluble carbohydrates; contained all essential amino acids. Fatty acids contain monounsaturated and polyunsaturated. Fat soluble vitamins A, D and E. Minerals: sodium, phosphorus, potassium, magnesium, calcium and manganese. Escamoles ant eggs include polyunsaturated fatty acids essential for mental development, vitamin A to prevent eye diseases, vitamin E as antioxidant and vitamin D involved in calcium absorption that low intake, impair grow and bone health. Iron and zinc contained anemia. Regarding the laboratory benefits, needs less expensive chemicals, testing is clean, rapid and easy results of multiple samples, but it is required to handle by qualified chemists. In conclusion, data may change according to biotic and abiotic conditions of the environment; however, escamoles have all nutrients in adequate balance to improve human health; and provide faster and precise results. 相似文献
56.
Psychrotrophic bacteria behaviour, when gamma irradiation is applied with shelf-life extension purposes to a fresh squid product, was modelled. In this regard, the effect of gamma irradiation at 0, 1.8, 3.3 and 5.8 kGy on psychrotrophic microorganisms in vacuum-packed squid (Illex argentinus) rings was analysed during storage at 4–5 °C. First-order kinetics satisfactorily described the radio-induced inactivation of the initial psychrotrophs population. The growth of surviving bacteria during storage was fitted to two empirical models: modified Gompertz model and a polynomial expression dependent on irradiation dose and storage time. In turn, the influence of irradiation dose on kinetic parameters of Gompertz model was described by second order polynomials. Both proposed models satisfactorily described the behaviour of psychrotrophs as affected by gamma irradiation, allowing accurate shelf-life predictions for doses up to 5.3 kGy. Considering the predictions accuracy, complete Gompertz model was preferred and model validation was done for irradiation at 4.8 kGy. 相似文献
57.
Ana I Pardo‐García Ana M Martínez‐Gil Horacio López‐Córcoles Amaya Zalacain Rosario Salinas 《Journal of the science of food and agriculture》2013,93(5):1147-1155
BACKGROUND: The present work was carried out because there is only a small amount of literature on how the volatile composition of tomatoes can be modified by the effect of exogenous substances in contact with tomato plants. This work studies how eugenol and guaiacol, either by foliar application and/or in the surrounding atmosphere, can affect the volatile composition of this fruit. An important work of this study was also conduced to validate the analytical method [headspace stir bar sorptive extraction–gas chromatography–mass spectrometry (HS‐SBSE‐GC‐MS)] to determine the composition of the volatiles in tomato. RESULTS: Analytical method validation parameters such as linearity, limit of detection, limit of quantification, and recovery proved that this method is suitable for the analysis of tomato volatiles. Their eugenol and guaiacol content changed, with an increase of 200 and 35 times, respectively, when foliar treatment was used, and an increase of 10, in both cases, when plants were in contact with the contaminated atmosphere. As consequence of the treatments other volatile compounds changed considerably. CONCLUSION: For first time, a HS‐SBSE‐GC‐MS method was successfully validated for the study of volatiles in tomatos. Results suggests that exogenous compounds in contact with the plants, such as eugenol and guaiacol, can be absorbed changing the global volatile composition of fruits, which could produce a negative or positive effect in their aroma. © 2012 Society of Chemical Industry 相似文献
58.
Mirna E. Sigrist Horacio R. Beldomenico Enrique E. Tarifa Carlos L. Pieck Carlos R. Vera 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2011,86(10):1256-1264
BACKGROUND: Arsenic decontamination of drinking water by adsorption is a simple and robust operation. When designing packed bed adsorbers for arsenic, the main problems are the slow diffusion kinetics of As in microporous media and the lack of simple equations for predicting the performance of the equipment. Commercial iron‐doped granular activated carbon adsorbents (Fe/GAC) for groundwater arsenic abatement were studied in this work. Basic parameters for arsenate (AsV) adsorption were measured and their performance at larger scale was simulated with an approximate analytical model. RESULTS: In the 0–300 µgAs L?1 range, the AsV adsorption isotherm on Fe/GAC was found to be approximately linear. Assuming Henry's law for adsorption and homogeneous surface diffusion with constant diffusivity for intrapellet mass transfer, an approximate model for flow and adsorption of arsenate inside packed bed adsorbers was developed, and reduced to an analytic compact solution using the quasi‐lognormal distribution (Q‐LND) approximation. The use of this model with fitted and reported parameters enabled the approximate simulation of industrial adsorbers and home point‐of‐use filters. Results show that industrial adsorbers meet the breakthrough condition with incomplete utilization of the adsorbent unless convenient process configurations are used. In point‐of‐use systems with short residence times intraparticle diffusion would drastically reduce the adsorbent performance. CONCLUSION: Assuming linear adsorption of AsV over Fe/GAC, an analytical approximate solution for flow and adsorption in packed beds can be obtained. The model seems to represent correctly the main features of industrial and home filters, however, more experimental data is necessary for scale‐up purposes. Copyright © 2011 Society of Chemical Industry 相似文献
59.
Horacio Cardenas Daniel Arango Courtney Nicholas Silvia Duarte Gerard J. Nuovo Wei He Oliver H. Voss M. Elba Gonzalez-Mejia Denis C. Guttridge Erich Grotewold Andrea I. Doseff 《International journal of molecular sciences》2016,17(3)
The increasing prevalence of inflammatory diseases and the adverse effects associated with the long-term use of current anti-inflammatory therapies prompt the identification of alternative approaches to reestablish immune balance. Apigenin, an abundant dietary flavonoid, is emerging as a potential regulator of inflammation. Here, we show that apigenin has immune-regulatory activity in vivo. Apigenin conferred survival to mice treated with a lethal dose of Lipopolysaccharide (LPS) restoring normal cardiac function and heart mitochondrial Complex I activity. Despite the adverse effects associated with high levels of splenocyte apoptosis in septic models, apigenin had no effect on reducing cell death. However, we found that apigenin decreased LPS-induced apoptosis in lungs, infiltration of inflammatory cells and chemotactic factors’ accumulation, re-establishing normal lung architecture. Using NF-κB luciferase transgenic mice, we found that apigenin effectively modulated NF-κB activity in the lungs, suggesting the ability of dietary compounds to exert immune-regulatory activity in an organ-specific manner. Collectively, these findings provide novel insights into the underlying immune-regulatory mechanisms of dietary nutraceuticals in vivo. 相似文献
60.
Marcella Trombetta Tiziana Armaroli Aìda Gutirrez Alejandre Horacio Gonzalez Jorge Ramirez Solis Guido Busca 《Catalysis Today》2001,65(2-4):285-292
The interaction of HZSM5 and Mo-ZSM5 with benzene, naphthalene, toluene, ortho-xylene, para-xylene, n-butane, isobutane, n-heptane, and methylcyclohexane, in the range 100–773 K has been investigated using FT-IR spectroscopy. Hydrogen bonded species with the internal bridging and the external terminal OHs has been detected. The reactivity at high temperature has also been studied. The access to the internal cavities and to the strongly acidic OHs is at least partly hindered in the case of Mo-ZSM5. The catalytic activity of ZSM5 was moderated by the addition of molybdenum, with lower cracking and higher liquid yields. 相似文献