Modelling and simulation of KNbO3 ceramics dispersion

The dispersion of potassium niobate (KNbO₃) ceramics is analysed using the multiple-arc approach. This has revealed a high frequency arc that is unattainable by the Cole-Cole single arc analysis. The temperature dependence of the new arc is derived through the spread parameter of the relaxation distribution and interpreted in terms of the ferroelectric property of the KNbO₃ ceramics. It is shown that the overall dispersion behaviour of the ceramics is mainly due to the existence of two distinctly different polarisation mechanisms. The arc approach has also provided an effective tool for network simulation of dispersion whereby the ceramics are modelled by nine parallel R-C branches over the frequency range 10²-10⁵ Hz used     

Electrophoretic deposition of electrolyte materials for solid oxide fuel cells

Electrophoretic deposition of electrolyte materials for solid oxide fuel cells, including La_0.8Sr_0.2Ga_0.875Mg_0.125O_3–x , yttria stabilized zirconia and (Ce_0.8Gd_0.2)O_1.9, was studied under various experimental conditions. The use of phosphate ester as a dispersant and poly (vinyl butyral) as a binder enabled high deposition rate and formation of crack-free, adherent deposits. Electrodeposition rates were quantified in experiments performed at constant current and constant voltage modes from suspensions in ethanol, isopropanol and mixed ethanol—isopropanol solvents. The microstructure of as prepared and sintered deposits was studied by electron microscopy. The bath composition was optimized to enable formation of dense deposits.     

Filtration efficiency and the percolation phenomenon in a grooved-plate Separator

We present here the results of a study of the separation process in the extraction matrix of a novel high-intensity magnetic separator (HIMS). The matrix uses an ordered array of grooved plates (replacing conventional collectors, which are generally made of wires). Only experimental results are available for grooved plates in the literature, but here we propose a new theoretical approach. We report on the particles' behavior, the existence of a percolation phenomenon, and the filtration efficiency, in order to analyze and compare the performance of matrix structures (Lenoir's and Jones'). We discuss the causes of the percolation phenomenon and its effect on filtration efficiency. Correspondence between the theory and the experiments is good. We suggest appropriate uses of each matrix structure according to the property of the processed particles.     

Thermal Transformations of an Aluminoborophosphate Binder

Thermal transformations of a commercial aluminoborophosphate binder are studied in a broad temperature range by optical microscopy, x-ray diffraction, IR spectroscopy, and thermal analysis. The introduction of B₂O₃ reduces the temperature of phosphate polycondensation, enhances the stability of cyclometaphosphates in a broad temperature range (180–1100°C), and reduces the stability of hydrogen phosphates.     

Relaxor Behavior of Ge-Doped TlInS2

The dielectric and pyroelectric properties of Ge-doped (0.1 mol %) TlInS₂ crystals are studied. The results demonstrate that TlInS₂ is a ferroelectric relaxor. The experimental data are used to evaluate, using the Vogel–Fulcher relation, the activation energy (0.045 eV), preexponential factor (f ₀ = 2 × 10¹³ Hz), and the dipole-freezing temperature (T _F = 142 K) and to determine the temperature range of the stable relaxor (nanodomain) state and the temperature of the transition to the ferroelectric (macrodomain) state, accompanied by an anomaly in the temperature-dependent pyroelectric coefficient.     

A test for the statistical significance of DNA sequence similarities for application in databank searches

A method is developed, based on word-searching, which provides a rapid test for the statistical significance of DNA sequence similarities for use in databank searching. The method makes allowance for the lengths and dinucleotide compositions of the sequences being compared. A way is also described to calculate the power of the test, i.e. the probability of detecting a given similarity as being statistically significant. The effects on the power of the test of the scoring method, word length, sequence length, and sequence composition are examined. A novel scoring method is shown to be superior to the method currently used in most word-searching algorithms.