On studying methods for cleaning dielectric oil for impregnation of high-voltage pulse capacitors with film dielectric

Methods for cleaning commercial T-1500 dielectric oil with different adsorbents are studied. The oil is intended for impregnation of high-voltage pulse capacitors with film dielectric.     

Environmentally friendly, heterogeneous acid and base catalysis for the methylation of catechol: Chances for the control of chemo-selectivity

The properties of catalysts with (i) Brønsted-type acidity (H-mordenite and Al/P mixed oxide), (ii) Lewis-type acidity (Al trifluoride) or (iii) basic characteristics (Mg/Fe mixed oxide) were investigated in the gas-phase methylation of catechol. When methanol was used as the methylating agent, H-mordenite and AlF₃ gave high selectivities to guaiacol (the product of O-methylation) under mild reaction conditions, that is at very low catechol conversions. An increase in temperature led to the transformation of guaiacol to phenol and cresols, and to considerable catalyst deactivation. The basic catalyst Mg/Fe/O also favored an extensive degradation of guaiacol to phenol. On the mildly acidic catalyst Al/P mixed oxide a stable catalytic performance and a high selectivity to guaiacol at 40% catechol conversion were obtained. When methylformate, a more reactive methylating agent, was used with AlF₃ and Mg/Fe mixed oxide as catalysts, higher catechol conversions and slower deactivation rates could be achieved under mild reaction conditions, with a low extent of guaiacol degradation. However, methylformate rapidly decomposed when temperatures above 350 °C were used. Finally, tests were made by reacting catechol and diethoxymethane with acid catalysts, with the aim of synthesizing methylenedioxybenzene. The latter product was obtained with high selectivity, but with very low yield, due to both catalyst deactivation and decomposition of diethoxymethane.     

Repetitively pulsed Nd-glass slab lasers

The possibility of obtaining high laser output energies at a 1.32-μm wavelength using thin LiNdLa phosphate glass slabs with a high Nd³⁺ concentration is discussed. In the experiments, 3×14×125-mm slabs were prepared from LiNdLa phosphate glass with a Nd-concentration of 1.2×10²¹ cm^-3. The facets of the slabs were not antireflection-coated. They were tested in a silver-coated quartz tube reflector of 25-mm diameter and pumped by 450-μs pulses from a flash lamp with a 120-mm arc length. In this construction the light, which passes through the slab, returns to it after reflection from the tube surface. Most of the radiation falls on the wider side of the slab at large angles of incidence, thus maximizing its path inside the slab. The quartz reflector was water cooled. The 150-mm laser resonator was formed by two flat mirrors. At 1.32-μm lasing wavelength an output mirror of r=95% reflectivity was used with less than 10% reflectivity at 1.32 μm     

The determinants of heat-shock element-directed lacZ expression in Saccharomyces cerevisiae.

Heat-shock induction of heat-shock protein genes is due to a specific promoter element (the heat-shock element, HSE). This study used lacZ under HSE control (HSE-lacZ) to characterize HSE activity in Saccharomyces cerevisiae cells of different physiological states and differing genetic backgrounds. In batch fermentations HSE-lacZ induction by heat shock was maximal in exponential growth, and showed marked decline with the approach to stationary phase. Expression in the absence of heat shock was unaffected by growth phase, indicating that the growth-dependent expression of many yeast heat-shock genes uses promoter elements in addition to the HSE. Heat-induced expression was strongly influenced by the temperature at which cultures were grown. While basal, uninduced expression was constant during growth at different temperatures to 30 degrees C, induction by transfer to 39 degrees C was reduced by increases in growth temperature as low as 18-24 degrees C. Maximal HSE-lacZ induction (30- to 50-fold) was in cultures grown at low temperatures (18-24 degrees C), then heat shocked at 39 degrees C. Ethanol was a poor inducer. Mutations having little effect on HSE-lacZ expression included a respiratory petite; ubi4 (which inactivates the poly-ubiquitin gene); also ubc4 and ubc5 (which each inactivate one of the ubiquitin ligases involved in degradation of aberrant protein). pep4-3 increased both basal and induced beta-galactosidase about two-fold, probably because of slower turnover of this enzyme in pep4-3 strains.     

Dynamic fields generated by rapid crack growth

Stresses and strains near a rapidly propagating crack tip are affected by the mass density of the material. This paper starts with a brief summary of analytical results for near-tip dynamic fields as predicted by linear elastic fracture mechanics. Next, exact expressions are derived for dynamic crack-line strains, for mode-III crack propagation in a nonlinear elastic material and in an elastic perfectly-plastic material. These expressions are valid on the crack line from the moving crack tip to the moving boundary with the region of linearly elastic deformation. For steady-state crack growth, a critical strain criterion is used to compute the relation between external load and crack tip speed. The required external load increases with crack-tip speed.