Assessment of the Superheater Ash Fouling Using a Numerical Model of the Superheater

ABSTRACT

Superheaters are high-temperature cross-flow heat exchangers. Steam flows inside the tubes, and the flue gas outside in a direction perpendicular to the axes of the tubes. However, they differ very substantially from the other heat exchangers operating at low temperatures. Superheaters are characterized by complex flow system and high tube walls temperature. Superheaters are among the most exposed to damaging pressure elements of steam boilers. Damage to the superheater causes about 40% of emergency shutdowns of boilers. The paper presents the boiler superheater model with distributed parameters, which is used to determine on-line the degree of superheater fouling by ash.     

Non‐parametric probabilistic forecasts of wind power: required properties and evaluation

Predictions of wind power production for horizons up to 48–72 h ahead comprise a highly valuable input to the methods for the daily management or trading of wind generation. Today, users of wind power predictions are not only provided with point predictions, which are estimates of the conditional expectation of the wind generation for each look‐ahead time, but also with uncertainty estimates given by probabilistic forecasts. In order to avoid assumptions on the shape of predictive distributions, these probabilistic predictions are produced from non‐parametric methods, and then take the form of a single or a set of quantile forecasts. The required and desirable properties of such probabilistic forecasts are defined and a framework for their evaluation is proposed. This framework is applied for evaluating the quality of two statistical methods producing full predictive distributions from point predictions of wind power. These distributions are defined by a number of quantile forecasts with nominal proportions spanning the unit interval. The relevance and interest of the introduced evaluation framework are discussed. Copyright © 2007 John Wiley & Sons, Ltd.     

Disclosure: Chaotic implementation thwarts intention of directive

Jan Willem Langeraar of Ecofys and Rolf de Vos of Greenprices argue that, as well as the Guarantee of Origin (see Refocus, Jul/Aug 2003, p. 62), European harmonisation is also needed for the mandatory disclosure of the fuel mix (legislation to be implemented before July 1st 2004). This they claim is needed foremost in the monitoring of the environmental quality of power generation. A harmonised way of collecting information will guarantee transparency and - in the end - establish the consumer's trust. There are several initiatives currently on the table. The implementation of the disclosure in Austria shows what the harmonisation could look like.     

Routine individual monitoring of aircraft crew exposure; Czech experience and results 1998-2008

Individual monitoring of aircrew of airline operators registered in the Czech Republic has been performed since 1998. In this work, annual effective doses and annual collective effective doses of aircrew from occupational exposure in the period from 1998 to 2008 are presented, methods used for their evaluation and verification are described, and general trends observed in the data are discussed. Annual effective doses were calculated using the computer code CARI from flight schedules provided by airline operators and typical flight profiles. The method was verified via a comparison with (i) measurements using different types of detectors and (ii) calculations using the CARI and EPCARD codes with actual flight data. It was found that average annual effective doses in the period from 1998 to 2008 were in the range from 1.2 to 2.0 mSv and followed the trend of the solar cycle. Annual collective effective doses increased from 1.4 manSv in 1998 to 4.1 manSv in 2008 as the number of aircrew increased from 857 to 2158 during this period. Combined relative uncertainties (coverage factor ) of reported individual and collective effective doses were ～ 25 %, which is well within the range given by the factor of 1.5. More work is needed to achieve a higher accuracy of this estimate.     

Knowledge production through collaborative research in sub-Saharan Africa: how much do countries contribute to each other’s knowledge output and citation impact?

This paper examines co-authorship of research articles in Thomson Reuters citation indexes in order to assess knowledge co-production in selected sub-Saharan African countries. Two indicators, namely publications and citations, were analysed to establish the patterns of knowledge co-production and its scientific impact, respectively. The study found that knowledge production through collaborative research among sub-Saharan African countries is minimal and contributes only a small percentage when compared to collaboration between sub-Saharan African countries and their foreign counterparts. Similarly, the scientific impact of international collaboration was higher than that of continental collaboration. Countries belonging to the same geographic region contributed to each other’s knowledge production more frequently than they did to the countries outside their region. It is recommended that, for knowledge co-production in sub-Saharan Africa to improve, various measures such as encouraging student and staff exchange, hosting more regional conferences and encouraging research networks need to be put in place.     

pH-dependant structural and morphology evolution of Ni(OH)2 nanostructures and their morphology retention upon thermal annealing to NiO

Nickel hydroxide nanosheets, nanobelts and nanorods were prepared by hydrothermal treatment of the precipitates obtained at different pH values. The morphology and crystal structure of the products could be controlled simply by adjusting the pH value at precipitation. Interconnected nanosheets of hexagonal β-Ni(OH)₂ with thickness around 10–20 nm were formed at pH ∼ 11, whereas nanobelts with typical widths around 40–80 nm, and nanorods with diameters around 50–60 nm of phase pure α-Ni(OH)₂ containing intercalated sulphate ions were obtained in the pH range ∼9.5–8.5. Thermal annealing of the hydroxides at 500 °C yielded cubic phase NiO with morphologies similar to their hydroxide precursors. X-ray powder diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and energy dispersive X-ray (EDX) analysis were used to characterize the as-prepared products. The role of pH in controlling the phase and morphology of the products was discussed.     

Aerobic degradation of 2,4-dinitrotoluene by individual bacterial strains and defined mixed population in submerged cultures

The degradation efficiencies of isomeric mononitrotoluenes (2- and 4-NTs) and dinitrotoluenes (2,4-DNT and 2,6-DNT) by either individual bacterial strains (Bacillus cereus NDT4, Pseudomonas putida NDT1, Pseudomonas fluorescens NDT2, and Achromobacter sp. NDT3) or their mixture were compared in submerged batch cultivations. The mixed culture degraded 2,4-DNT nearly 50 times faster than any of the individual strains. The mixed culture also demonstrated significantly shorter lag periods in 2,4-DNT degradation, a lack of nitrite or organic intermediates accumulation in the liquid medium and the ability to degrade a broader spectrum of nitrotoluenes over a wider concentration range. The presence of both readily degradable 2-NT (or 4-NT) and poorly degradable 2,6-DNT in the medium negatively affected 2,4-DNT biodegradation. However, the mixed bacterial culture still effectively degraded 2,4-DNT with only slightly lower rates under these unfavorable conditions, thus showing potential for the remediation of 2,4-DNT contaminated sites.     

Migration of Mineral Oil into Noodles from Recycled Fibres in the Paperboard Box and the Corrugated Board Transport Box as well as from Printing Inks: A Case Study

From the toxicological evaluation of mineral oils as used in offset printing inks by the Joint Food and Agriculture Organization of the United Nations/World Health Organization Expert Committee on Food Additives (JECFA), a specific migration limit of 0.6 mg/kg in food can be derived. Experimental packs for taglioline (fine noodles) were investigated, aiming at respecting this limit. This ended with four conclusions. First, during the 65 day test (shelf life of 2 years), the transport box of corrugated board contaminated the bottom packs in the box with 6.1 mg/kg mineral oil saturated hydrocarbons (MOSH) and had the potential of contaminating all the 10 packs on average at about 10 mg/kg. Second, the migration from an improved recycled paperboard (five times less mineral oil than average) still amounted to 4.9 mg/kg, indicating that optimization of recycling is not promising to respect the 0.6 mg/kg limit. Third, a printing ink containing 3 g/kg MOSH (about 100 times less than conventional offset inks) still contaminated the taglioline with 0.6 mg/kg MOSH. Finally, the taglioline were contaminated with 2.5 mg/kg MOSH already before packing, illustrating that there are other sources of mineral oil violating the 0.6 mg/kg limit. Copyright © 2011 John Wiley & Sons, Ltd.