Anaerobic methane oxidation and aerobic methane production in an east African great lake (Lake Kivu)

We investigated CH₄ oxidation in the water column of Lake Kivu, a deep meromictic tropical lake with CH₄-rich anoxic deep waters. Depth profiles of dissolved gases (CH₄ and N₂O) and a diversity of potential electron acceptors for anaerobic CH₄ oxidation (NO₃^?, SO₄^2?, Fe and Mn oxides) were determined during six field campaigns between June 2011 and August 2014. Denitrification measurements based on stable isotope labelling experiments were performed twice. In addition, we quantified aerobic and anaerobic CH₄ oxidation, NO₃^? and SO₄^2? consumption rates, with and without the presence of an inhibitor of SO₄^2?-reducing bacteria activity. Aerobic CH₄ production was also measured in parallel incubations with the addition of an inhibitor of aerobic CH₄ oxidation. The maximum aerobic and anaerobic CH₄ oxidation rates were estimated to be 27?±?2 and 16?±?8?μmol/L/d, respectively. We observed a difference in the relative importance of aerobic and anaerobic CH₄ oxidation during the rainy and the dry season, with a greater role for aerobic oxidation during the dry season. Lower anaerobic CH₄ oxidation rates were measured in presence of molybdate in half of the measurements, suggesting the occurrence of linkage between SO₄^2? reduction and anaerobic CH₄ oxidation. NO₃^? consumption and dissolved Mn production rates were never high enough to sustain the measured anaerobic CH₄ oxidation, reinforcing the idea of a coupling between SO₄^2? reduction and CH₄ oxidation in the anoxic waters of Lake Kivu. Finally, significant rates (up to 0.37?μmol/L/d) of pelagic CH₄ production were also measured in oxygenated waters.     

Electrical contact resistance between stainless steel bipolar plate and carbon felt in PEFC: A comprehensive study

Bipolar plate represents a key component of Proton Exchange Membrane Fuel Cell (PEFC) with several essential functions, among them the electric connection of elementary cells. Usually made of graphite, this component is studied worldwide in order to develop a commercially viable alternative: different ways have been being investigated, and to date, despite corrosion issues, stainless steel (SS) appears as a good candidate material, but its Electrical Contact Resistance (ECR) can reach unacceptable values when exposed to PEFC environment. This paper offers a comprehensive study of the parameters acting on ECR when using uncoated SS in PEFC: roughness, which influences the surface contact area with carbon baking, bulk composition of the alloy, which influences only partly the nature of passive films, and the composition and structure of passive films, strongly modified by surface treatments and ageing conditions.     

The effect of a scattering layer on the edge output of a luminescent solar concentrator

The effect of adding white scattering layers to the bottom side of luminescent solar concentrator waveguides is evaluated. It is determined that adding a rear scatterer separated from the waveguide by an air gap results in a large increase of energy output from the waveguides, and this enhancement persists over long (>30 cm) distances, although the magnitude of the enhancement decreases with distance. An attached scatterer resulted in the greatest improvement of light output for short (∼6 cm) distances, but actually reduced edge emissions over longer distances. We provide estimates for the relative contribution of dye-emitted light and scattered light to the total waveguide emission, as well as distinguishing between the contributions of direct and indirect scattering of light to the total output as a function of dye content of the waveguides.     

Stress-strain relationships in uniaxial extension of high cis-1,4-polyisoprene networks with different molecular weight precursors

Equilibrium stress-strain relationships in uniaxial extension for high cis-1,4-polyisoprene (Shell IR 307) networks were obtained by extrapolation of relaxation measurements to infinite time through a BKZ constitutive equation. Three series of networks were investigated, each series being characterized by its polymer precursor molecular weight. Influence of crosslinking density was studied through varying amounts of dicumyl peroxide as crosslinking agent. These results were used to test Flory and Erman's recent molecular elasticity theory of imperfect networks with constraints on junctions. It was shown that this later theory treating entanglements as restrictions on junction fluctuations could be reasonably used to characterize network topology. A universal value of 0.50 for the interpenetration parameter I is confirmed and an interpretation of parameter ζ in terms of network inhomogeneity is tentatively given.     

A hierarchical approach for planning a multisensor multizone search for a moving target

This paper deals with a well-known problem in the general area of search theory: optimize the search resources sharing so as to maximize the probability of detection of a (moving) target. However, the problem we consider here considerably differs from the classical one. First, there is a bilevel search planning and we have to consider jointly discrete and continuous optimization problems. To this perspective original methods are proposed within a common framework. Furthermore, this framework is sufficiently general and versatile so as to be easily and successfully extended to the difficult problem of the multizone multisensor search planning for a Markovian target.     

RFID behavior study in enclosed marine container for real time temperature tracking

The performance of radio waves in open environments has been studied for years. In contrast, the behavior of Radio Frequency Identification (RFID) inside metal enclosed areas is not yet understood. This research project focuses on the 3-D mapping of RFID signal strength inside a 12 m refrigerated marine container instrumented with three different types of radio frequency (RF) emitters: 915 MHz reader; 2.45 GHz reader and 433 MHz RF transmitter. The main goal is to find a frequency/configuration that would allow real time reading of the temperature in a shipment of perishable products using RFID. Only one frequency and one antenna were used at a time. The RF transmitter antenna was mounted at two different places inside the container; at the top of the front wall (facing back) and on the ceiling in the middle of the container (facing down). The signal strength was acquired by a spectrum analyzer and its antenna was mounted on a small electric cart inside the container. The cart was programmed to move along the length of the container and stop repeatedly, allowing three automated measures per position. All data were analyzed in terms of power level and attenuation. The maps showed that the RFID antenna positioned at the front of the container delivered slightly better results than the one in the middle of the ceiling. The results showed a significantly higher performance at the 433 MHz level. This article was presented at Food Processing Automation Conference, American Society of Agricultural and Biological Engineering (ASABE), Providence, RI, June 28–29 2008.     

Formation of the Perovskite Phase in the PbMg1/3Nb2/3O3─PbTiO3 System

The reaction sequences during calcination of oxide mixtures were studied for the PbMg_1/3Nb_2/3O₃─PbTiO₃ (PMN-PT) system. The effect of reactivity and composition of the starting mixtures was investigated. In the present study, a B-site-deficient, cubic pyrochlore phase in the PbO-Nb₂O₅ system was formed at 500°C. The perovskite phase of PMN was formed at 7007deg;C through the diffusion of MgO into the pyrochlore phase. The lattice parameter of the pyrochlore phase decreased as this transformation to perovskite progressed.     

Separation sequencing. use of information distance

A fast process synthesis procedure is developed for generating preliminary separation schemes. The main approach is based on similarity indices obtained from chemical, physical and operating properties between two chemical species in a separation scheme. For the whole set of species, a similarity matrix results. On this basis, algorithms for classifying chemical species and generating separation sequences are developed. A distance between flowsheets is used in order to compare different separation schemes with one another or to some reference cases. The weights of the properties and heuristics are adjusted to account for well-known optimal cases. Changes in the number of considered separation properties and in their hierarchy are also used to improve the procedure. The algorithm requires very little calculation and can even be implemented by hand in the simplest cases. Extensions of the algorithm include the use of actual values of the separation properties instead of boolean ones and the generation of non-sharp flowsheets.