A pin-electrode atmospheric-pressure CO2laser

A 1.2-m-long transversely excited atmospheric-pressure (TEA) CO2laser utilizing shower discharges is described and its operating characteristics as a function of voltage examined up to 60 kV. Pulse energies in excess of 2 J, peak powers in excess of 20 MW, and efficiencies up to 15 percent have been achieved.     

The Generalized Expectancy for Success Scale: A new measure.

Assessed the psychometric properties of a new measure of generalized expectancy for success. Three samples of White, middle-class undergraduates participated in the study. The 1st sample of 59 females and 41 males received a preliminary version of the Generalized Expectancy for Success Scale (GESS). Item analysis yielded 30 items that were substantially correlated with the total score but were not significantly related to social desirability. The 2nd sample of 63 females and 41 males received the 30-item GESS twice at a 6-wk interval. The 3rd sample of 69 females and 34 males received the GESS, the Marlowe-Crowne Social Desirability Scale, Rotter's Internal–External Locus of Control Scale, the Self-Rating Depression Scale, the Beck Depression Inventory, and the Hopelessness Scale. Results indicate that the GESS has acceptable test–retest reliability, high internal consistency, and minimal relationship with social desirability. Predicted relationships between high generalized expectancy for success, depressive symptomatology, and internality were supported. Factor analysis indicated that GESS scores are a function of one general factor. Further construct validation is reviewed, and implications for future use of the GESS are discussed. (27 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Whole lake responses to low level copper sulfate treatment

The impact of three low level copper sulfate applications to Cazenovia Lake, New York, was assessed through a high frequency monitoring program. Monitored parameters included: (1) filtered and total copper; (2) phytoplankton identification and enumeration; (3) chlorophyll-a, (4) in situ¹⁴C assimilation; (5) bacteria numbers; (6) zooplankton identification and enumeration, (7) macrophyte nutrient status and (8) filtered reactive and total phosphorus.The low level application caused only small increases (maximum of 5 μg/l) of short duration (2–5 days) in filtered copper. The treatments failed to induce effective algicidal action in the target phytoplankton populations of the lake, but they did induce short term stress and alterations in the natural seasonal succession processes within these populations. No definitive responses in the zooplankton, submerged macrophytes or water column phosphorus levels were noted. Dramatic reductions in the water column bacteria occurred immediately following each treatment, indicating direct negative impact. Phytoplankton and bacteria populations recovered within 1 week and several days, respectively.     

Brittle‐to‐Ductile Transition in Uniaxial Compression of Silicon Pillars at Room Temperature

Robust nanostructures for future devices will depend increasingly on their reliability. While great strides have been achieved for precisely evaluating electronic, magnetic, photonic, elasticity and strength properties, the same levels for fracture resistance have been lacking. Additionally, one of the self‐limiting features of materials by computational design is the knowledge that the atomistic potential is an appropriate one. A key property in establishing both of these goals is an experimentally‐determined effective surface energy or the work per unit fracture area. The difficulty with this property, which depends on extended defects such as dislocations, is measuring it accurately at the sub‐micrometer scale. In this Full Paper the discovery of an interesting size effect in compression tests on silicon pillars with sub‐micrometer diameters is presented: in uniaxial compression tests, pillars having a diameter exceeding a critical value develop cracks, whereas smaller pillars show ductility comparable to that of metals. The critical diameter is between 310 and 400 nm. To explain this transition a model based on dislocation shielding is proposed. For the first time, a quantitative method for evaluating the fracture toughness of such nanostructures is developed. This leads to the ability to propose plausible mechanisms for dislocation‐mediated fracture behavior in such small volumes.     

Temperature dependence and interferences of NO and N₂O microelectrodes used in wastewater treatment

Electrodes for nitric and nitrous oxide have been on the market for some time, but have not yet been tested for an application in wastewater treatment processes. Both sensors were therefore assessed with respect to their (non)linear response, temperature dependence and potential cross sensitivity to dissolved compounds, which are present and highly dynamic in nitrogen conversion processes (nitric oxide, nitrous oxide, nitrogen dioxide, ammonia, hydrazine, hydroxylamine, nitrous acid, oxygen, and carbon dioxide). Off-gas measurements were employed to differentiate between cross sensitivity to interfering components and chemical nitric oxide or nitrous oxide production. Significant cross sensitivities were detected for both sensors: by the nitrous oxide sensor to nitric oxide and by the nitric oxide sensor to ammonia, hydrazine, hydroxylamine and nitrous acid. These interferences could, however, be removed by correction functions. Temperature fluctuations in the range of ±1 °C lead to artifacts of ±3.5% for the nitric oxide and ±3.9% for the nitrous oxide sensor and can be corrected with exponential equations. The results from this study help to significantly shorten and optimize the determination of the correction functions and are therefore relevant for all users of nitric and nitrous oxide electrodes.     

The scanning optical microscope (extracts on near-field microscopy)—from a 1975 report

The following consists of extracts concerning near-field microscopy from a Progress Report prepared in April 1975 as Oxford University Engineering Laboratory Report No. 1883/77, describing work initiated by the late Professor R. Kompfner. Preliminary experimental work on near-field microscopy is outlined, and a theory for contrast formation is presented.     

Experimental infection of 35, 50 and 60 day old pig foetuses with porcine parvovirus

Foetuses of six seronegative gilts, two of which each respectively 35, 50 and 60 days pregnant, were inoculated intrauterinely with porcine parvovirus (PPV) and examined 7 and 11 days after inoculation. HI antibody was not detected in any of the foetuses although all but one gilt developed low levels of antibody. All but one of the foetuses inoculated with PPV died in utero prior to examination at 11 days after inoculation. Infection also spread to non-inoculated litter mates. Histological changes were mild in the gilts but there was widespread tissue necrosis in infected foetuses, and intranuclear inclusion bodies were observed in cells of the liver, lung, kidney and cerebellum. The increased survival of foetuses infected at later stages of gestation appeared to be related to increased numbers of mononuclear cells then present in many tissues.     

Fermentative hydrogen production by Clostridium butyricum and Escherichia coli in pure and cocultures

The effect of coculture of Clostridium butyricum and Escherichia coli on hydrogen production was investigated. C. butyricum and E. coli were grown separately and together as batch cultures. Gas production, growth, volatile fatty acid production and glucose degradation were monitored. Whilst C. butyricum alone produced 2.09 mol-H₂/mol-glucose the coculture produced 1.65 mol-H₂/mol-glucose. However, the coculture utilized glucose more efficiently in the batch culture, i.e., it was able to produce more H₂ (5.85 mmol H₂) in the same cultivation setting than C. butyricum (4.62 mmol H₂), before the growth limiting pH was reached.     

Prospecting hydrogen production of Escherichia coli by metabolic network modeling

Genome-scale model was applied to analyze the anaerobic metabolism of Escherichia coli. Three different methods were used to find deletions affecting fermentative hydrogen production: flux balance analysis (FBA), algorithm for blocking competing pathways (ABCP), and manual selection. Based on these methods, 81 E. coli mutants possessing one gene deletion were selected and cultivated in batch experiments. Experimental results of H₂ and biomass production were compared against the results of FBA. Several gene deletions enhancing H₂ production were found. Correctness of gene essentiality predictions of FBA for the selected genes was 78% and 77% in glucose and galactose media, respectively. 33% of the mutations that were predicted by FBA to increase H₂ production had a positive effect in experiments. Batch cultivation is a simple and straightforward experimental way to screen improvements in H₂ production. However, the ability of FBA to predict the H₂ production rate cannot be evaluated by batch experiments. Metabolic network models provide a method for gaining broader understanding of the complicated metabolic system of a cell and can aid in prospecting suitable gene deletions for enhancing H₂ production.     

Pyrolysis of peat: Product yield and characterization

Pyrolysis of peat obtained from Yeniça?a, Bolu, Turkey was conducted in a fixed-bed tube furnace under various conditions, and variations in the structure of the char, tar and gas products were examined. The chars produced were studied by proximate and ultimate analyses. The maximum tar yield of 20.41% was obtained at a heating rate of 20 °C/min, a temperature of 450 °C, a sweeping gas flow rate of 100 ml/min and a 0.5–2.0 mm size range. The chemical composition of the tar was examined by elemental analysis, FTIR spectroscopy, ¹H-NMR spectroscopy and column chromatography. The chemical composition of the tar with dense aliphatic structure was established to be CH_1.22O_0.25N_0.02. The composition of the gases obtained at a heating rate of 20 °C/min for the 0.5–2.0 mm size range was examined by gas chromatography.