锌铝镁镀层钢板前处理与电泳性能研究

以镀锌钢板作为对比,考察锌铝镁钢板涂装前处理和电泳性能.结果显示:锌铝镁钢板的脱脂性能与镀锌钢板相近,磷化膜外观、膜重、覆盖率和结晶尺寸与镀锌钢板差异较小,电泳漆膜外观、膜厚、附着力和耐冲击性与镀锌钢板一致,但电泳漆膜的杯突极限性能和划线循环腐蚀性能优于镀锌钢板.     

Molecular Dynamics Simulations Based on 1-Phenyl-4-Benzoyl-1-Hydro-Triazole ERRα Inverse Agonists

Estrogen-related receptor α (ERRα), which is overexpressed in a variety of cancers has been considered as an effective target for anticancer therapy. ERRα inverse agonists have been proven to effectively inhibit the migration and invasion of cancer cells. As few crystalline complexes have been reported, molecular dynamics (MD) simulations were carried out in this study to deepen the understanding of the interaction mechanism between inverse agonists and ERRα. The binding free energy was analyzed by the MM-GBSA method. The results show that the total binding free energy was positively correlated with the biological activity of an inverse agonist. The interaction of the inverse agonist with the hydrophobic interlayer composed of Phe328 and Phe495 had an important impact on the biological activity of inverse agonists, which was confirmed by the decomposition of energy on residues. As Glu331 flipped and formed a hydrogen bond with Arg372 in the MD simulation process, the formation of hydrogen bond interaction with Glu331 was not a necessary condition for the compound to act as an inverse agonist. These rules provide guidance for the design of new inverse agonists.     

A Dual Physical Cross-Linking Strategy to Construct Tough Hydrogels with High Strength,Excellent Fatigue Resistance,and Stretching-Induced Strengthening Effect

Hydrogels with excellent stiffness, toughness, anti-fatigue, and self-recovery properties are regarded as promising water-containing materials. In this work, a dual physically cross-linked (DPC) sodium alginate (SA)/poly[acrylamide (AAm)-acrylic acid (AAc)-octadecyl methacrylate (OMA)]-Fe³⁺ hydrogel is reported, which is constructed by hydrophobic association (HA) and ionic coordination (IC). The optimal DPC hydrogel demonstrates excellent mechanical performance: tensile modulus of 0.65 MPa, tensile strength of 3.31 MPa, elongation at break of 1547%, and toughness of 27.8 MJ m^–3. SA/P(AAm-AAc-OMA)-Fe³⁺ DPC hydrogels also exhibit prominent anti-fatigue and self-recovery performance (99.1–109.7% modulus recovery and 90.4–108.9% dissipated energy recovery after resting for 5 min without additional stimuli at ambient temperature) through the reconstruction of reversible physical cross-linking. Some of the SA/P(AAm-AAc-OMA)-Fe³⁺ DPC hydrogels even exhibit a stretching-induced strengthening effect, which is similar to the performance of muscle—“the more training, the more strength.” Hence, the combination of HA and IC will provide an effective approach to design DPC hydrogels with desirable mechanical performances and a longer service life for wider applications of soft materials.     

金属-多酚络合物用于吸附去除四环素的研究

环境中的抗生素会对生态系统和人类健康产生不利影响.吸附法被认为是去除抗生素的一种有效方法.本研究中通过简单将单宁酸(TA)与Fe3+在溶液中混合,方便快捷地获得了一种新型吸附材料金属-多酚络合物(MPN),并利用扫描电镜(SEM)、X射线能谱(XPS)、傅里叶红外光谱(FTIR)等手段对其微观结构和化学组成进行表征.此法制备的MPN材料具有良好的吸附性能,对四环素的最大平衡吸附能力可达329.5 mg·g-1.     

NiFeAlO4载氧体制备及煤化学链燃烧反应特性

铁基载氧体是一种具有工业应用前景的载氧体,但存在氧利用率低、在高温下易烧结等问题。虽可通过制备双金属复合载氧体或添加惰性组分改进其性能,但均存在一定缺陷。若将活性组分和惰性材料融入到一个晶体结构制备尖晶石结构载氧体,则可实现利用双金属协同作用提高载氧体活性的同时,利用Al3+提高载氧体的稳定性。采用共沉淀法和溶胶凝胶法制备了具有尖晶石结构的NiFeAlO₄载氧体,考察了制备方法、载氧体与煤质量比对NiFeAlO₄载氧体化学链燃烧特性和循环稳定性的影响,并分析了载氧体对煤转化过程的作用。结果表明,溶胶凝胶法制备的NiFeAlO₄载氧体具有更好的反应性,载氧体与煤质量比为20∶1时,碳转化率为86.7%,远高于煤单独热解时的碳转化率(34%),此时CO₂体积分数为93.6%。对反应前后NiFeAlO₄载氧体晶相结构和形貌进行分析,表明循环过程中经“还原-氧化”后生成的NiO和载氧体颗粒团聚是导致载氧体活性下降的主要原因。相较于载热作用,NiFeAlO₄载氧体在煤化学链燃烧中主要起供氧作用,其不仅会促进挥发分向煤气的转化,且NiFeAlO₄载氧体与焦炭之间也存在固-固反应,利于更多CO₂的生成。     

10.5/0.4kV干式变压器承受短路冲击电流能力的分析与研究

本文主要针对AP1000核电机组10.5/0.4kV低压厂用干式变压器的设计规格书与实际设备存在的技术参数偏差,根据GB 1094.5-2008和IEC 60076.5-2005中的相关理论要求,来分析该变压器承受短路冲击电流的能力是否满足要求,为后续项目变压器短路耐受能力验算提供借鉴意义,并提出了后续项目变压器采购过程中的关注点.     

含储能型虚拟同步发电机的直驱风机并网系统自适应协调阻尼控制策略

储能型虚拟同步发电机(VSG)的灵活控制特性能够为风电并网系统提供有效的频率和电压支撑,然而系统振荡特性会受到一定程度的影响,同时风电时变出力特性导致的运行点变化也将使得定参数阻尼控制表现出适应性不足的问题.为此,提出了适应风电出力时变特性的自适应协调阻尼控制策略.首先,在风电并网系统状态空间模型的基础上推导线性变参数模型,以直驱风机的有功功率为调度变量,根据稳定域确定运行空间范围;然后,利用间隙度量对运行空间进行划分,确定各子运行空间的典型运行点并将其作为多胞形顶点,建立调度增益与系统运行工况以及控制器的映射关系;最后,针对不同频率振荡模式协调设计自适应控制器.测试系统的仿真结果表明,所设计的自适应协调阻尼控制器不仅能够同时阻尼含储能型VSG并网系统中的次同步振荡和低频振荡,也能在风电出力大范围时变工况下保持良好的阻尼水平.     

离子液体改性花生壳对铬离子的吸附行为与机制

研究了用离子液体改性花生壳,并考察了改性花生壳对Cr(Ⅵ)的吸附行为与机制.结果表明:在改性花生壳用量10 g/L、温度50℃、初始Cr(Ⅵ)质量浓度10 mg/L条件下,改性花生壳对Cr(Ⅵ)的吸附率达99.82％;吸附过程符合Langmuir等温吸附模型,为单分子层吸附,吸附发生在均匀的吸附点位上,理论最大吸附量qm=9.70 mg/g;RL=0.221<1,表明吸附过程为优惠吸附;吸附过程符合准二级动力学模型,动力学常数k2=0.0452 g/(mg·min),理论平衡吸附量qe=1.14 mg/L,表明吸附过程主要为化学吸附.