甲基异氰酸酯制备方法评述

甲基异氰酸酯是一种重要的有机中间体,广泛用于氨基甲酸酯类农药合成.对甲氨基甲酰氯生产甲基异氰酸酯制备方法进行了评述.     

新型邻胺基苯甲酰胺类杀虫剂的创制研究

自主设计、合成了系列新型邻胺基苯甲酰胺类化合物,并对其进行了杀虫活性、安全性、毒性、工艺、制剂、温室和/或田间防治效果等研究,获得了Ia、Ib和Ic等系列自主知识产权的高杀虫活性化合物.结果 表明化合物Ic等对咀嚼口器害虫如粘虫和小菜蛾等的活性较邻胺基苯甲酰胺类杀虫剂氯虫苯甲酰胺水平相当或更胜一筹,对刺吸口器害虫如蚜虫等的活性远优于氯虫苯甲酰胺及溴氰虫酰胺.田间药效试验进一步证实,Ic等对咀嚼口器害虫如水稻二化螟、稻纵卷叶螟、甜菜夜蛾等的防治效果相当于或优于氯虫苯甲酰胺,对刺吸口器害虫如蚜虫等的防治效果优于溴氰虫酰胺.新型邻胺基苯甲酰胺类化合物Ic等可作为候选杀虫剂进一步研究开发.     

Pd/Mg(OH)2 Heterogeneous Nanocatalysts Synthesized by a Facile One-Pot Hydrothermal Method for CO Direct Esterification to Dimethyl Oxalate

Catalysis Letters - Pd-based heterogeneous nanocatalysts have wide application in chemical industry. However, the traditional synthesis process contains multi-steps such as impregnation, dry,...     

采用交流海缆接入的海上风电场无功配置方法

对于海上风电采用交流电缆接入电网的形式,由于电缆充电功率较大,在接入电缆超过一定距离时,可能导致海上风电工程及其并网点电压以及载流量控制困难.针对上述问题,本文提出了海上风电经由交流海缆接入输变电工程无功配置方法.该方法可确定初步的无功配置方案;然后对不同方案下海缆的载流量以及沿线的电压分布情况进行了分析;最后,结合不同接入功率下接入点的电压波动情况,验证初步无功配置方案的可行性.     

基于虚拟阻抗的逆变器并联控制策略研究

在低压微网孤岛运行中,基于下垂控制策略的逆变器并联控制会因控制器参数和线路阻抗的差异等因素出现功率耦合,难以精确分配输出功率,出现系统环流等问题.文中提出了一种引入虚拟阻抗的改进下垂控制策略.引入虚拟阻抗的负阻性部分减小线路的阻性分量,虚拟阻抗的感性部分增大系统的感性成分,减弱功率的耦合程度,提高功率分配精度和环流抑制效果.并在无功下垂控制中引入电压反馈和电压补偿环节,抬高逆变器的输出电压,减小电压降落,使逆变器并联运行拥有良好的供电质量.由Matlab/Simulink仿真验证了文中改进控制方法的有效性.     

Study on heat conduction and adsorption/desorption characteristic of MIL-101/few layer graphene composite

Journal of Porous Materials - Aiming at the poor heat conduction performance of porous MIL-101 applied in adsorption cooling process, few layer graphene (FLG) was selected as a promising thermal...     

Ovule Development and in Planta Transformation of Paphiopedilum Maudiae by Agrobacterium-Mediated Ovary-Injection

In this paper, the development of the Paphiopedilum Maudiae embryo sac at different developmental stages after pollination was assessed by confocal laser scanning microscopy. The mature seeds of P. Maudiae consisted of an exopleura and a spherical embryo, but without an endosperm, while the inner integument cells were absorbed by the developing embryo. The P. Maudiae embryo sac exhibited an Allium type of development. The time taken for the embryo to develop to a mature sac was 45-50 days after pollination (DAP) and most mature embryo sacs had completed fertilization and formed zygotes by about 50–54 DAP. In planta transformation was achieved by injection of the ovaries by Agrobacterium, resulting in 38 protocorms or seedlings after several rounds of hygromycin selection, corresponding to 2, 7, 5, 1, 3, 4, 9, and 7 plantlets from Agrobacterium-mediated ovary-injection at 30, 35, 42, 43, 45, 48, 50, and 53 DAP, respectively. Transformation efficiency was highest at 50 DAP (2.54%), followed by 2.48% at 53 DAP and 2.45% at 48 DAP. Four randomly selected hygromycin-resistant plants were GUS-positive after PCR analysis. Semi-quantitative PCR and quantitative real-time PCR analysis revealed the expression of the hpt gene in the leaves of eight hygromycin-resistant seedlings following Agrobacterium-mediated ovary-injection at 30, 35, 42, 43, 45, 48, 50, and 53 DAP, while hpt expression was not detected in the control. The best time to inject P. Maudiae ovaries in planta with Agrobacterium is 48-53 DAP, which corresponds to the period of fertilization. This protocol represents the first genetic transformation protocol for any Paphiopedilum species and will allow for expanded molecular breeding programs to introduce useful and interesting genes that can expand its ornamental and horticulturally important characteristics.     

论王维山水诗的空白艺术

本文论述了王维山水诗的空白艺术,指出由于他的道家思想中的"有"与"无"、佛家理念中的"空"与"寂",加之他所具有的良好绘画、音乐领悟能力,通过有与无、虚与实的结合,将中国绘画、音乐中的空白艺术与诗歌进行了紧密的结合,使诗成为一种玲珑剔透的,可以品、可以画、可以听的艺术品,并且其诗呈现出了一种"蓝田日暖,良玉生烟"的空灵境界.     

Graph-Based Dimensionality Reduction for Hyperspectral Imagery: A Review

Hyperspectral image(HSI) contains a wealth of spectral information, which makes fine classification of ground objects possible. In the meanwhile, overly redundant information in HSI brings many challenges. Specifically, the lack of training samples and the high computational cost are the inevitable obstacles in the design of classifier. In order to solve these problems, dimensionality reduction is usually adopted. Recently, graph-based dimensionality reduction has become a hot topic. In this paper, the graph-based methods for HSI dimensionality reduction are summarized from the following aspects. 1) The traditional graph-based methods employ Euclidean distance to explore the local information of samples in spectral feature space. 2) The dimensionality-reduction methods based on sparse or collaborative representation regard the sparse or collaborative coefficients as graph weights to effectively reduce reconstruction errors and represent most important information of HSI in the dictionary. 3) Improved methods based on sparse or collaborative graph have made great progress by considering global low-rank information, local intra-class information and spatial information. In order to compare typical techniques, three real HSI datasets were used to carry out relevant experiments, and then the experimental results were analysed and discussed.Finally, the future development of this research field is prospected.