Physical and Morphological Properties of Combined Treated Wood Polymer Composites by Maleic Anhydride and Methyl Methacrylate

Wood polymer composites were prepared by consecutive impregnation with maleic anhydride (MAN) and methyl methacrylate (MMA). Samples impregnated with MAN alone, were heated at 120°C and 150°C for 4 and 8 h. Based on the Fourier transform infrared (FT-IR) analysis and soaking-drying test results, treatment with MAN at 150°C for 4 h resulted in formation of stable crosslinks. In the second stage, MMA was used for in situ polymerization within MAN-treated wood. Field emission scanning electron microscopy observation and FT-IR analysis indicated that MMA copolymerized with MAN, and the resultant polymer filled up the lumen and is also grafted on to the cell wall. Improvement of water repellency and dimensional stability were observed in the treated samples, particularly in combined treated samples. The MAN/MMA treatment improved interaction between polymer and wood.     

A linear model of elasto-plastic and adhesive contact deformation

Rigorous non-linear models of elasto-plastic contact deformation are time-consuming in numerical calculations for the distinct element method (DEM) and quite often unnecessary to represent the actual contact deformation of common particulate systems. In this work a simple linear elasto-plastic and adhesive contact model for spherical particles is proposed. Plastic deformation of contacts during loading and elastic unloading, accompanied by adhesion are considered, for which the pull-off force increases with plastic deformation. Considering the collision of a spherical cohesive body with a rigid flat target, the critical sticking velocity and coefficient of restitution in the proposed model are found to be very similar to those of Thornton and Ning’s model. Sensitivity analyses of the model parameters such as plastic, elastic, plastic-adhesive stiffnesses and pull-off force on work of compaction are carried out. It is found that by increasing the ratio of elastic to plastic stiffness, the plastic component of the total work increases and the elastic component decreases. By increasing the interface energy, the plastic work increases, but the elastic work does not change. The model can be used to efficiently represent the force-displacement of a wide range of particles, thus enabling fast numerical simulations of particle assemblies by the DEM.     

ERES: an extended regular expression signature for polymorphic worm detection

Journal of Computer Virology and Hacking Techniques - The quick spreading of modern sophisticated polymorphic worms poses a serious threat to the internet security. So far, several signature...     

Synthesis of Cellulose-graft-Polychloromethylstyrene-graft-Polyacrylonitrile Terpolymer/Organoclay Bionanocomposite by Metal Catalyzed Living Radical Polymerization and Solvent Blending Method

A bionanocomposite of grafted cellulose and organo-modified clay was synthesized through solution intercalation method. For this purpose, chloromethylstyrene was grafted onto cellulose using acryloylchloride and the subsequent free radical polymerization. The synthesized cellulose-graft-polychloromethylstyrene was used as an atom transfer radical polymerization macroinitiator of acrylonitrile in the presence of CuCl/2,2′-bipyridine catalyst system, to prepare the cellulose-graft-polychloromethylstyrene-graft-polyacrylonitrile terpolymer. For preparing the modified clay, Na-montmorillonite was mixed with hexadecyl trimethyl ammonium chloride salt. Finally, cellulose-graft-polychloromethylstyrene-graft-polyacrylonitrile/organoclay bionanocomposite was prepared in CCl₄ by solution intercalation method.     

Large Scale Reservoirs System Operation Optimization: the Interior Search Algorithm (ISA) Approach

Reservoirs are built to provide a powerful tool to control and manage surface water resources in order to cover inconsistency between water resources and demands. Due to finite available water and the increasing demands for water especially in arid and semi-arid regions like Iran, reservoirs must be optimally operated in order to use water in the most efficient way. This study applies the Interior Search Algorithm (ISA) to solve large scale reservoirs system operation optimization problems. The ISA is a meta-heuristic algorithm inspired from a systematic methodology of architecture process and mirror work utilized by Persian designers for decoration. Unlike other meta-heuristic algorithms, the ISA just have one parameter to tune which is a great advantage. In this study the parameter of the ISA tuned automatically using a linear equation. A real-world one-reservoir operation problem (i.e. Karun-4) and two large scale benchmark problems (i.e. four-reservoir and ten-reservoir operation problem) were employed to show the effectiveness of the ISA. The results shows the high ability of the ISA to solve reservoirs system operation problems as it achieved solutions 99.97, 99.99 and 99.95 % of global optimum for Karun-4 reservoir, four-reservoir and ten-reservoir system operation problems, respectively. These results are the best results reported so far in the studied problems. Comparing results of the ISA with those of non-linear programming (NLP), linear programming (LP), genetic algorithm (GA) and other meta-heuristic algorithms indicates fast convergence to global optimum. Considering the results, it can be stated that the ISA is a powerful tool to optimize complex large scale reservoir system operation problems.     

Synthesis of water dispersible reduced graphene oxide via supramolecular complexation with modified β-cyclodextrin

A noncovalent functionalization of the edges of reduced graphene oxide (RGO) with β-cyclodextrin-graft-hyperbranched polyglycerol (β-CD-g-HPG) was successfully performed via a host-guest interaction. The results showed that β-CD-g-HPG disperses the graphene sheets better than pure β-CD or HPG. The resulted supramolecular structure is stable in neutral water medium more than one week. However, in acidic medium the host-guest interaction is collapsed and graphene nanosheets precipitate.     

Simulation and energy optimization of the stabilizer tower of a pyrolysis gasoline hydrogenation unit

Energy optimization of second distillation tower of a pyrolysis gasoline hydrogenation unit has been studied by the thermal cycle of vapor recompression method. The mentioned cycle is connected to the second distillation tower of the stabilizer of pyrolysis gasoline, and the results are found promising. The composite pinch curve for both the current and the optimized methods are shown. Moreover, an increase in the heat transfer rate in heat exchanger E-1014 causes energy recovery in reboiler. According to simulation results, by vapor recompression to 1970 kPa and using this heat source for thermal integration, condenser and reboiler’s energies are decreased by 56.93 and 30.4 percentage, respectively.     

Optimum section selection procedure for horizontal axis tidal stream turbines

Stochastic behavior of renewable energy sources forces designers to optimize the energy converters for the purpose of capturing the maximum amount of available energy. The performance of horizontal axis wind and tidal turbines mainly depends on the geometrical properties such as chord and twist distributions and also the types of sections which are utilized along the blade. The purpose of presented paper is introducing a procedure which can be utilized in order to select the optimum sections for horizontal axis tidal turbines for the purpose of increasing the turbine performance. The presented procedure also can be applied for horizontal axis wind turbines. For the purpose of evaluating the performance of the proposed method, two design types (chord and twist distributions) of tidal turbines are selected as case studies. Power coefficient is considered as objective function, and three types of hydrofoils namely NACA63-8xx, NACA44xx, and RISO-A1-xx are selected as candidate solutions. A blade element momentum theory model is used for calculating the power coefficient. The discrete ant colony optimization algorithm is selected as optimization tool. The results indicate that the utilization of the proposed method will considerably decrease the required process time for obtaining the optimum sections across the blade span, and also it is shown that using different types of sections across the blade span can increase the power coefficient of the turbine. The importance of the proposed method will be significant when various types of hydrofoils and airfoils can be considered as candidate sections across the blade span.