Growth of calcium carbonate by the atomic layer chemical vapour deposition technique

Thin films of CaCO₃ (calcite) have been grown with the atomic layer chemical vapour deposition (ALCVD) technique, using Ca(thd)₂ (Hthd=2,2,6,6-tetramethylheptan-3,5-dione), CO₂, and ozone as precursors. Pulse parameters for the ALCVD-type growth are found and self-limiting reaction conditions are established between 200 and 400 °C. Calcium carbonate films have been deposited on soda-lime glass, Si(100), -Al₂O₃(001), -Al₂O₃(012), -SiO₂(001), and MgO(100) substrates. The observed textures were: in-plane oriented films with [100](001)CaCO₃ [100](001)Al₂O₃ and [100](001)CaCO₃[110](001)Al₂O₃ on -Al₂O₃(001), amorphous films on -Al₂O₃(012) when grown at 250 °C, and columnar oriented films on soda-lime glass, Si(001), -SiO₂(001), and MgO(100) substrates with (00l) and (104) parallel to the substrate plane at 250 and 350 °C, respectively. The film topography was studied by atomic force microscopy and AC impedance characteristics were measured on as-deposited films at room temperature. The films were found to be insulating with a dielectric constant (_r) typically approximately 8. Thin films of CaO were obtained by heat treatment of the carbonate films at 670 °C in a CO₂-free atmosphere, but the thermal decomposition led to a significant increase in surface roughness.     

Continuous carbon nanotube reinforced composites

Carbon nanotubes are considered short fibers, and polymer composites with nanotube fillers are always analogues of random, short fiber composites. The real structural carbon fiber composites, on the other hand, always contain carbon fiber reinforcements where fibers run continuously through the composite matrix. With the recent optimization in aligned nanotube growth, samples of nanotubes in macroscopic lengths have become available, and this allows the creation of composites that are similar to the continuous fiber composites with individual nanotubes running continuously through the composite body. This allows the proper utilization of the extreme high modulus and strength predicted for nanotubes in structural composites. Here, we fabricate such continuous nanotube polymer composites with continuous nanotube reinforcements and report that under compressive loadings, the nanotube composites can generate more than an order of magnitude improvement in the longitudinal modulus (up to 3,300%) as well as damping capability (up to 2,100%). It is also observed that composites with a random distribution of nanotubes of same length and similar filler fraction provide three times less effective reinforcement in composites.     

Chemical doping and improved flux pinning in Hg-based superconductors

Chemical doping of a small amount (0.020.3) of rhenium (Re) ion into HgBa₂Ca_n–1Cu_nO_y(n=14) has been studied. The flux pinning strength in these Hg-based superconductors is significantly enhanced compared to the undoped parent materials. Neutron diffraction analysis of representative samples (n=3) revealed that Re partially substitutes the Hg-site with octahedrally fully coordinated oxygen atoms, giving rise to the stabilization of Hg(Re)O layer and reduction of this blocking layer thickness. Associated with the expected hybridization of Re-5d and O-2p orbitals and possible metallization of the Hg(Re)O layer, the improved flux pinning behavior is considered to be caused by the decrease of the electromagnetic anisotropy and the enhanced interlayer superconducting coupling strength.     

Ultralow Voltage Nanoelectronics Powered Directly, and Solely, From a Tree

Complex patterns of electrical potential differences exist across the structure of a tree. We have characterized these voltages, and measured values ranging from a few millivolts to a few hundred millivolts for Bigleaf maple trees. These potential differences provide a unique opportunity to power nanoelectronic circuits directly from a tree. We have designed, constructed, and successfully tested two ICs, powered solely through a connection to Bigleaf maple trees. The first circuit, built in a 130-nm technology, creates a stable 1.1 V supply from input voltages as low as 20 mV, and can be deployed to generate a usable voltage level for standard circuits. The second circuit, fabricated in 90-nm technology is a timer, operating at 0.045 Hz and can be used for time keeping in stand-alone sensor network nodes. The boost circuit and timer consume 10 and 2.5 nW of power during operation, respectively.      

Study of amperometric diffusion solid-state electrolyte cell operating regimes

Different operating regimes are considered for operation of an amperometric diffusion solid-state electrolyte cell for measuring the volume fraction of oxygen. The design of an oxygen sensor is described. Experimental results confirm the efficiency of the proposed diffusion solid-state electrolyte cell for measuring oxygen in the range of 98–100%. Translated from Izmeritel’naya Tekhnika, No. 10, pp. 64–65, October, 2008.     

Stochastic aspects of bridge deck aeroelasticity under turbulent flow

Returning to an earlier frequency-domain analysis of the problem of long-span bridge response to ambient winds, the paper emphasizes the indispensable experimental information necessary to bring results into conformity with full-scale prototype action. Focus is placed upon the use of a sectional wind tunnel model under simulated turbulent flow as the prime source of this information, which consists principally of the flutter derivatives and the spectra of the wind forces, both obtained under turbulent flow. The effect of three-dimensional turbulence upon the flutter derivatives is observed to influence structural stability in a manner consistent with that observed in full-bridge wind tunnel models.