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911.
Integrating legacy soil phosphorus into sustainable nutrient management strategies for future food,bioenergy and water security 总被引:11,自引:0,他引:11
912.
Morten Slyngborg Dennis Achton Nielsen Assoc. Prof. Peter Fojan 《Chembiochem : a European journal of chemical biology》2016,17(21):2083-2092
The self‐assembly of fibers from peptides has attracted a tremendous amount of attention due to its many applications, such as in drug‐delivery systems, in tissue engineering, and in electronic devices. Recently, the self‐assembly potential of the designer peptide RFFFR has been reported. Here it is experimentally verified that the peptide forms fibers that are entangled and form solid spheres without water inside. Upon dilution below the critical fiber concentration, the fibers untangle and become totally separated prior to dissolution. These structures readily bind thioflavin T, resulting in a characteristic change in fluorescent properties consistent with β‐sheet‐rich amyloid structures with aromatic/hydrophobic grooves. The circular dichroism spectroscopy data are dominated by a π→π* transition, thus indicating that the fibers are stabilized by π‐stacking. Contrary to what was expected, the dissolution of the spheres/fibers results in increasing fluorescence anisotropy over time. This is explained in terms of HomoFRET between phenylalanine residues with a T‐shaped π‐stacking mode, which was determined in another study to be the dominant mode through atomistic simulations and semiempirical calculations. Kelvin probe force microscopy measurements indicate that the spheres and fibers have a conductivity comparable to that of gold. Hence, these self‐assembled structures might be applicable in organic solid‐state electronic devices. The dissolution properties of the spheres further suggest that they might be used as drug‐delivery systems. 相似文献
913.
914.
Daniela M. Ushizima Hrishikesh A. Bale E. Wes Bethel Peter Ercius Brett A. Helms Harinarayan Krishnan Lea T. Grinberg Maciej Haranczyk Alastair A. Macdowell Katarzyna Odziomek Dilworth Y. Parkinson Talita Perciano Robert O. Ritchie Chao Yang 《JOM Journal of the Minerals, Metals and Materials Society》2016,68(11):2963-2972
915.
916.
Roza Bouchal Abdellah Hamel Peter Hesemann Martin In Bénédicte Prelot Jerzy Zajac 《International journal of molecular sciences》2016,17(2)
Surface activity and micelle formation of alkylguanidinium chlorides containing 10, 12, 14 and 16 carbon atoms in the hydrophobic tail were studied by combining conductivity and surface tension measurements with isothermal titration calorimetry. The purity of the resulting surfactants, their temperatures of Cr→LC and LC→I transitions, as well as their propensity of forming birefringent phases, were assessed based on the results of 1H and 13C NMR, differential scanning calorimetry (DSC), and polarizing microscopy studies. Whenever possible, the resulting values of Krafft temperature (TK), critical micelle concentration (CMC), minimum surface tension above the CMC, chloride counter-ion binding to the micelle, and the standard enthalpy of micelle formation per mole of surfactant (ΔmicH°) were compared to those characterizing alkyltrimethylammonium chlorides or bromides with the same tail lengths. The value of TK ranged between 292 and 314 K and increased strongly with the increase in the chain length of the hydrophobic tail. Micellization was described as both entropy and enthalpy-driven. Based on the direct calorimetry measurements, the general trends in the CMC with the temperature, hydrophobic tail length, and NaCl addition were found to be similar to those of other types of cationic surfactants. The particularly exothermic character of micellization was ascribed to the hydrogen-binding capacity of the guanidinium head-group. 相似文献
917.
Marie-Alix Pizzoccaro Martin Drobek Eddy Petit Gilles Guerrero Peter Hesemann Anne Julbe 《International journal of molecular sciences》2016,17(8)
Imidazolium bromide-based ionic liquids bearing phosphonyl groups on the cationic part were synthesized and grafted on γ-alumina (γ-Al2O3) powders. These powders were prepared as companion samples of conventional mesoporous γ-alumina membranes, in order to favor a possible transfer of the results to supported membrane materials, which could be used for CO2 separation applications. Effective grafting was demonstrated using energy dispersive X-ray spectrometry (EDX), N2 adsorption measurements, fourier transform infrared spectroscopy (FTIR), and special attention was paid to 31P and 13C solid state nuclear magnetic resonance spectroscopy (NMR). 相似文献
918.
Scheidler Stefan Anders Birte Regli Christian Bolay Stephan Huggenberger Peter 《Grundwasser》2019,24(4):277-286
Grundwasser - Topographically induced Alpine regional groundwater flow systems below the unconsolidated valley fillings constitute a substantial unused geothermal resource. Within the... 相似文献
919.
<正>奔富玛吉尔酒庄是奔富品牌以及澳大利亚最著名的红酒Grange的原产地,已被升级定位为南澳国际知名的旅游胜地。这一项目是对这个历史悠久的著名酒庄进行全面改造和提升,范围包括5公顷的优质西拉子葡萄树和酒庄上现存的历史建筑群和餐厅。新展厅与品酒间、先进的会议设施、教育场所、咖啡厅、红酒选购区、个人酒窖和为VIP地下酒库、美术馆和展馆区都为来访者带来一种独特的综合体验。 相似文献
920.
Hazrat Ali Azim Khan Tauqeer Ahmad Athanasia Dervisi Ian Fallis Ibrahim O. Shoetan Abbas Khan Arshad Hussain Peter Griffiths 《Journal of surfactants and detergents》2022,25(3):341-350
Zwitterionic surfactants based on 3-(1-alkyl-3-imidazolio) propane-sulfonate ([ImS3-R] where R is octyl or dodecyl) is an emerging and important class of amphiphile due to their relevance as nano reactors for the synthesis of metallic nanoparticles and accelerated acid hydrolysis. The physicochemical properties of such synthesized imidazolium ring-containing zwitterionic surfactants have been characterized by surface tension and small-angle neutron scattering (SANS) techniques. Surface tension measurements were used to calculate several thermodynamic parameters over a range of concentrations and temperatures (298–313 K). The results obtained showed a weak signature representing the critical micelle concentration (CMC) for ImS3-8, however, by increasing the alkyl length of the hydrophobic group to dodecyl, that is, ImS3-8 to ImS3-12, the signature of the CMC was much more evident. As expected, the CMC for ImS3-12 shifted to a lower concentration. An increase in temperature increased the surface activity and decreased the CMC of both zwitterionic surfactants, although the changes were small. Compared to classical surfactants, that is, sodium dodecyl sulfate and dodecyl trimethylammonium bromide, the CMC of ImS3-12 is much lower. Modeling of SANS data demonstrated that the morphology of the micelles formed by these amphiphiles may be described by the “classical” model, a central hydrophobic core, with a shell of hydrated headgroups. Due to their widespread applications in colloidal and interfacial science, the present study adds new insight to the fundamental understanding of these interesting imidazolium-based surface-active ionic liquids (ImS3-R). 相似文献