Electron spin resonance and AC susceptibility studies on La0.9Pb0.1MnO3 single crystals

Phase separation has been recognized as important properties of manganite to create colossal magnetoresistance (CMR). Frequency dependence of AC susceptibility and electron spin resonance (ESR) studies confirm the phase separated glassy magnetism in the La_0.9Pb_0.1MnO₃ crystals. ESR spectra exhibit a gradual narrowing of the asymmetric FMR signals upon increasing the temperature and approaching the Curie temperature (T_c). The temperature dependence of line width (ΔH_pp), g-factor, double integrated (I) intensity of the resonance signals and frequency dependence peak temperatures are discussed in this paper to explain inhomogeneity in the La_0.9Pb_0.1MnO₃ single crystals.     

Sintering and mechanical properties of MgO-doped nanocrystalline hydroxyapatite

Hydroxyapatite (HA) has been extensively studied for its exceptional ability in promoting osseointegration as in bone graft substitute and biomimetic coating of prosthetic implants. However poor mechanical properties of HA, in particular its low fracture toughness, has made its widespread adaption in a number of biomedical applications challenging. Here we employ an optimized wet precipitation method to synthesize nanocrystalline HA with significantly improved mechanical properties. In addition doping by MgO is found to effectively suppress grain growth and enhance fracture toughness by nearly 50% while good densification and phase stability in all samples regardless of concentration of dopant are fully maintained. Microstructural analysis further suggests that the exceptionally superior mechanical properties can be explained by migration of MgO to grain boundaries where they transform the more common transgranular fracture into an intergranular mode. Our biodegradation tests also confirm that MgO-doped HA is indeed a suitable candidate for load bearing implants.     

Porous composites of hydroxyapatite‐filled poly[ethylene‐co‐(vinyl acetate)] for tissue engineering

A novel porous composite of hydroxyapatite/poly[ethylene‐co‐vinyl acetate)] (HAP/EVA) having better osteointegration was fabricated by gas foaming technique using a non toxic gas blowing agent intended for bone replacement applications. Combined techniques of scanning electronic microscopy (SEM) and X‐ray microcomputed tomography (µCT) analysis showed that the pore size and pore volume of the porous composite decrease with the increase of HAP content. The gravimetric analysis evidenced for good pore interconnectivity within the porous composites. Energy dispersive X‐ray analysis (EDX) studies inveterated the even scattering of Ca ions which in turn indicate the uniform dispersion of HAP particles in the composites. The significant gradation in Ca ion concentration seen in EDX studies is well accordance with the amount of HAP loading in the sample. Mechanical properties of the porous composite having different HAP content were measured to have the compressive strength varying from 1.06 to 2.2 MPa. Non‐cytotoxic character of the material was observed by the cytocompatibility studies. The metabolic activity of L929 cells seeded on the material assessed by [3‐(4,5‐dimethylthiazol)‐2‐yl]‐2,5‐diphenyltertrazolium bromide (MTT) assay was found to be 91.8%. The adhesion and migration of the cells inside the pore walls were visualized by confocal microscopy. Copyright © 2010 Society of Chemical Industry     

A relativistic two-parameter core-envelope model of compact stars

A core-envelope model for a spherical superdense distribution of matter is reported, with a core consisting of anisotropic fluid engulfed by an envelope containing fluid with isotropic pressure is reported. The background space-time of the whole configuration is characterized by a two-parameter parabolic geometry. The physical plausibility of the model is examined both analytically and numerically, and suitability of the model for describing space-times of superdense stars containing strange matter, such as Her-X1 and SAX, is also discussed.     

Traffic sensing and characterization in multi-channel wireless networks for cognitive networking

Traffic sensing and characterization is an important building block of cognitive networking systems, however, it is very challenging to perform traffic characterization in multi-channel multi-radio wireless networks. Due to the presence of network traffic in multiple channels, the existing count-based packet sampling methods demand continuous capture on each channel to be effective; this requires a dedicated wireless interface per channel, and hence the existing sampling methods require a very expensive infrastructure and have poor scalability. Time-based sampling methods, on the other hand, offer a cost-effective and scalable solution by reducing the amount and cost of the resources necessary to monitor and characterize the wireless spectrum.The contributions of this paper include the following: (i) a discussion of packet sampling techniques for traffic sensing in multi-channel wireless networks, (ii) a comparison of various time-based sampling strategies using the Kullback–Leibler divergence (KLD) measure, (iii) a study on the effect of the sampling parameters on the accuracy of the sampling strategies, (iv) development of sampling accuracy graphs for easing the process of best sampling scheme selection in multi-channel wireless networks, (v) the proposal of a new metric (traffic intensity) which estimates the busyness of channels by taking into consideration not only the successfully received packets but also corrupt or broken packets, (vi) implementation of time-based sampling in a prototype traffic sensor device for multi-channel traffic sensing in IEEE 802.11 b/g networks, and (vii) characterization of a campus IEEE 802.11 network environment in a spatio-temporal–spectral fashion using sampled traffic traces collected by traffic sensors.     

A statistical approach to the optimization of a laser-assisted micromachining process

The objective of this study is to optimize a laser-assisted micro-grooving process designed for micromachining of difficult-to-machine materials such as hard mold/die steels and ceramics. The process uses a relatively low power continuous wave laser beam focused directly in front of a micro-grooving tool to thermally soften the material thereby lowering the cutting forces and associated machine and tool deflections. However, the use of laser heating can produce a detrimental heat-affected zone (HAZ) in the workpiece surface layers. Consequently, the laser and micro-grooving parameters need to be optimized in order to achieve the desired thermal softening effect while minimizing the formation of a HAZ in the material. Although thermal and force models for the hybrid process have been developed for possible use in process optimization, they are computationally intensive and are not accurate enough to produce reliable results. We overcome these deficiencies using a statistical approach. First, easy-to-evaluate metamodels are developed to approximate the complex engineering models. Then, the metamodels are statistically adjusted using real data from the process to make more accurate predictions. The optimization is then carried out on this statistically adjusted metamodels. The optimization strategy is experimentally verified and shown to yield good results.     

Exploring the role of the spacers and acceptors on the triphenylamine-based dyes for dye-sensitized solar cells

Six triphenylamine-based dyes were explored for their application in dye-sensitized solar cells (DSSCs). Dyes 1–3 and dyes 4–6 possess cyanoacrylic acid (C-acceptor) and rhodanine-3-acetic acid (R-acceptor), respectively. Stilbene (in dyes 2 and 5) and bis(styryl)benzene (in dyes 3 and 6) were used as π-spacers. There is no π-spacer in the dye 1 and 4. To elucidate the role of π-spacers, optical, electrochemical, and photovoltaic properties of the dyes were studied. Among C-acceptor dyes, dye 2 exhibits the highest light-to-electricity conversion efficiency of 4.45%, followed by dye 3 (4.16%). Similarly, among R-acceptor dyes, dye 5 is the best. These results indicate that stilbene is a better π-spacer over bis(styryl)benzene. Although bis(styryl)benzene could extend the light absorption range (in dye-adsorbed TiO₂ film), its tendency to promote intermolecular π-π stacking is possibly the reason for its poor performance in DSSCs. Furthermore, the conjugation break in the R-acceptor moiety attached to the TiO₂ surface limits the electron injection of R-acceptor dyes poorer than C-acceptor dyes. Density functional theory calculations were performed for the dye-(TiO₂)₈ cluster, assuming a bidentate chelation of a carboxylic acid group with Ti⁴⁺ of TiO₂ anatase. The natural bond orbital (NBO) analysis indicated relatively more electron-accepting ability of cyanoacrylic acid over rhodanine-3-acetic acid.     

Reactive power pricing structure for hydroelectric power station in condenser mode operation

Reactive power support is critical for system security and pricing of reactive power is a vital issue in restructured environment. Peaking units at hydroelectric power plant in condenser mode operation can provide major reactive power support. Therefore costing structure for hydroelectric power plant incorporating various cost components in condenser mode operation is presented in this paper. Major cost components include capital cost component, changeover cost component and a cost component related to number of service hours in condenser mode operation. A methodology is proposed based on these components. A case study of Koyna Hydro Electric Power Plant (KHEPP) is elaborated.