Modification of Fe and Al elemental powders’ sintering with addition of magnesium and magnesium hydride

An attempt to modify sintering of iron and aluminium elemental powders with use of small additions of Mg and MgH₂ was presented in this paper. The kinetics of such modified sintering was investigated using DSC technique, XRD analysis and SEM observations. Significant changes in the mechanism of exothermal formation reaction of Fe–Al intermetallic phases in compositions doped with magnesium and its hydride was observed. Initiation temperature of Self-propagating High-temperature Synthesis (SHS) reaction was pronouncedly shifted to lower value as compared with undoped composition. Influence of additions on the SHS reaction kinetics parameters was also calculated with use of the JMA model and changes of the Avrami exponent value of specific phase formation was noticed. Positive effect of MgH₂ addition on partial homogeneity of final product was also studied.     

Microstructure of NiCoAlFeCuCr multi-component systems synthesized by mechanical alloying

The present study uses the mechanical alloying method to produce series of binary to senary alloys based on Ni, Co, Al, Fe, Cu, Cr. Milling times are 0, 10, 20 and 30 h and experiments are performed in a high energy ball mill. The results of this investigation show that an FCC solid solution is formed in all the studied systems, but a different phase formation response is presented in each system. A mixture of FCC and BCC solid solutions in quaternary to senary systems, is formed for short milling times. Apparently, the dissolution rate of Fe and Cr into the FCC solid solution, is low. Moreover, it is observed that additions of these elements promote the formation of BCC solid solution, which is stable at temperatures up to ?1273 K. Finally, it is observed that the heat treated products present a mixture of FCC and BCC solid solutions with lattice parameters close to those found in the milled products.     

Study of the geometry of a voided clay brick using non-rectangular perforations to optimise its thermal properties

This study seeks to improve the geometrical distribution of bricks to optimise the equivalent thermal transmittance of a wall built of Termoarcilla^® ECO 29 voided clay bricks, using calculations according to Spanish UNE [1], AENOR [10], European EN [6], [7], [8] and [9] and international ISO [11] and [12] standards.The objective is to study improvements in the wall's thermal conductivity, always remembering the limitations imposed by the manufacturing process. Simulations are made using a finite elements application [14].It is concluded that, within the possibilities allowed by the manufacturing process, with non-rectangular voids the heat flux has to cross a higher number of voids, which improves its thermal properties. A rhomboid layout of voids with the longer diagonal at right angles to the heat flux is the best internal void layout. If the internal perforations are also extended to the end of the tongue and groove, the direct thermal bridge in this type of brick is broken.Finally, a 290 mm wide brick with 25 rows is obtained with the geometrical properties described above which shows an improvement of almost 16% over the original ECO 29 brick, performing well in all climatic areas of Spain, with a full-bed mortar joint 30 mm thick.     

Analysis and DEM simulation of granular material flow patterns in hopper models of different shapes

By using the discrete element method (DEM) a comparison and observations on material flow patterns in plane-wedged, space-wedged, and flat-bottomed hopper were accounted for. Numerical results obtained by combining data of individual particles, statistical processing of particle assemblies and evaluation of the field variables provided the essential characteristics for different regimes of the discharge flow (within steady or unsteady state of flow) and the differences in differently shaped hoppers due to different microscopic inter-particle friction. For validation of the performed simulations, velocity patterns developed in three-dimensional flat-bottomed hopper containing 20,400 pea grains were also analysed. To represent the continuum by avoiding the local effects produced by the individual grains, the simulation results were focused on the mean velocity distributions with data smoothening. The effect of rolling resistance on granular material flow was also considered.     

Use of coordinate measuring machines and digital optical machines for the geometric characterization of circumference arcs using the minimum zone method

This paper presents an optimised method for the characterization of circular features of any amplitude, which includes the capture of geometric data, by means of the use of three-coordinate measuring machine or digital optical machines with a CCD camera, and its subsequent mathematical processing. The proposed model determines the radius and the circularity error, based on the minimum zone method, and to this end it uses linear programming techniques, the Simplex programming principles and the limaçon approximation. An experimental study on ring gauges and reference disks is provided, including a comparative analysis using the Chauvenet and Grubbs filtering procedures. Last of all, an uncertainty estimation method is proposed by means of the Monte Carlo simulation. The experimental analysis carried out on ring gauges and reference disks accredit that the algorithm developed, implemented in a Matlab® environment, gives reliable results for any circumference arc considered, regardless of its amplitude.     

Physical and mechanical characterization of phyllites and metagreywackes in central Portugal

This work defines the physical and mechanical characteristics of phyllites and metagreywackes belonging to a schist–greywacke complex in central Portugal. The index properties, point load strength, uniaxial compressive strength, slake durability and Schmidt rebound hardness were determined. In general, the metagreywackes gave a higher strength than phyllites with the same weathering degree. Possible correlations and estimation models were established and compared with the equations obtained by different researchers.     

Is time really important for research into contracting out public services in cities? Evidence for urban water management in Southern Spain

Local governments are responsible for the supply of important public services in cities. On many occasions the management of those services is externalized. There is extensive literature analyzing the explanations for the governance option taken by local governments, aiming to ascertain the reasons why the management of certain services is externalized. Recent research has highlighted the fact that time has not been contemplated by research dealing with explanatory factors in the decision to contract out municipal services. This is a key issue in order to identify the real reason behind policymakers’ decisions about the management of the services in cities. This paper tests the importance of taking into account time in the research into contracting out. This is undertaken by means of two methodological tests in the design of variables from a dataset containing 744 municipalities in Southern Spain. Using this empirical analysis as a basis, it is concluded that considering time contributes towards enhancing the specification of the model and that omitting this aspect could lead to misunderstanding the motivation behind such decisions.     

Multiscale Fitting Procedure Using Markov Modulated Poisson Processes

This paper proposes a parameter fitting procedure using Markov Modulated Poisson Processes (MMPPs) that leads to accurate estimates of queuing behavior for network traffic exhibiting long-range dependence behavior. The procedure matches both the autocovariance and marginal distribution of the counting process. A major feature is that the number of states is not fixed a priori, and can be adapted to the particular trace being modeled. The MMPP is constructed as a superposition of L 2-MMPPs and one M-MMPP. The 2-MMPPs are designed to match the autocovariance and the M-MMPP to match the marginal distribution. Each 2-MMPP models a specific time-scale of the data. The procedure starts by approximating the autocovariance by a weighted sum of exponential functions that model the autocovariance of the 2-MMPPs. The autocovariance tail can be adjusted to capture the long-range dependence characteristics of the traffic, up to the time-scales of interest to the system under study. The procedure then fits the M-MMPP parameters in order to match the marginal distribution, within the constraints imposed by the autocovariance matching. The number of states is also determined as part of this step. The final MMPP with M2 ^L states is obtained by superposing the L 2-MMPPs and the M-MMPP. We apply the inference procedure to traffic traces exhibiting long-range dependence and evaluate its queuing behavior through simulation. Very good results are obtained, both in terms of queuing behavior and number of states, for the traces used, which include the well-known Bellcore traces.